Triassic calc-alkaline lamprophyre dykes from the North Qiangtang, central Tibetan Plateau: evidence for a subduction-modified lithospheric mantle

Primitive lamprophyres in orogenic belts can provide crucial insights into the nature of the subcontinental lithosphere and the relevant deep crust–mantle interactions. This paper reports a suite of relatively primitive lamprophyre dykes from the North Qiangtang, central Tibetan Plateau. Zircon U–Pb ages of the lamprophyre dykes range from 214 Ma to 218 Ma, with a weighted mean age of 216 ± 1 Ma. Most of the lamprophyre samples are similar in geochemical compositions to typical primitive magmas (e.g. high MgO contents, Mg no. values and Cr, with low FeOt/MgO ratios), although they might have experienced a slightly low degree of olivine crystallization, and they show arc-like trace-element patterns and enriched Sr–Nd isotopic composition ((87Sr/86Sr)i = 0.70538–0.70540, ϵNd(t) = −2.96 to −1.65). Those geochemical and isotopic variations indicate that the lamprophyre dykes originated from partial melting of a phlogopite- and spinel-bearing peridotite mantle modified by subduction-related aqueous fluids. Combining with the other regional studies, we propose that slab subduction might have occurred during Late Triassic time, and the rollback of the oceanic lithosphere induced the lamprophyre magmatism in the central Tibetan Plateau.

Isotopic signatures induced by upwelling tag regional fish populations in Lake Tanganyika

Lake Tanganyika's pelagic fish sustain the second largest inland fishery in Africa and are under pressure from heavy fishing and global warming related increases in stratification. Only little is known about whether basin-scale hydrodynamics - including a more stratified north and an upwelling-driven south - lead to regional fish populations with varying ecological adaptations. Here, we examine whether the basin-scale dynamics leave distinct isotopic imprints in the pelagic fish of Lake Tanganyika, which may reveal differences in habitat, diet, or lipid content. We conducted two lake-wide campaigns during different seasons and collected physical, nutrient, chlorophyll, phytoplankton and zooplankton data. Additionally, we analyzed the pelagic fish - the clupeids Stolothrissa tanganicae, Limnothrissa miodon and four Lates species - for their isotopic and elemental carbon (C) and nitrogen (N) compositions. The δ13C values were significantly higher in the productive south after the upwelling/mixing period across all trophic levels, implying that the fish have regional foraging grounds, and thus record these latitudinal isotope gradients. However, the degree of regional isolation is insufficient to suppress lake-wide gene flow, suggesting that the fish form regional populations only on a basin-wide and seasonal scale. Based on δ15N and C:N ratios, we found no strong evidence for varying diets or lipid contents between those populations. Additional analyses revealed that isotopic variations between specimens from the same location are not linked to genetic differences. Our findings provide fundamental insight on the connectivity and ecology of Lake Tanganyika's pelagic fish and imply that sustainable management strategies may adopt basin-scale fishing quotas.

Plumbotectonics of Moroccan ore deposits

The synthesis of 240 lead isotopes analyzes, measured on Moroccan ore deposits of Ediacarian to Neogene ages located in all geotectonic domains of Morocco allows a global reflection on the metallogeny of Morocco. The isotopic compositions vary widely, from 17.738 (Bou Skour) to 18.905 (Draa Sfar) for the 206Pb/204Pb ratio, and from 15.521 to 15.706 for the 207Pb/204Pb ratio. The source of lead in the studied deposits is located in the upper continental crust, except for those in the Anti-Atlas (Bou Skour, Imiter, etc.) and some in the High Atlas (Azegour) with a clear mantellic contribution. Isotopic variations noted at the scale of a district result either from the presence of several superimposed hydrothermal events calling upon different local sources as at Tighza, or from a single event disturbed by the segmentation of a volcanosedimentary basin, as for the Jebilet and Guemassa ore deposits. At the scale of the deposit (Draa Sfar, Bou Skour), isotopic variations result from the superposition of several hydrothermal events each with their own lead and associated metals. Overall, we can distinguish three generations of lead incorporated successively into the Moroccan geological base by magmatism and / or hydrothermalism, characterized by their 206Pb/204Pb ratios: 17.74-17.90 (Ediacarian), 18.10-18.40 (Hercynian) and 18.75-18.90 (Alpine). Ediacarian lead is present in the Anti-Atlas, and very locally in the meseta (Bouznika), and feeds in part on the mafic magmatism of Gondwana. Hercynian lead is the most represented and displays a definitive rupture in the source of metals, which is now exclusively crustal. It invades all Moroccan areas, including the Anti-Atlas, where it re-mobilizes and mixes with the Ediacaran lead. Alpine lead, more discreet, marks out the large scarf going from Agadir to Nador which traces on the surface the mantle plume of the Canaries and accompanies a Neogene magmatism which may also have acted as a simple engine remobilizing Hercynian lead, in particular to form MVT deposits from Touissit. The Hercynian and Alpine lead influxes are partly responsible for resetting the mineralizations, as at Bou Azzer or Imiter. In the Sawkins’s model, lead isotopic results support successive remobilisations of lead stored in primary and secondary tanks, as well as inheritance phenomena. Finally, the good transfer of the isotopic signature of lead from deposits to surface gossans shows that the isotopic geochemistry of lead is a useful tool for mineral exploration in Morocco.

Investigating Hydrogen Isotope Variation during Heating of n-Alkanes under Limited Oxygen Conditions: Implications for Palaeoclimate Reconstruction in Archaeological Settings

This paper reports on a series of heating experiments that focus on n-alkanes extracted from leaf, bark, and xylem tissues of the Celtis australis plant. These lipid biomarkers were analysed for their compound-specific hydrogen isotopic composition (δ2Hwax) under limited oxygen conditions at 150, 250, 350, and 450 °C. Our results reveal isotopic variations in wax lipids of different plant organs during short-term low-temperature combustion. We conclude that, in the absence of a detailed characterisation of the depositional environment in advance of sampling, δ2Hwax values in archaeological or otherwise highly anthropogenic environments should be interpreted cautiously. In addition, we observed that variation in δ2Hwax of leaves is minimal at temperatures ≤ 350 °C, highlighting the potential for δ2Hwax in thermally altered combustion substrates to yield palaeoclimate information, which could allow researchers to investigate links between archaeological and climatic records at a high spatial and temporal resolution.