The Effect of Differentiation Processes in Tholeiite-Basalt Melts on the Rare Elements Distribution

Basite magmatism has been manifested repeatedly for a long time in various geodynamic structures within the eastern part of the Siberian platform. In the Middle Paleozoic, it was related to rifting processes, and in the Late Paleozoic-Early Mesozoic – to the initiation and development of trap syneclises. Differences of the geodynamic regime of magma formation are displayed in the material composition of rocks. This report presents a generalizing study of the petro-geochemical features of the tholeiitic basaltic melts formed in different geodynamic settings. The initial magmas composition changes significantly at different stages of the magmatic system development. Using multicomponent analysis, we reviewed the impact of the fractionation processes of the basal melt, which occurred under various PT conditions, on its material composition. Among the trapp bodies there are powerful differentiated intrusions. A significant change of the composition occurs during the intra-chamber differentiation of the melt in a sequence of rock strata varied from the basic magnesian to felsic alkaline rocks. In the resulting series of rocks, the content of rare elements included in the lattice of the early femic phases decreases, as well as the accumulation of almost all incompatible elements. The evolution of melts of normal alkalinity occurs with an increase of REE content and their insignificant separation. Intrusions that have undergone the stage of high-pressure fractionation in the deep transitional chamber are of particular importance. As a result of such differentiation, a peculiar group of rocks is formed in the cross section of the Middle Paleozoic bodies, such as monzonite-porphyries in one case and anorthosite gabbro-dolerites - in the other. . It is established that the monzoitoid type of differentiation is characterized by accumulation of LREE, LILE and elements of the zirconium group Nb, Ta, Hf and Y. Isolation of anorthosite gabbro-dolerites in the cross-section of bodies, as well as an increase in the content of aluminum, calcium, and strontium in them, is an indication of the anorthositic tendency of magmatic melt differentiation/When the basite-tholeiite melt interacts with the mantle reducing fluid in the deep core, its metallization occurs with the release of drop-liquid separations of native iron up to the formation of its large segregations. Intrusions with a large-scale content of native iron are found among the trap formations of Siberia. All this leads to a decrease in the total concentration and activity of iron in the partially metallized silicate matrix, there is a significant increase in the content of MgO and trace elements-Ni, Co, Cr. The Fe-phase-containing intrusives are characterized by minimal LILE, HFSE, and REE contents. Start your abstract here… 250 to 500 words concise and factual abstract is required. The abstract should include the purpose of research, principal results and major conclusions. References should be avoided, if it is essential, only cite the author(s) and year(s) without giving reference list. Prepare your abstract in this file and upload it into the registration web field.

Mineralization in the andesitic lava from Kildyam volcanic complex, central Yakutia, Russia

This contribution presents the first detailed analysis of a new volcanic succession of olivine-pyroxenites, andesite, and dacite discovered in the Kildyam Late Jurassic complex in Central Yakutia. Petrographic and microprobe studies confirmed the liquid immiscibility in silicate melts during crystallization. Immiscible liquids are preserved as globules of one glass in another in andesites and as melted inclusions of native iron in matrix, clinopyroxene and plagioclase phenocrysts. Our analyses reveal the complex textural relationships between silicates and Fe-oxides, native iron and (Cu, Pb, Ag and Au)-rich phases, and provide unequivocal textural evidences, not observed previously. Purpose of this research is to preserve a very important data on IO (Iron Oxide) or IOCG (Iron Oxide Copper Gold) mineralization. Obtained results support occurrence and diverse of gold, silver, copper and lead minerals in magnetite lavas. During the early stage of fine-grained subvolcanic olivine-clinopyroxenite end pyrrhotite, globular igneous sulfides is a first proposed style of economic deposit formation. The second proposed style of economic mineralization in Kildyam is to be a magnetite-bearing lava; iron enrichment of the melilitic melt phase, followed by iron depletion and silica enrichment. The vesicle-hosted alloys and sulfides provide significant new data on metal transport and precipitation from high-temperature magmatic vapors. During syneruptive vapor phase exsolution, volatile metals (Cu-Zn, Fe-Al-Cu, Ni-Fe-Cu-Sn) and Ag-Cu-sulfides contribute to the formation of economic concentrations. Major conclusions contribute to 3-step genetic model. (1) Early-formed magmatic minerals led to partial dissolution of olivine-clinopyroxenite and their enrichment in Cu, Co and Ni relative to other metals, while troilite globules droplets grew.(2) First stage of division into two immiscible silicate and sulfide melt liquids (a) K-rich dacitic and rhyolithic glass, and (b) vesicles of heavy sulfide minerals with a large segregations and drops of native iron. (3) Lava of fused magnetite crystals and voids enriched in silver and gold, and (b) globular disseminated chalcopyrite in mineralized melilitic rocks.

Mineralogy and geochemistry of native iron

Basite magmatism has been manifested repeatedly for a long time in various geodynamic structures within the eastern part of the Siberian platform. In the Middle Paleozoic, it was related to rifting processes, and in the Late Paleozoic-Early Mesozoic – to the initiation and development of trap syneclises. Differences of the geodynamic regime of magma formation are displayed in the material composition of rocks. This report presents a generalizing study of the petro-geochemical features of the tholeiitic basaltic melts formed in different geodynamic settings. The initial magmas composition changes significantly at different stages of the magmatic system development. Using multicomponent analysis, we reviewed the impact of the fractionation processes of the basal melt, which occurred under various PT conditions, on its material composition. Among the trapp bodies there are powerful differentiated intrusions. A significant change of the composition occurs during the intra-chamber differentiation of the melt in a sequence of rock strata varied from the basic magnesian to felsic alkaline rocks. In the resulting series of rocks, the content of rare elements included in the lattice of the early femic phases decreases, as well as the accumulation of almost all incompatible elements. The evolution of melts of normal alkalinity occurs with an increase of REE content and their insignificant separation. Intrusions that have undergone the stage of high-pressure fractionation in the deep transitional chamber are of particular importance. As a result of such differentiation, a peculiar group of rocks is formed in the cross section of the Middle Paleozoic bodies, such as monzonite-porphyries in one case and anorthosite gabbro-dolerites - in the other. It is established that the monzoitoid type of differentiation is characterized by accumulation of LREE, LILE and elements of the zirconium group Nb, Ta, Hf and Y. Isolation of anorthosite gabbro-dolerites in the cross-section of bodies, as well as an increase in the content of aluminum, calcium, and strontium in them, is an indication of the anorthositic tendency of magmatic melt differentiation/When the basite-tholeiite melt interacts with the mantle reducing fluid in the deep core, its metallization occurs with the release of drop-liquid separations of native iron up to the formation of its large segregations. Intrusions with a large-scale content of native iron are found among the trap formations of Siberia. All this leads to a decrease in the total concentration and activity of iron in the partially metallized silicate matrix, there is a significant increase in the content of MgO and trace elements-Ni, Co, Cr. The Fe-phase-containing intrusives are characterized by minimal LILE, HFSE, and REE contents. Start your abstract here… 250 to 500 words concise and factual abstract is required. The abstract should include the purpose of research, principal results and major conclusions. References should be avoided, if it is essential, only cite the author(s) and year(s) without giving reference list. Prepare your abstract in this file and upload it into the registration web field.

GEODYNAMICS

The purpose of the study. It needs to substantiate that sources of magnetic anomalies with wavelengths of the first thousand kilometers detected at the present time might have a magneto-mineralogical origin due to the existence of magnetic minerals at the mantle depths, in particular magnetite, hematite, native iron, as well as iron alloys. It should be also shown that present temporal changes of long-wave magnetic anomalies should be induced by changes of the magnetic properties of these minerals due to thermodynamic and fluid modes. According to numerous authors, the transformations of magnetic minerals occur in special tectonic zones of the upper mantle of the Earth, in particular at junction zones of lithospheric plates of different types, rifts, plumes, tectonic-thermal activation, etc. Areas of the upper mantle with temperatures below the Curie temperature of magnetite can be magnetic, such as subduction zones, cratons, and regions with the old oceanic lithosphere. Iron oxides might be a potential source of magnetic anomalies of the upper mantle besides magnetite and native iron, in particular hematite (α-Fe2O3), which is the dominant oxide in subduction zones at depths of 300 to 600 km. It was proved experimentally by foreign researchers that in cold subduction slabs, hematite remains its magnetic properties up to the mantle transition zone (approximately 410-600 km). Conclusions. A review of previous studies of native and foreign authors has made it possible to substantiate the possibility of the existence of magnetized rocks at the mantle depths, including native iron at the magneto-mineralogical level, and their possible changes due to thermodynamic factors and fluid regime. It has been experimentally proven by foreign researchers that in subduction zones of the lithospheric slabs their magnetization might be preserved for a long time at the mantle depths, as well as increase of magnetic susceptibility may observed due to the Hopkinson effect near the Curie temperature of magnetic minerals. Practical value. Information about the ability of the mantle to contain magnetic minerals and to have a residual magnetization up to the depths of the transition zone was obtained. It should be used in the interpretation of both modern magnetic anomalies and paleomagnetic data.

Phase Relations in the FeO-Fe3C-Fe3N System at 7.8 GPa and 1350 °C: Implications for Oxidation of Native Iron at 250 km

Oxidation of native iron in the mantle at a depth about 250 km and its influence on the stability of main carbon and nitrogen hosts have been reconstructed from the isothermal section of the ternary phase diagram for the FeO-Fe3C-Fe3N system. The results of experiments at 7.8 GPa and 1350 °C show that oxygen increase in the system to > 0.5 wt % provides the stability of FeO and leads to changes in the phase diagram: the Fe3C, L, and Fe3N single-phase fields change to two-phase ones, while the Fe3C + L and Fe3N + L two-phase fields become three-phase. Сarbon in iron carbide (Fe3C, space group Pnma) is slightly below the ideal value and nitrogen is below the EMPA (Electron microprobe analysis) detection limit. Iron nitride (ε-Fe3N, space group P63/mmc) contains up to 2.7 wt % С and 4.4 wt % N in equilibrium with both melt and wüstite but 2.1 wt % С and 5.4 wt % N when equilibrated with wüstite alone. Impurities in wüstite (space group Fmm) are within the EMPA detection limit. The contents of oxygen, carbon, and nitrogen in the metal melt equilibrated with different iron compounds are within 0.5–0.8 wt % O even in FeO-rich samples; 3.8 wt % C and 1.2 wt % N for Fe3C + FeO; and 2.9 wt % C and 3.5 wt % N for Fe3N + FeO. Co-crystallization of Fe3C and Fe3N from the O-bearing metal melt is impossible because the fields of associated C- and N-rich compounds are separated by that of FeO + L. Additional experiments with excess oxygen added to the system show that metal melt, which is the main host of carbon and nitrogen in the metal-saturated (~0.1 wt %) mantle at a depth of ~250 km and a normal heat flux of 40 mW/m2, has the greatest oxygen affinity. Its partial oxidation produces FeO and causes crystallization of iron carbides (Fe3C and Fe7C3) and increases the nitrogen enrichment of the residual melt. Thus, the oxidation of metal melt in the mantle enriched in volatiles may lead to successive crystallization of iron carbides and nitrides. In these conditions, magnetite remains unstable till complete oxidation of iron carbide, iron nitride, and the melt. Iron carbides and nitrides discovered as inclusions in mantle diamonds may result from partial oxidation of metal melt which originally contained relatively low concentrations of carbon and nitrogen.

Molecular Hydrogen in Natural Mayenite

In the last 15 years, zeolite-like mayenite, Ca12Al14O33, has attracted significant attention in material science for its variety of potential applications and for its simple composition. Hydrogen plays a key role in processes of electride material synthesis from pristine mayenite: {Ca12Al14O32}2+(O2) → {Ca12Al14O32}2+(e−)2. A presence of molecular hydrogen in synthetic mayenite was not confirmed by the direct methods. Spectroscopy investigations of mayenite group mineral fluorkyuygenite, with empirical formula (Ca12.09Na0.03)∑12.12(Al13.67Si0.12Fe3+0.07Ti4+0.01)∑12.87O31.96 [F2.02Cl0.02(H2O)3.22(H2S)0.15□0.59]∑6.00, show the presence of an unusual band at 4038 cm−1, registered for the first time and related to molecular hydrogen, apart from usual bands responding to vibrations of mayenite framework. The band at 4038 cm−1 corresponding to stretching vibrations of H2 is at lower frequencies in comparison with positions of analogous bands of gaseous H2 (4156 cm−1) and H2 adsorbed at active cation sites of zeolites (4050–4100 cm−1). This points out relatively strong linking of molecular hydrogen with the fluorkyuygenite framework. An appearance of H2 in the fluorkyuyginite with ideal formula Ca12Al14O32[(H2O)4F2], which formed after fluormayenite, Ca12Al14O32[□4F2], is connected with its genesis. Fluorkyuygenite was detected in gehlenite fragments within brecciaed pyrometamorphic rock (Hatrurim Basin, Negev Desert, Israel), which contains reduced mineral assemblage of the Fe-P-C system (native iron, schreibersite, barringerite, murashkoite, and cohenite). The origin of phosphide-bearing associations is connected with the effect of highly reduced gases on earlier formed pyrometamorphic rocks.

Formation of Hydrocarbons in the Presence of Native Iron under Upper Mantle Conditions: Experimental Constraints

The formation of hydrocarbons (HCs) upon interaction of metal and metal–carbon phases (solid Fe, Fe3C, Fe7C3, Ni, and liquid Fe–Ni alloys) with or without additional sources of carbon (graphite, diamond, carbonate, and H2O–CO2 fluids) was investigated in quenching experiments at 6.3 GPa and 1000–1400 °C, wherein hydrogen fugacity (fH2) was controlled by the Fe–FeO + H2O or Mo–MoO2 + H2O equilibria. The aim of the study was to investigate abiotic generation of hydrocarbons and to characterize the diversity of HC species that form in the presence of Fe/Ni metal phases at P–T–fH2 conditions typical of the upper mantle. The carbon donors were not fully depleted at experimental conditions. The ratio of H2 ingress and consumption rates depended on hydrogen permeability of the capsule material: runs with low-permeable Au capsules and/or high hydrogenation rates (H2O–CO2 fluid) yielded fluids equilibrated with the final assemblage of solid phases at fH2sample ≤ fH2buffer. The synthesized quenched fluids contained diverse HC species, predominantly light alkanes. The relative percentages of light alkane species were greater in higher temperature runs. At 1200 °C, light alkanes (C1 ≈ C2 > C3 > C4) formed either by direct hydrogenation of Fe3C or Fe7C3, or by hydrogenation of graphite/diamond in the presence of Fe3C, Fe7C3, and a liquid Fe–Ni alloy. The CH4/C2H6 ratio in the fluids decreased from 5 to 0.5 with decreasing iron activity and the C fraction increased in the series: Fe–Fe3C → Fe3C–Fe7C3 → Fe7C3–graphite → graphite. Fe3C–magnesite and Fe3C–H2O–CO2 systems at 1200 °C yielded magnesiowüstite and wüstite, respectively, and both produced C-enriched carbide Fe7C3 and mainly light alkanes (C1 ≈ C2 > C3 > C4). Thus, reactions of metal phases that simulate the composition of native iron with various carbon donors (graphite, diamond, carbonate, or H2O–CO2 fluid) at the upper mantle P–T conditions and enhanced fH2 can provide abiotic generation of complex hydrocarbon systems that predominantly contain light alkanes. The conditions favorable for HC formation exist in mantle zones, where slab-derived H2O-, CO2- and carbonate-bearing fluids interact with metal-saturated mantle.