Chemical and Structural Analysis of Newly Prepared Co-W-Al Alloy by Aluminothermic Reaction

This article is devoted to the characterization of a new Co-W-Al alloy prepared by an aluminothermic reaction. This alloy is used for the subsequent preparation of a special composite nanopowder and for the surface coating of aluminum, magnesium, or iron alloys. Due to the very high temperature (2000 °C–3000 °C) required for the reaction, thermite was added to the mixture. Pulverized coal was also added in order to obtain the appropriate metal carbides (Co, W, Ti), which increase hardness, resistance to abrasion, and the corrosion of the coating and have good high temperature properties. The phase composition of the alloy prepared by the aluminothermic reaction showed mainly cobalt, tungsten, and aluminum, as well as small amounts of iron, titanium, and calcium. No carbon was identified using this method. The microstructure of this alloy is characterized by a cobalt matrix with smaller regular and irregular carbide particles doped by aluminum.

Effect of rolling deformation on microstructure and properties of Cu–Ni–Mo alloy prepared by aluminothermic reaction

The metallic element Mo has almost no solid solubility in copper and can be used as a nucleation particle to refine the grain size and increase the recrystallization temperature of the alloy during solidification. It is expected to obtain copper alloys with good comprehensive properties by reasonably controlling the addition amount of Mo. However, it is difficult to prepare Cu–Mo alloys with uniform structure and there are few related literatures. In this paper, the aluminothermic reaction method, which has the advantages of simple process, low cost, and large size of the prepared alloy, was adopted, and a cluster model with the atomic ratio of Mo and Ni of 1:12 was introduced to design the alloy composition. Here, five alloys with different copper contents were prepared and followed by room temperature rolling with 40%, 60%, and 80% deformation. The results show that the as-cast Cu–Ni–Mo alloys exhibit good formability, have no macroscopic defects and present a small amount of precipitates. With the increase of alloy elements Ni and Mo, the hardness and strength of the alloys increase obviously, while the electrical conductivity decreases gradually. For the rolled alloys, a large number of lamellar deformed structures are formed, the grains are obviously refined, the precipitated phases are broken and the distribution is more uniform, thus the strength and hardness of the alloy increase significantly, the plasticity decrease significantly, while the conductivity changed little. In this study, high-strength samples were obtained, which may be a valuable exploration for the preparation of Cu–Ni–Mo alloy sheets with excellent microstructure and mechanical properties.

Investigation on the quality of silicon extracted from the Padma river sand using magnesio-aluminothermic process

Investigation on the quality of the extracted Silicon (Si) from the sand of the Padma river of Bangladesh using the Magnesio-Aluminothermic process has been presented in this work. Magnesio-Aluminothermic process, which is low-energy, low-cost and CO2 free compared to conventional carbothermic process, was used for the extraction of Si from the sand. By performing the thermite process, Si was extracted as a eutectic mixture of Aluminium and Si, following that, several cycles of acid leaching were used to obtain highly pure polycrystalline silicon. After grinding the cleaned sand and making a homogeneous mixture with associated chemicals and ignition materials, modified Aluminothermic reaction was performed to produce a eutectic mixture of Si and Al. Grinded eutectic mixture of Si and Al was then purified with acid leaching and finally above 97% pure crystalline Si was extracted. XRD (X-ray diffraction) and Raman Spectroscopy confirmed the polycrystalline nature of Si where XRF (X-ray fluorescence) and EDX (Energy Dispersive X-ray Spectroscopy) corroborated the high purity of extracted Si describing the chemical composition. Bangladesh Journal of Physics, 26(2), 33-40, December 2019

Effect of multiple warm rolling on microstructure and mechanical properties of 304 stainless steel prepared by aluminothermic reaction

304 stainless steels were prepared by aluminothermic reaction method; first steels are annealed at 1000°C and then rolled at 700°C for different deformation. The microstructures evolution and mechanical properties were distinguished in details. It was found that the steel contains nanocrystalline/submicrocrystalline/microcrystalline austenite and submicrocrystalline ferrite. After rolling to a thickness reduction of 30%, 50%, and 70%, the mechanical properties of the rolled steels were substantially increased, as the deformation increased from 30% to 50%, the tensile strength increased from 650 to 1110 MPa, the yield strength increased from 400 to 665 MPa, and the elongation increased from 8% to 8.5%.

Rolling tuning microstructure and tensile properties of nano/microcrystalline 304 stainless steel

The effect of rolling parameters on microstructure and tensile properties of nanocrystalline/microcrystalline 304 stainless steel (SS) casted by the aluminothermic reaction was investigated in this work. It was found that majority of the nanocrystalline austenite of the 304 SS rolled at 700[Formula: see text]C and 900[Formula: see text]C grew up and transformed to sub-microcrystalline. While the nanocrystalline/microcrystalline structure still retained rolled at 900[Formula: see text]C with 40% deformation followed 600[Formula: see text]C with 70% thickness reduction, and microcrystalline austenite grains distributed evenly. The strength and ductility of the various rolled 304 SS were improved compared with the as-casted 304 SS steel. The steel rolled at 900[Formula: see text]C with 80% deformation exhibited a uniform elongation as large as 31.3%, which is almost the same ductility level of counterpart coarse-grained steel. The rolled steel at 700[Formula: see text]C with 80% deformation achieved the maximum tensile strength but the smallest elongation. The sample, two-step rolled at 900[Formula: see text]C with 40% thickness reduction and then 600[Formula: see text]C with 70% thickness reduction, yielded the satisfactory combination of strength and ductility. The yield strength and elongation were appropriate 767 MPa and 22.8%, respectively, which resulted from the optimized nanocrystalline/microcrystalline structure and distribution.