Consistent Characterization of Color Degradation Due to Artificial Aging Procedures at Popular Pigments of Byzantine Iconography

The degradation effects of artificial aging on the “true” pigment color of Byzantine iconography are thoroughly investigated in this work. For this purpose, a multi-material palette is fabricated, consisting of various popular egg-tempera pigments, while the original recipes from the literature are utilized in order to mimic the genuine art of Byzantine painters. Then, artificial aging procedures are appropriately employed to simulate environmental fluctuations in historical buildings, such as churches. A total of four time steps are investigated, including the initial condition, and pigments’ spectra in the ultraviolet/visible (UV/Vis) area are acquired in the diffuse reflectance mode at each individual step. Moreover, a color characterization procedure is realized via the quantification of lightness and saturation by means of the measured UV/Vis spectrum. The main objectives of this work are to determine the color stability, the type of color degradation, and generally the color response through time of the studied pigments. The extracted results indicate that a couple of pigments suffer severe color degradation while the majority present moderate darkening or discoloration.

Investigating Object Files in Spatial Cueing

In spatial cueing, cues presented at target position (valid condition) can capture visual attention and facilitate responses to the target relative to cues presented away from target position (invalid condition). If cues and targets carry different features, the necessary updating of the object representation from the cue to the target display sometimes counteracts and even reverses facilitation in valid conditions, resulting in an inverted validity effect. Previous studies reached partly divergent conclusions regarding the conditions under which object-file updating occurs, and little is known about the exact nature of the processes involved. Object-file updating has so far been investigated by manipulating cue–target similarities in task-relevant target features, but other features that change between the cue and target displays might also contribute to object-file updating. This study examined the conditions under which object-file updating could counteract validity effects by systematically varying task-relevant (color), response-relevant (identity), and response-irrelevant (orientation) features between cue and target displays. The results illustrate that object-file updating is largely restricted to task-relevant features. In addition, the difficulty of the search task affects the degree to which object-file updating costs interact with spatial cueing.

Precise, sensitive, and reversible thermochromic luminescent sensing facilitated via bright high-temperature luminescent PEAMnBrxI3−x (x = 0/1/2/3)

PEAMnBrxI3−x (x = 0/1/2/3) show a reversible color response to temperature, achieving precise, sensitive and reversible thermochromic temperature sensing.

Colorimetry of Acacia mangium wood from plantations in northeast Brazil

The aim of this study was to evaluate color characteristics in wood samples from Acacia mangium from a homogeneous plantation in Bahia state, northeast Brazil, and also analyze the influence of anatomical section and radial position in the trunk on color response to contribute to information for the best use of the wood, such as, for example, the optimization of the performance of the pieces in sawmill through the most acceptable aesthetic form by the final consumer. Six trees with age of 14 years were cut. The species was identified by anatomical analysis at the Laboratory of Wood Anatomy of the Federal University of Paraná, comparing the sample collected with the authenticated material. A disc from the base of each tree was divided into six samples oriented in anatomical sections (transversal, radial and tangential), with dimensions of 20 × 20 × 30mm, named near pith, intermediate and near bark. A total of 36 samples were evaluated, 12 from each position. The colorimetric evaluation was performed with a CM-5 spectrophotometer. Data on lightness, green-red and blue-yellow chromatic coordinates were obtained, and values of saturation and hue angle were calculated. Acacia wood from planted forest is classified as olive color. Color parameters were influenced by anatomical section and radial position in the trunk, being found 44 for the transversal section, 55 for the tangential section and 57 in the radial for luminosity. Transversal sections had lower values in comparison to longitudinal surfaces and radial sections had higher luminosity than tangential sections. The near bark region presented lower values in most colorimetric parameters, except hue angle, in comparison with the intermediate and near pith regions, which was around 70 in the different positions of the wood.

DNA–Gold Nanozyme-Modified Paper Device for Enhanced Colorimetric Detection of Mercury Ions

In this work, a paper device consisted of a patterned paper chip, wicking pads, and a base was fabricated. On the paper chip, DNA–gold nanoparticles (DNA–AuNPs) were deposited and Hg2+ ions could be adsorbed by the DNA–AuNPs. The formed DNA–AuNP/Hg2+ nanozyme could catalyze the tetramethylbenzidine (TMB)–H2O2 chromogenic reaction. Due to the wicking pads, a larger volume of Hg2+ sample could be applied to the paper device for Hg2+ detection and therefore the color response could be enhanced. The paper device achieved a cut-off value of 50 nM by the naked eye for Hg2+ under optimized conditions. Moreover, quantitative measurements could be implemented by using a desktop scanner and extracting grayscale values. A linear range of 50–2000 nM Hg2+ was obtained with a detection limit of 10 nM. In addition, the paper device could be applied in the detection of environmental water samples with high recoveries ranging from 85.7% to 105.6%. The paper-device-based colorimetric detection was low-cost, simple, and demonstrated high potential in real-sample applications.

A Flavone-Based Solvatochromic Probe with A Low Expected Perturbation Impact on the Membrane Physical State

The study of the cell membrane is an ambitious and arduous objective since its physical state is regulated by a series of processes that guarantee its regular functionality. Among the different methods of analysis, fluorescence spectroscopy is a technique of election, non-invasive, and easy to use. Besides, molecular dynamics analysis (MD) on model membranes provides useful information on the possibility of using a new probe, following its positioning in the membrane, and evaluating the possible perturbation of the double layer. In this work, we report the rational design and the synthesis of a new fluorescent solvatochromic probe and its characterization in model membranes. The probe consists of a fluorescent aromatic nucleus of a 3-hydroxyflavone moiety, provided with a saturated chain of 18 carbon atoms and a zwitterionic head so to facilitate the anchoring to the polar heads of the lipid bilayer and avoid the complete internalization. It was possible to study the behavior of the probe in GUV model membranes by MD analysis and fluorescence microscopy, demonstrating that the new probe can efficiently be incorporated in the lipid bilayer, and give a color response, thanks to is solvatochromic properties. Moreover, MD simulation of the probe in the membrane supports the hypothesis of a reduced perturbation of the membrane physical state.