Experimental study of nonlinear absorption in hyperbolic metamaterials based on ordered arrays of nanorods

Nanophotonics is a rapidly developing branch of physics that studies light interaction with nanoscaled objects such as metamaterials. Hyperbolic metamaterials (HMMs) based on ordered arrays of metal nanorods embedded in a dielectric matrix are of great interest due to their nontrivial optical properties and abilities to control over the parameters of light. In this article, we present the results of nonlinear absorbtion measurements in HMMs based on ordered arrays of silver nanorods. The main finding consists in the spectral vicinity of Epsilon-Near-Zero and Epsilon-Near-Pole features.

Grating Theory Approach to Optics of Nanocomposites

Nanocomposites, i.e., materials comprising nano-sized entities embedded in a host matrix, can have tailored optical properties with applications in diverse fields such as photovoltaics, bio-sensing, and nonlinear optics. Effective medium approaches such as Maxwell-Garnett and Bruggemann theories, which are conventionally used for modeling the optical properties of nanocomposites, have limitations in terms of the shapes, volume fill fractions, sizes, and types of the nanoentities embedded in the host medium. We demonstrate that grating theory, in particular the Fourier Eigenmode Method, offers a viable alternative. The proposed technique based on grating theory presents nanocomposites as periodic structures composed of unit-cells containing a large and random collection of nanoentities. This approach allows us to include the effects of the finite wavelength of light and calculate the nanocomposite characteristics regardless of the morphology and volume fill fraction of the nano-inclusions. We demonstrate the performance of our approach by calculating the birefringence of porous silicon, linear absorption spectra of silver nanospheres arranged on a glass substrate, and nonlinear absorption spectra for a layer of silver nanorods embedded in a host polymer material having Kerr-type nonlinearity. The developed approach can also be applied to quasi-periodic structures with deterministic randomness or metasurfaces containing a large collection of elements with random arrangements inside their unit cells.

The Bio-Persistence of Reversible Inflammatory, Histological Changes and Metabolic Profile Alterations in Rat Livers after Silver/Gold Nanorod Administration

As a widely applied nanomaterial, silver nanomaterials (AgNMs) have increased public concern about their potential adverse biological effects. However, there are few related researches on the long-term toxicity, especially on the reversibility of AgNMs in vivo. In the current study, this issue was tackled by exploring liver damage after an intravenous injection of silver nanorods with golden cores (Au@AgNRs) and its potential recovery in a relatively long term (8 w). After the administration of Au@AgNRs into rats, Ag was found to be rapidly cleared from blood within 10 min and mainly accumulated in liver as well as spleen until 8 w. All detected parameters almost displayed a two-stage response to Au@AgNRs administration, including biological markers, histological changes and metabolic variations. For the short-term (2 w) responses, some toxicological parameters (hematological changes, cytokines, liver damages etc.) significantly changed compared to control and AuNRs group. However, after a 6-week recovery, all abovementioned changes mostly returned to the normal levels in the Au@AgNRs group. These indicated that after a lengthy period, acute bioeffects elicited by AgNMs could be followed by the adaptive recovery, which will provide a novel and valuable toxicity mechanism of AgNMs for potential biomedical applications of AgNMs.

Significantly enhanced coupling effect and gap plasmon resonance in a MIM-cavity based sensing structure

Herein, we design a high sensitivity with a multi-mode plasmonic sensor based on the square ring-shaped resonators containing silver nanorods together with a metal–insulator-metal bus waveguide. The finite element method can analyze the structure's transmittance properties and electromagnetic field distributions in detail. Results show that the coupling effect between the bus waveguide and the side-coupled resonator can enhance by generating gap plasmon resonance among the silver nanorods, increasing the cavity plasmon mode in the resonator. The suggested structure obtained a relatively high sensitivity and acceptable figure of merit and quality factor of about 2473 nm/RIU (refractive index unit), 34.18 1/RIU, and 56.35, respectively. Thus, the plasmonic sensor is ideal for lab-on-chip in gas and biochemical analysis and can significantly enhance the sensitivity by 177% compared to the regular one. Furthermore, the designed structure can apply in nanophotonic devices, and the range of the detected refractive index is suitable for gases and fluids (e.g., gas, isopropanol, optical oil, and glucose solution).

Significantly Enhanced Coupling Effect and Gap Plasmon Resonance in a MIM-cavity based Sensing Structure

Herein, we design a high sensitivity with a multi-mode plasmonic sensor based on the square ring-shaped resonators containing silver nanorods together with a metal-insulator-metal bus waveguide. The finite element method is used to analyze the transmittance properties and electromagnetic field distributions of the structure in detail. Results show that the coupling effect between the bus waveguide and the side-coupled resonator can enhance by generating gap plasmon resonance among the silver nanorods, increasing the cavity plasmon mode in the resonator. The suggested structure obtained relatively high sensitivity and acceptable figure of merit and quality factor of about 2473 nm/RIU (refractive index unit), 34.18 1/RIU and 56.35, respectively. The achieved plasmonic sensor is ideal for lab-on-chip in gas and biochemical analysis and can significantly enhance the sensitivity by 177% compared to the regular one. The designed structure can apply in nanophotonic devices, and the range of the detected refractive index is suitable for gases and fluids (e.g., gas, isopropanol, optical oil and glucose solution).