The social habit of smoking has affected the whole world in a social manner. It is the main cause of diseases like cancers, asthma, bad breath, etc., and a source of spreading of infectious diseases like COVID-19. This work is related to an existing smoking model with relapse habit converted in fractional order. First, formulation of fractional-order smoking model is presented and then the dynamics of proposed problem is analyzed. Fixed-point theory via Banach contraction and Schauder theorems is used to derive the existence and uniqueness of the model. At last, the adaptive predictor–corrector algorithm and Runge–Kutta fourth-order (RK4) strategy are used to perform simulation. To bolster the validity of the theoretical results, a set of numerical simulations are performed. A good agreement between hypothetical and numerical results is demonstrated via numerical simulations using MATLAB software.