Evidence of two-dimensional flat band at the surface of antiferromagnetic kagome metal FeSn

The kagome lattice has long been regarded as a theoretical framework that connects lattice geometry to unusual singularities in electronic structure. Transition metal kagome compounds have been recently identified as a promising material platform to investigate the long-sought electronic flat band. Here we report the signature of a two-dimensional flat band at the surface of antiferromagnetic kagome metal FeSn by means of planar tunneling spectroscopy. Employing a Schottky heterointerface of FeSn and an n-type semiconductor Nb-doped SrTiO3, we observe an anomalous enhancement in tunneling conductance within a finite energy range of FeSn. Our first-principles calculations show this is consistent with a spin-polarized flat band localized at the ferromagnetic kagome layer at the Schottky interface. The spectroscopic capability to characterize the electronic structure of a kagome compound at a thin film heterointerface will provide a unique opportunity to probe flat band induced phenomena in an energy-resolved fashion with simultaneous electrical tuning of its properties. Furthermore, the exotic surface state discussed herein is expected to manifest as peculiar spin-orbit torque signals in heterostructure-based spintronic devices.

RNA X-ray footprinting reveals the consequences of an in vivo acquired determinant of viral infectivity

The secondary structures of the bacteriophage MS2 ssRNA genome, frozen in defined states, were determined with minimal perturbation using constraints from X-ray synchrotron footprinting (XRF). The footprints of the gRNA in the virion and as transcript are consistent with single, dominant but distinct conformations, and reveal the presence of multiple Packaging Signals potentially involved in assembly regulation that have not been detected by other techniques. XRF also reveals the dramatic effect of the unique Maturation Protein (MP) on both the capsid lattice, and the gRNA conformation inside the phage compared with a virus-like-particle composed only of coat protein subunits. Aspects of genome organisation in the phage, their impacts on the capsid shell, and the distortion of lattice geometry by MP, are hallmarks of molecular frustration. Phage assembly therefore appears to prepare the particle for the next step of the infectious cycle.

Supportless printing of lattice structures by metal fused filament fabrication (MF3) of Ti-6Al-4V: design and analysis

Purpose This paper aims to investigate the feasibility of supportless printing of lattice structures by metal fused filament fabrication (MF3) of Ti-6Al-4V. Additionally, an empirical method was presented for the estimation of extrudate deflection in unsupported regions of lattice cells for different geometric configurations. Design/methodology/approach Metal-polymer feedstock with a solids-loading of 59 Vol.% compounded and extruded into a filament was used for three-dimensional printing of lattice structures. A unit cell was used as a starting point, which was then extended to multi-stacked lattice structures. Feasible MF3 processing conditions were identified to fabricate defect-free lattice structures. The effects of lattice geometry parameters on part deflection and relative density were investigated at the unit cell level. Computational simulations were used to predict the part quality and results were verified by experimental printing. Finally, using the identified processing and geometry parameters, multi-stacked lattice structures were successfully printed and sintered. Findings Lattice geometry required considerable changes in MF3 printing parameters as compared to printing bulk parts. Lattice cell dimensions showed a considerable effect on dimensional variations and relative density due to varying aspect ratios. The experimental printing of lattice showed large deflection/sagging in unsupported regions due to gravity, whereas simulation was unable to estimate such deflection. Hence, an analytical model was presented to estimate extrudate deflections and verified with experimental results. Lack of diffusion between beads was observed in the bottom facing surface of unsupported geometry of sintered unit cells as an effect of extrudate sagging in the green part stage. This study proves that MF3 can fabricate fully dense Ti-6Al-4V lattice structures that appear to be a promising candidate for applications where mechanical performance, light-weighting and design customization are required. Originality/value Supportless printing of lattice structures having tiny cross-sectional areas and unsupported geometries is highly challenging for an extrusion-based additive manufacturing (AM) process. This study investigated the AM of Ti-6Al-4V supportless lattice structures using the MF3 process for the first time.

Vital role of magnetocrystalline anisotropy in cubic chiral skyrmion hosts

Magnetic anisotropy is anticipated to govern the formation of exotic spin textures reported recently in cubic chiral magnets, like low-temperature tilted conical and skyrmion lattice (SkL) states and metastable SkLs with various lattice geometry. Motivated by these findings, we quantified the cubic anisotropy in a series of CoZnMn-type cubic chiral magnets. We found that the strength of anisotropy is highly enhanced towards low temperatures. Moreover, not only the magnitude but also the character of cubic anisotropy drastically varies upon changing the Co/Mn ratio. We correlate these changes with temperature- and composition-induced variations of the helical modulation vectors, deformations of skyrmions, structural rearrangements of the metastable SkLs and the large enhancement of Gilbert damping. Similar studies on magnetic anisotropy are required for the quantitative, unified description of the known stable and metastable modulated spin textures and for the systematic exploration of novel ones in this large class of skyrmion hosts.

Mechanism, Thermodynamics and Kinetics of Rutile Leaching Process by Sulfuric Acid Reactions

Rutile decomposition by sulfuric acid, including the formation of two salts, Ti(SO4)2/TiOSO4, is thermodynamically modelled. It is shown that TiO2 can spontaneously dissolve in H2SO4 solutions. However, titania is considered as an inert (ballast) phase component of titanium-containing raw materials due to the decelerated separate nature of such chemical transformations. It is concluded that the hampered related kinetics of dissolution can be attributed to the lability of Ti(IV) cations/the specific engineered features of the hierarchical crystalline structure. It is suggested that the breaking of Ti–O–Ti bonds without additional mechanical strains in crystal lattice geometry becomes more advantageous when smaller negative anions/fluoride ions can be used. The analysis of sulfate-fluoride extraction leaching of titanium confirmed that a decrease in the Gibbs energy in the presence of F occurs. It is indicated by kinetic research studies that the addition of corrosive sodium reagent (NaF) reduces the activation by 45 kJ/mol, which results in intensification. A mechanism is proposed for the interactions involving the Ti–O–Ti cleavage on the surface/the H2SO4-induced Ti dioxide degradation on the sites of defects. Moreover, F acts as a homogeneous/heterogeneous bifunctional catalyst.