Application of environmental magnetism to trace sediment sources contributing to Kruger National Park reservoirs

Sediment source fingerprinting using environmental magnetism has successfully differentiated between sediment sources in different regions of South Africa. The method was applied in the natural landscape of the Kruger National Park to trace sediment sources delivered to four reservoirs (Hartbeesfontein, Marheya, Nhlanganzwani, Silolweni) whose contributing catchments were underlain by a range of igneous, metamorphic, and sedimentary rocks. This research attempted to evaluate the impact of vegetation, lithology, and particle size controls on the ability of magnetic signatures to discriminate between lithology-defined potential sources. Potential source samples were collected from each lithology present in all catchments, except for the Lugmag catchment where the lithology was uniform, but the vegetation type varied significantly between woodland and grassland. One sediment core was taken in each of the four catchment reservoirs where there was more than one lithology present in order to unmix and apportion contributing sediment sources. Sampling time in the field was often restricted to short periods, dependent on anti-poaching activities and movement of free-roaming wildlife across the Park. This occasionally led to the sub-optimal collection of enough source samples to capture source signature variability. Mineral magnetic parameters were unable to discriminate between vegetation-defined sediment sources in the Lugmag catchment (homogenous underlying lithology) but were able to discriminate between lithology-defined sediment sources (to varying degrees) in the other four catchments. The contributions of each lithology-defined sediment source were estimated using a straightforward statistical protocol frequently used in published literature that included a Mann-Whitney U or Kruskal-Wallis H test, mass conservation test, discriminant function analysis, and an (un)mixing model. A contribution from each lithology source to reservoir sediment was estimated. Connectivity was a significant factor in understanding erosion in each of the catchments. Both longitudinal (e.g., drainage density) and lateral connectivity (e.g., floodplain - river) were important. Travel distance of eroded sediment to reservoirs was also an essential element in two of the four catchments. There are no defined floodplains, so channel bank soils are very similar to the catchment soils. Therefore, channel bank storage potential would be similar to the storage potential within the catchment. Vegetation played a crucial role in protecting soils, by reducing ii erosion potential as well as trapping and storing sediment, thereby interrupting lateral connectivity. Underlying geology and soils are determining factors of vegetation type and density. A published study estimated catchment area-specific sediment yields for different KNP catchments, including the Hartbeesfontein, Marheya, Nhlanganzwani and Silolweni catchments. The published data was used in combination with the (un)mixing model source contribution estimates of this thesis to determine specific sediment yields by lithology, i.e., for each catchment source. The polymodal particle size characteristics of the sample material led to an investigation into particle size controls on the ability of magnetic signatures to discriminate between potential sources. Due to time constraints, only the Hartbeesfontein and Marheya catchments were tested for grain size differences. For each catchment, one bulk sample was created for each lithology source. This bulk sample was divided into 10 subsamples. The samples were then fractionated into four particle size fraction groups: coarse (250 – 500 μm), medium (125 – 250 μm), fine (63 – 125 μm), and very fine (<63 μm). Reservoir samples were also bulked to create 10 down-core samples for each reservoir, and the samples were also fractionated into the four fraction groups. The same statistical protocol was applied to the fractionated samples and contribution estimates were obtained by lithology for each particle size fraction group. The goodness of fit and uncertainty of the (un)mixing model varied in each catchment, with the two measures of accuracy often showing an inverse relationship. The fractionated modelling estimated the same primary source in the two catchments as in the unfractionated modelling. However, additional information on the secondary and tertiary sources was obtained. Connectivity remained a significant factor in interpreting the results of the fractionated analysis. Specific sediment yields were estimated for each catchment source per particle size fraction group. These sediment yields provided a deeper understanding of sediment transport through a catchment and which particle size groups are most important in catchment erosion. An original contribution to research was made by estimating source contribution estimates for the four reservoirs, quantifying sediment yields for each catchment lithology and then for each catchment lithology by particle size. Mineral magnetic tracing of the catchments was applied for the first time in this region of South Africa.

The relative contributions of weathering and aeolian inputs to postglacial formation of Mediterranean alpine loess

Between the southern margin of the European loess belt and Sahara Desert, thin and irregularly distributed loess deposits occur in Mediterranean mountains. During the most recent deglaciation, along the Pleistocene-Holocene boundary, the deposition of glacial, periglacial and outwash sediments, was the main local source of Mediterranean alpine loess, whereas proximal alluvial planes comprised a secondary source. The mid-Holocene termination of African Humid Period and subsequent aridification of Sahara Desert occurred simultaneously with a change of the regional climate from Atlantic to Mediterranean-dominated, characterized by frequent episodes of southerly winds. This resulted to a change of the loess source, as deflation of quartz rich silts enriched in Zr during intense episodes of Sahara dust transport became more dominant. Here, a 32cm loess profile from the Plateau of Muses (PM), below the summit of Mount Olympus, Greece, is investigated on the basis of grain size, mineralogy, environmental magnetism and geochemistry. Comparisons of loess samples with glacial and periglacial deposits, enables us to differentiate relative contributions of local sources and allochthonous aeolian inputs. Calcite sand rich in feldspars makes up the glacial and periglacial clast free matrix. In contrast, PM loess is composed by clay and fine silt fractions with minor calcite sand contributions. The mineralogical matrix of loess contains quartz, phyllosilicates and mixed layer clays, while its geochemical composition contains high amounts of detrital Fe-Ti oxides and aeolian transported Al and Zr. Based on the multi-proxy approach applied here, the loess profile is partitioned in three layers. Holocene average deposition rates (~2.5 cm/ka) broadly agree with modern Sahara dust deposition (~2.0 cm/ka) and long-term postglacial Mediterranean mountain denudation rates (~0.5 cm/ka). Such low rates provided ample time for post depositional modifications, such as decalcification, deferrification and removal of K, evident from the trends of chemical weathering proxies Ca/Sr, Fe/Ti and K/Rb, respectively.

Magnetic parameters and palaeoclimate: A case study of loess deposits of North-East of Iran

Environmental magnetism techniques enable us to reconstruct paleoclimate conditions in some deposition such as losses. The magnetic properties of minerals are used as proxies for environmental changes. For this study, loess/paleosol sequence of Kolet section at Neka, north-east of Iran were magnetically investigated. We applied environmental magnetism methods, to reconstruct paleoclimate changes. We investigated relationship between paleoclimate changes and environmental magnetism proxies like magnetic susceptibility (?) variation. The laboratory techniques indicated the presence of main factor of magnetic property in loess/paleosol sequence, such as magnetite, maghemite and etc. We also estimated magnetically parameters (like SIRM, HIRM and etc.) to confirm concentrations of both aeolian and pedogenic particles versus variations of magnetic susceptibility enhancement. The ? values show prominent peaks for the three well developed soil and paleosol horizons, Recent Soil (S0), Upper Paleosol (S1) and Lower Paleosol (S2); which refer to warmer and wetter conditions. As result, we concluded that the increase/decreasing of magnetic susceptibility is coinciding with palaeosol/loess sequence, and probably with humid/arid conditions. Moreover, variations of magnetic susceptibility versus lithological column of Kolet section enabled us to recognize paleoclimatically periods known as interglacial/glacial cycles. The obtained magnetic data indicate that during over the past 50 ka, there have been at least two glacial/interglacial periods and since last 20 ka, there was no main glaciation occurrence, in the study area.

Tracking Airborne Pollution with Environmental Magnetism in A Medium-Sized African City

As in other parts of the world, air pollution over West and Central Africa has major health and meteorological impacts. Air quality assessment and its possible sanitary impact have become essential even in medium-sized towns, therefore amplifying the need for easy-to-implement monitoring methods with low environmental impact. We present here the potential of magnetic methods to monitor air quality at street level in the medium-sized city of Maroua (northern Cameroon) affected by dust-laden desert winds. More than five hundred (544) samples of bark and leaves taken from Neem trees in Maroua were analyzed. Magnetic susceptibility, saturation remanence, and S-ratio were found to determine the concentration and nature of magnetic particles. They are dominated by magnetite-like particle signals as a part of particulate emissions due to urban activities, including both traffic, composed of a substantial proportion of motorcycles, and wood burning for food preparation. We show that both bark and leaves from Neem trees are adequate passive bio-recorders. The use of both enables different times and heights to be sampled, allowing for the high-resolution monitoring, in terms of spatialization, of various urban environments. Particle emissions require assessment and screening that could be carried out rapidly and efficiently by magnetic methods on bio-recorders, even in cities impacted by dust-laden wind.

Quantification of pedogenic particles masked by geogenic magnetic fraction

Pedogenic magnetic fraction in soils is attributed to fine-grained particles, i.e. superparamagnetic grains. In the case of a strongly magnetic geogenic fraction, pedogenic magnetic contribution is hard to detect. To the best of our knowledge, detailed research into the masking of pedogenic superparamagnetic grains and quantification of this effect has not yet been carried out. The principal aim of our research is to quantify the influence of coarse-grained ferrimagnetic fraction on the detection of the superparamagnetic grains. In order to describe the masking phenomenon, volume and frequency-dependent magnetic susceptibility were determined on a set of laboratory prepared samples composed of natural substances: a diamagnetic quartz matrix, detrital coarse-grained ferrimagnetic crystals from alkaline and ultra-alkaline igneous rocks, and superparamagnetic soil concretions formed in the Haplic Cambisol. Mineralogy, concentration, type and grain size of the tested material were described by parameters of environmental magnetism. The magnetic parameters distinguish both geogenic multidomain and pedogenic superparamagnetic grains. The magnetic signal of the superparamagnetic grains is gradually masked by the increasing proportion of multidomain grains of magnetite/maghemite. The experiment clearly describes the masking effect and brings new insight to studies dealing with strongly magnetic soils of natural and/or highly contaminated origin as a tool for estimation of superparamagnetic pedogenic contribution.

Magnetic Mineralogy of Speleothems From Tropical-Subtropical Sites of South America

Fe-bearing minerals are a tiny fraction of the composition of speleothems. They have their origin in the karst system or are transported from the drainage basin into the cave. Recent studies on the magnetism of speleothems focused on the variations of their magnetic mineralogy in specific time intervals and are usually limited to a single sample. In this study, we describe a database of environmental magnetism parameters built from 22 stalagmites from different caves located in Brazil (South America) at different latitudes, comprising different climates and biomes. The magnetic signal observed in these stalagmites is dominated by low-coercivity minerals (∼20 mT) whose magnetic properties resemble those of the magnetite formed in pedogenic environments. Also, a comparison with few samples from soils and the carbonate from cave’s walls shows a good agreement of the magnetic properties of speleothems with those of soil samples, reinforcing previous suggestions that in (sub-)tropical regimes, the dominant magnetic phase in speleothems is associated with the soil above the cave. Spearman’s rank correlation points to a positive strong correlation between magnetic concentration parameters (mass-normalized magnetic susceptibility, natural remanent magnetization, anhysteretic remanent magnetization, and isothermal remanent magnetization). This implies that ultrafine ferrimagnetic minerals are the dominant phase in these (sub-)tropical karst systems, which extend across a diverse range of biomes. Although the samples are concentrated in the savannah biome (Cerrado) (∼70%), comparison with other biomes shows a higher concentration of magnetic minerals in speleothem underlying savannahs and lower concentration in those underlying moist broadleaf forests (Atlantic and Amazon biome) and dry forests (Caatinga). Thus, rainfall, biome, and epikarst dynamics play an important role in the concentration of magnetic minerals in speleothems in (sub-)tropical sites and indicate they can be an important target for paleoenvironmental research in cave systems.

Environmental magnetism study of Lake Cadagno, Switzerland

&lt;p&gt;Climate affects the mineralogy and grain size of sediments deposited in lakes. These properties are reflected in the sediment magnetic properties and can be characterized using magnetic methods. As part of the Cadagno-Project, which recovered several gravity and piston cores spanning the entire lake history from the deglacial to the present from the deepest part of permanently stratified Lake Cadagno, which is due to its peculiar water column chemistry considered an early Earth ocean analogue, our study aims to define changes in climate conditions during sedimentation. Here, we present a rock magnetic dataset (low-field magnetic susceptibility and its temperature dependence, anhysteretic and isothermal remanent magnetization (ARM, IRM), acquired in various fields, AF demagnetization, and hysteresis loops) that helps characterize the concentration, mineralogy, and grain size of magnetic carriers, and their variability with depth. Susceptibility, ARM, and IRM were measured on core sediments down to a depth of 886 cm below the lake bottom, providing a high-resolution record of the sedimentary environment of Lake Cadagno over the last 11,000 years. In addition to these depth profiles, detailed rock magnetic experiments were conducted at specific depths. The cores consist of pelagic sediments, flood turbidites, and late glacial sediments. In order to determine the characteristics of the background sedimentation, only turbidite-free intervals were included in this study. The depth profiles of susceptibility, ARM and IRM have approximately similar variations with depth. They show distinct peaks at the upper parts of the pelagic sediments (156-158 cm below the lake bottom,&amp;#160; &amp;#160;&amp;#820;1280-1320 cal. Yr Bp) and of the late glacial sediments (826-844 cm below the lake bottom), which can be interpreted as increased concentration of ferromagnetic minerals or as a change in the magnetic mineralogy, in addition to decreasing trend in the background. Several intervals within the pelagic sediments are dominated by low-coercivity minerals (&lt;10 mT), while higher coercivity grains (10&amp;#8211;100 mT) contribute significantly at (150-170, 418-448 and 719-735 cm below the lake bottom). Magnetic grain size was analyzed using a Day plot, and shows that single domain magnetite dominates at (844 cm) below the lake bottom, indicating the presence of magnetotactic bacteria, which are believed to dwell mainly in the oxic&amp;#8211;anoxic interface where chemical gradients are high. These results provide important constraints on the environmental conditions and climate change recorded by the magnetic minerals in Lake Cadagno.&lt;/p&gt;