The Cost of Improving the Precision of the Variational Quantum Eigensolver for Quantum Chemistry

New approaches into computational quantum chemistry can be developed through the use of quantum computing. While universal, fault-tolerant quantum computers are still not available, and we want to utilize today’s noisy quantum processors. One of their flagship applications is the variational quantum eigensolver (VQE)—an algorithm for calculating the minimum energy of a physical Hamiltonian. In this study, we investigate how various types of errors affect the VQE and how to efficiently use the available resources to produce precise computational results. We utilize a simulator of a noisy quantum device, an exact statevector simulator, and physical quantum hardware to study the VQE algorithm for molecular hydrogen. We find that the optimal method of running the hybrid classical-quantum optimization is to: (i) allow some noise in intermediate energy evaluations, using fewer shots per step and fewer optimization iterations, but ensure a high final readout precision; (ii) emphasize efficient problem encoding and ansatz parametrization; and (iii) run all experiments within a short time-frame, avoiding parameter drift with time. Nevertheless, current publicly available quantum resources are still very noisy and scarce/expensive, and even when using them efficiently, it is quite difficult to perform trustworthy calculations of molecular energies.

Simulating of X-states and the two-qubit XYZ Heisenberg system on IBM quantum computer

Two qubit density matrices which are of X-shape, are a natural generalization of Bell Diagonal States (BDSs) recently simulated on the IBM quantum device. We generalize the previous results and propose a quantum circuit for simulation of a general two qubit X-state, implement it on the same quantum device, and study its entanglement for several values of the extended parameter space. We also show that their X-shape is approximately robust against noisy quantum gates. To further physically motivate this study, we invoke the two-spin Heisenberg XYZ system and show that for a wide class of initial states, it leads to dynamical density matrices which are X-states. Due to the symmetries of this Hamiltonian, we show that by only two qubits, one can simulate the dynamics of this system on the IBM quantum computer.

Crossed Andreev Reflection in Zigzag Phosphorene Nanoribbon Based Ferromagnet/Superconductor/Ferromagnet Junctions

We study the crossed Andreev reflection in zigzag phosphorene nanoribbon based ferromagnet/superconductor/ferromagnet junction. Only edge states, which are entirely detached from the bulk gap, involved in the transport process. The perfect crossed Andreev reflection, with the maximal nonlocal conductance −2e 2 /h, is addressed by setting the chemical potentials of the leads properly. At this situation, the local Andreev reflection and the electron tunneling are completely eliminated, the incoming electrons can only be reflected as electrons or transmitted as holes, corresponding to the electron reflection and the crossed Andreev reflection respectively. The nonlocal conductance oscillates periodically with the length and the chemical potential of the superconductor. Our study shows that the phosphorene based junction can be used as the quantum device to generate entangled-electrons.

Quantum batteries at the verge of a phase transition

Starting from the observation that the reduced state of a system strongly coupled to a bath is, in general, an athermal state, we introduce and study a cyclic battery-charger quantum device that is in thermal equilibrium, or in a ground state, during the charge storing stage. The cycle has four stages: the equilibrium storage stage is interrupted by disconnecting the battery from the charger, then work is extracted from the battery, and then the battery is reconnected with the charger; finally, the system is brought back to equilibrium. At no point during the cycle are the battery-charger correlations artificially erased. We study the case where the battery and charger together comprise a spin-1/2 Ising chain, and show that the main characteristics - the extracted energy and the thermodynamic efficiency - can be enhanced by operating the cycle close to the quantum phase transition point. When the battery is just a single spin, we find that the output work and efficiency show a scaling behavior at criticality and derive the corresponding critical exponents. Due to always present correlations between the battery and the charger, operations that are equivalent from the perspective of the battery can entail different energetic costs for switching the battery-charger coupling. This happens only when the coupling term does not commute with the battery's bare Hamiltonian, and we use this purely quantum leverage to further optimize the performance of the device.

Geometric measure of entanglement of multi-qubit graph states and its detection on a quantum computer

Multi-qubit graph states generated by the action of controlled phase shift operators on a separable quantum state of a system, in which all the qubits are in arbitrary identical states, are examined. The geometric measure of entanglement of a qubit with other qubits is found for the graph states represented by arbitrary graphs. The entanglement depends on the degree of the vertex representing the qubit, the absolute values of the parameter of the phase shift gate and the parameter of state the gate is acting on. Also the geometric measure of entanglement of the graph states is quantified on the quantum computer ibmq athens. The results obtained on the quantum device are in good agreement with analytical ones.

A Cryptographic Test of Quantumness and Certifiable Randomness from a Single Quantum Device

We consider a new model for the testing of untrusted quantum devices, consisting of a single polynomial time bounded quantum device interacting with a classical polynomial time verifier. In this model, we propose solutions to two tasks—a protocol for efficient classical verification that the untrusted device is “truly quantum” and a protocol for producing certifiable randomness from a single untrusted quantum device. Our solution relies on the existence of a new cryptographic primitive for constraining the power of an untrusted quantum device: post-quantum secure trapdoor claw-free functions that must satisfy an adaptive hardcore bit property. We show how to construct this primitive based on the hardness of the learning with errors (LWE) problem.

Self-testing of a single quantum device under computational assumptions

Self-testing is a method to characterise an arbitrary quantum system based only on its classical input-output correlations, and plays an important role in device-independent quantum information processing as well as quantum complexity theory. Prior works on self-testing require the assumption that the system's state is shared among multiple parties that only perform local measurements and cannot communicate. Here, we replace the setting of multiple non-communicating parties, which is difficult to enforce in practice, by a single computationally bounded party. Specifically, we construct a protocol that allows a classical verifier to robustly certify that a single computationally bounded quantum device must have prepared a Bell pair and performed single-qubit measurements on it, up to a change of basis applied to both the device's state and measurements. This means that under computational assumptions, the verifier is able to certify the presence of entanglement, a property usually closely associated with two separated subsystems, inside a single quantum device. To achieve this, we build on techniques first introduced by Brakerski et al. (2018) and Mahadev (2018) which allow a classical verifier to constrain the actions of a quantum device assuming the device does not break post-quantum cryptography.

Private Weakly-Random Sequences from Human Heart Rate for Quantum Amplification

We investigate whether the heart rate can be treated as a semi-random source with the aim of amplification by quantum devices. We use a semi-random source model called ε-Santha–Vazirani source, which can be amplified via quantum protocols to obtain a fully private random sequence. We analyze time intervals between consecutive heartbeats obtained from Holter electrocardiogram (ECG) recordings of people of different sex and age. We propose several transformations of the original time series into binary sequences. We have performed different statistical randomness tests and estimated quality parameters. We find that the heart can be treated as a good enough, and private by its nature, source of randomness that every human possesses. As such, in principle, it can be used as input to quantum device-independent randomness amplification protocols. The properly interpreted ε parameter can potentially serve as a new characteristic of the human heart from the perspective of medicine.