Triggering and propagation of exogenous sediment pulses in mountain channels: insights from flume experiments with seismic monitoring

In the upper part of mountain river catchments, large amounts of loose debris produced by mass-wasting processes can accumulate at the base of slopes and cliffs. Sudden destabilizations of these deposits are thought to trigger energetic sediment pulses that may travel in downstream rivers with little exchange with the local bed. The dynamics of these exogenous sediment pulses remain poorly known because direct field observations are lacking, and the processes that control their formation and propagation have rarely been explored. Here we carry out flume experiments with the aims of investigating (i) the role of sediment accumulation zones in the generation of sediment pulses, (ii) their propagation dynamics in low-order mountain channels, and (iii) the capability of seismic methods to unravel their physical properties. We use an original setup wherein we supply liquid and solid discharge to a low-slope storage zone acting like a natural sediment accumulation zone that is connected to a downstream 18 % steep channel equipped with geophones. We show that the ability of the self-formed deposit to generate sediment pulses is controlled by the fine fraction of the mixture. In particular, when coarse grains coexist with a high content of finer particles, the storage area experiences alternating phases of aggradation and erosion strongly impacted by grain sorting. The upstream processes also influence the composition of the sediment pulses, which are formed by a front made of the coarsest fraction of the sediment mixture, a body composed of a high concentration of sand corresponding to the peak of solid discharge, and a diluted tail that exhibits a wide grain size distribution. Seismic measurements reveal that the front dominates the overall seismic noise, but we observe a complex dependency between seismic power and sediment pulse transport characteristics, which questions the applicability of existing seismic theories in such a context. These findings challenge the classical approach for which the sediment budget of mountain catchments is merely reduced to an available volume, since not only hydrological but also granular conditions should be considered to predict the occurrence and propagation of such sediment pulses.

Influence of Storage Period on the Geochemical Evolution of a Compressed Energy Storage System

Subsurface porous aquifers are being considered for use as reservoirs for compressed energy storage of renewable energy. In these systems, a gas is injected during times in which production exceeds demand and extracted for energy generation during periods of peak demand or scarcity in production. Current operational subsurface energy facilities use salt caverns for storage and air as the working gas. CO2 is potentially a more favorable choice of working gas where under storage conditions CO2 has high compressibility which can improve operational efficiency. However, the interaction of CO2 and brine at the boundary of the storage zone can produce a chemically active fluid which can result in mineral dissolution and precipitation reactions and alter the properties of the storage zone. This study seeks to understand the geochemical implications of utilization of CO2 as a working gas during injection, storage and extraction flow cycles. Here, reactive transport simulations are developed based on 7 h of injection, 11 h of withdrawal and 6 h of reservoir closure, corresponding to the schedule of the Pittsfield field test, for 15 years of operational life span to assess the geochemical evolution of the reservoir. The evolution in the storage system is compared to a continuously cyclic system of 12 h injection and extraction. The result of the study on operational schedule show that mineral reactivity occurs at the inlet of the domain. Furthermore, the porosity of the inner domain is preserved during the cycling of CO2 acidified brine for both systems.

Clinopyroxene Crystals in Basic Lavas of the Marsili Volcano Chronicle Early Magmatic Stages in a Back-Arc Transcrustal Mush System

Constraining the pre-eruptive processes that modulate the chemical evolution of erupted magmas is a challenge. An opportunity to investigate this issue is offered by the interrogation of the crystals carried in lavas. Here, we employ clinopyroxene crystals from back-arc lavas in order to identify the processes driving basalt to andesite magma evolution within a transcrustal plumbing system. The assembled clinopyroxene archive reveals that mantle melts injected at the crust-mantle transition cool and crystalize, generating a clinopyroxene-dominated mush capped by a melt-rich domain. Magma extracted from this deep storage zone fed the eruption of basalt to basaltic andesite lavas. In addition, chemically evolved melts rapidly rising from this zone briefly stalled at shallow crustal levels, sourcing crystal-poor andesite lavas. Over time, hot ascending primitive magmas intercepted and mixed with shallower cooling magma bodies forming hybrid basic lavas. The blended clinopyroxene cargoes of these lavas provide evidence for the hybridization, which is undetectable from a whole-rock chemical perspective, as mixing involved chemically similar basic magmas. The heterogeneity we found within the clinopyroxene archive is unusual since it provides, for the first time, a complete set of mush-related scenarios by which mantle melts evolve from basalt to andesite compositions. Neither the whole-rock chemistry alone nor the record of the mineral phases crystallizing subsequent to clinopyroxene can provide insights on such early magmatic processes. The obtained clinopyroxene archive can be used as a template for interpretation of the record preserved in the clinopyroxene cargoes of basalt to andesite lavas elsewhere, giving insights into the magma dynamics of the feeding plumbing system that are lost when using whole-rock chemistry.

Macroplastic storage and remobilization in rivers

<p>Processes of macroplastic (plastic particles > 5 mm) storage and remobilization in rivers have been overlooked so far, but are of crucial importance for the estimation of plastic accumulation and transport and associated risks. We present a conceptual model that defines phases of the macroplastic route through a fluvial system and systematizes their main controls. We divided macroplastic route into (1) input, (2) transport, (3) storage, (4) remobilization and (5) output phases. Phase 1 is mainly controlled by humans, phases 2–4 by fluvial processes, and phase 5 by both types of controls. We hypothesize that natural characteristics of fluvial systems and their modification by dam reservoirs and flood embankments construction are key controls on macroplastic storage and remobilization in rivers. The zone of macroplastic storage can be defined as a river floodplain inundated since the beginning of widespread disposal of plastic waste to the environment in the 1960s and the remobilization zone as a part of the storage zone currently influenced by floodwaters and bank erosion. The amount of macroplastic in both zones can be estimated using data on the abundance of surface- and subsurface-stored macroplastic, and the lateral and vertical extent of the zones. A demonstrated diversity of factors controlling the route of macroplastic through a fluvial system requires a broader, transdisciplinary perspective including humans who not only dispose plastic, but are also affected by it both physically and aesthetically, and who may remove it from rivers.</p>

Identification Framework of Contaminant Spill in Rivers Using Machine Learning with Breakthrough Curve Analysis

To minimize the damage from contaminant accidents in rivers, early identification of the contaminant source is crucial. Thus, in this study, a framework combining Machine Learning (ML) and the Transient Storage zone Model (TSM) was developed to predict the spill location and mass of a contaminant source. The TSM model was employed to simulate non-Fickian Breakthrough Curves (BTCs), which entails relevant information of the contaminant source. Then, the ML models were used to identify the BTC features, characterized by 21 variables, to predict the spill location and mass. The proposed framework was applied to the Gam Creek, South Korea, in which two tracer tests were conducted. In this study, six ML methods were applied for the prediction of spill location and mass, while the most relevant BTC features were selected by Recursive Feature Elimination Cross-Validation (RFECV). Model applications to field data showed that the ensemble Decision tree models, Random Forest (RF) and Xgboost (XGB), were the most efficient and feasible in predicting the contaminant source.

Numerical and experimental study of effect of paraffin phase change heat storage capsules on the thermal performance of the solar pond

In this paper, the effect of adding the composite PCM (Phase Change Material) heat storage capsules to the heat storage layer of the salt gradient solar pond on the thermal performance of the solar pond was studied numerically and experimentally. Based on the program-controlled temperature simulation of the solar pond experimental platform, the effect of adding the composite PCM (48–50°C and 58–60°C melting point paraffin) heat storage capsules on the solar pond temperature and stability was studied, and a numerical simulation model was established to be compared by the experimental results. The results showed that the experimental temperature was consistent with the simulation results; the solar pond with PCM capsules had a smaller temperature change range than the conventional solar pond during the phase change process, but it did not have such effect in the non-phase transition process; in terms of flow, the addition of the PCM phase change units could reduce the flow rate of the heat storage zone, and the PCM with a larger latent heat had a more obvious suppression effect on the flow. Therefore, within a certain temperature range, adding PCM units to the solar pond had a positive effect on maintaining the stable temperature and stability of solar pond.

Macroplastic Storage and Remobilization in Rivers

The paper presents a conceptual model of the route of macroplastic debris (>5 mm) through a fluvial system, which can support future works on the overlooked processes of macroplastic storage and remobilization in rivers. We divided the macroplastic route into (1) input, (2) transport, (3) storage, (4) remobilization and (5) output phases. Phase 1 is mainly controlled by humans, phases 2–4 by fluvial processes, and phase 5 by both types of controls. We hypothesize that the natural characteristics of fluvial systems and their modification by dam reservoirs and flood embankments construction are key controls on macroplastic storage and remobilization in rivers. The zone of macroplastic storage can be defined as a river floodplain inundated since the beginning of widespread disposal of plastic waste to the environment in the 1960s and the remobilization zone as a part of the storage zone influenced by floodwaters and bank erosion. The amount of macroplastic in both zones can be estimated using data on the abundance of surface- and subsurface-stored macroplastic and the lateral and vertical extent of the zones. Our model creates the framework for estimation of how much plastic has accumulated in rivers and will be present in future riverscapes.

Macroplastic Storage and Remobilization in Rivers

The paper presents a conceptual model of the route of macroplastic debris (5 > mm) through a fluvial system, which can support future works on the overlooked processes of macroplastic storage and remobilization in rivers. We divided the macroplastic route into (1) input, (2) transport, (3) storage, (4) remobilization and (5) output phases. Phase 1 is mainly controlled by humans, phases 2–4 by fluvial processes, and phase 5 by both types of controls. We hypothesize that natural characteristics of fluvial systems and their modification by dam reservoirs and flood embankments construction are key controls on macroplastic storage and remobilization in rivers. The zone of macroplastic storage can be defined as a river floodplain inundated since the beginning of widespread disposal of plastic waste to the environment in the 1960s and remobilization zone as a part of the storage zone influenced by floodwaters and bank erosion. The amount of macroplastic in both zones can be estimated using data on the abundance of surface- and subsurface-stored macroplastic and the lateral and vertical extent of the zones. Our model creates the framework for estimation of how much plastic has accumulated in rivers and will be present in future riverscapes.

Macroplastic Storage and Remobilization in Rivers

The paper presents a conceptual model of the route of macroplastic debris (5 > mm) through a fluvial system, which can support future works on the overlooked processes of macroplastic storage and remobilization in rivers. We divided the macroplastic route into (1) input, (2) transport (3) storage, (4) remobilization and (5) output phases. Phase 1 is mainly controlled by humans, phases 2–4 by fluvial processes, and phase 5 by both types of controls. We hypothesize that natural characteristics of fluvial systems and their modification by dam reservoirs and flood embankments construction are key controls on macroplastic storage and remobilization in rivers. The zone of macroplastic storage can be defined as a river floodplain inundated since the beginning of widespread disposal of plastic waste to the environment in the 1960s and remobilization zone as a part of the storage zone influenced by floodwaters and bank erosion. The amount of macroplastic in both zones can be estimated using data on the abundance of surface- and subsurface-stored macroplastic and the lateral and vertical extent of the zones. Our model creates the framework for estimation of how much plastic has accumulated in rivers and will be present in future riverscapes.

Changing modes and rates of mafic magma supply at Pantelleria (Sicily Channel, Southern Italy): new perspectives on the volcano factory drawn upon olivine records

The island of Pantelleria, located in the Sicily Channel Rift Zone (Italy), has been the site of violent peralkaline silicic magmatism alternating with minor effusive to low-intensity Strombolian eruptions of basaltic composition. The basaltic rock suites exposed on the island were sampled to investigate the plumbing system dynamics through the study of chemical stratigraphy and temporal records of olivine crystals. Our petrographic and geochemical observations, together with the compositional variability of olivine, suggest different evolutionary histories for basaltic magmas erupted over two major periods divided by the ∼45 ka Green Tuff (GT) eruption. Core-to-rim compositional traverses across olivine crystals document different types of zoning. We recognized olivine zones affected by Fo oscillations at very fine scales in the inner cores, rims and/or in intermediate portions of crystals and used them to reconstruct the residence and passage of crystals through different magmatic environments, with P–T–ƒO2 and compositional characteristics constrained by thermodynamic modeling. The sequence of magmatic environments evidenced by olivine zoning indicate that the pre-GT volcanic period was dominated by injection at shallow crustal levels (∼300–200 MPa) of primitive melts, initially moving from a deep storage zone at the crust-mantle boundary. Supply of this magma significantly decreased after the GT eruption, while the dynamics of magma transfer within the upper portion of the plumbing system were greatly enhanced. The diffusive relaxation of olivine zoning provided the timing of storage and migration of a crystal through different environments. For magmas feeding the ancient (>45 ka) basaltic activity we retrieved transfer histories that are much longer (up to ∼3 years) if compared with those calculated for the post-GT basalts (1–9 months). The compositional and temporal dataset presented in this study supports the idea that the GT eruption and the subsequent collapse of the volcanic edifice could have caused major changes to the internal structural setting of Pantelleria, creating more favorable conditions for the migration of magmas in the upper portions of the plumbing system.