Do coherent structures organize scalar mixing in a turbulent boundary layer?

A scalar emanating from a point source in a turbulent boundary layer does not mix homogeneously, but is organized in large regions with little variation of the concentration: uniform concentration zones. We measure scalar concentration using laser-induced fluorescence and, simultaneously, the three-dimensional velocity field using tomographic particle image velocimetry in a water tunnel boundary layer. We identify uniform concentration zones using both a simple histogram technique, and more advanced cluster analysis. From the complete information on the turbulent velocity field, we compute two candidate velocity structures that may form the boundaries between two uniform concentration zones. One of these structures is related to the rate of point separation along Lagrangian trajectories and the other one involves the magnitude of strong shear in snapshots of the velocity field. Therefore, the first method allows for the history of the flow field to be monitored, while the second method only looks at a snapshot. The separation of fluid parcels in time was measured in two ways: the exponential growth of the separation as time progresses (related to finite-time Lyapunov exponents and unstable manifolds in the theory of dynamical systems), and the exponential growth as time moves backward (stable manifolds). Of these two, a correlation with the edges of uniform concentration zones was found for the past Lyapunov field but not with the time-forward future field. The magnitude of the correlation is comparable to that of the regions of strong shear in the instantaneous velocity field.

Solubilization Behavior of Homopolymer in Its Blend with the Block Copolymer Displaying the Feature of Lower Critical Ordering Transition

Blending with homopolymer offers a facile approach for tuning the microdomain morphology of block copolymer, provided that the homopolymer chains are uniformly solubilized in the corresponding microdomain to swell the junction point separation. Here we studied the solubilization behavior of poly(4-vinyl pyridine) homopolymer (h-P4VP) in the lamellar microdomain formed by its blends with a poly(ethylene oxide)-block-poly(4-vinyl pyridine) (PEO-b-P4VP) showing the feature of lower critical ordering transition (LCOT) in terms of weaker segregation strength at lower temperature. We revealed that, while the conventional criterion of homopolymer-to-block molecular weight ratio for attaining uniform solubilization was applicable to LCOT blend, there was an excess swelling of junction point separation upon the addition of homopolymer, leading to a decrease of interdomain distance with increasing homopolymer composition. This anomalous phenomenon was attributed to the reduction of interfacial free energy due to the incorporation of P4VP homopolymer into the microdomain interface.

Three-dimensional magnetic field structure of a flux-emerging region in the solar atmosphere

We analyze high-resolution spectropolarimetric observations of a flux-emerging region (FER) in order to understand its magnetic and kinematic structure. Our spectropolarimetric observations in the He I 10830 Å spectral region of a FER were recorded with GRIS at the 1.5 m aperture GREGOR telescope. A Milne–Eddington-based inversion code was employed to extract the photospheric information of the Si I spectral line, whereas the He I triplet line was analyzed with the Hazel inversion code, which takes into account the joint action of the Hanle and the Zeeman effects. The spectropolarimetric analysis of the Si I line reveals a complex magnetic structure near the vicinity of the FER, where a weak (350–600 G) and horizontal magnetic field was observed. In contrast to the photosphere, the analysis of the He I triplet presents a smooth variation of the magnetic field vector (ranging from 100 to 400 G) and velocities across the FER. Moreover, we find supersonic downflows of ∼40 km s−1 appearing near the foot points of loops connecting two pores of opposite polarity, whereas strong upflows of 22 km s−1 appear near the apex of the loops. At the location of supersonic downflows in the chromosphere, we observed downflows of 3 km s−1 in the photosphere. Furthermore, nonforce-free field extrapolations were performed separately at two layers in order to understand the magnetic field topology of the FER. We determine, using extrapolations from the photosphere and the observed chromospheric magnetic field, that the average formation height of the He I triplet line is ∼2 Mm from the solar surface. The reconstructed loops using photospheric extrapolations along an arch filament system have a maximum height of ∼10.5 Mm from the solar surface with a foot-point separation of ∼19 Mm, whereas the loops reconstructed using chromospheric extrapolations reach around ∼8.4 Mm above the solar surface with a foot-point separation of ∼16 Mm at the chromospheric height. The magnetic topology in the FER suggests the presence of small-scale loops beneath the large loops. Under suitable conditions, due to magnetic reconnection, these loops can trigger various heating events in the vicinity of the FER.

Numerical analysis of the forward roll coating of a Rabinowitsch fluid

This paper analyses an isothermal roll coating for a Rabinowitsch fluid. Equations of motion are simplified using lubrication approximation theory. Analytical solutions of velocity, flow rate and pressure-gradient are calculated. Outcomes of coating thickness, pressure distribution, split position, stresses, forces, the power input to the roller and the temperature rise between the coating rollers and substrate are obtained. The effects of some involved parameters are displayed through graphs and tables. It is noted that the Rabinowitsch parameter is a controlling quantity for coating thickness, flow rate, separation point, separation force, pressure distribution, and power input. Moreover, an exponential and monotonic change in the above-mentioned engineering parameters is a function of the Rabinowitsch fluid parameter.

Temperature-responsive extraction of violacein using a tuneable anionic surfactant-based system

A tuneable and thermoresponsive ionic system is applied to the extraction and cloud-point separation of violacein from biomass.