A Comparison of Various Correction and Blending Techniques for Creating an Improved Satellite-Gauge Rainfall Dataset over Australia

Satellites offer a way of estimating rainfall away from rain gauges which can be utilised to overcome the limitations imposed by gauge density on traditional rain gauge analyses. In this study, Australian station data along with the Japan Aerospace Exploration Agency’s (JAXA) Global Satellite Mapping of Precipitation (GSMaP) and the Bureau of Meteorology’s (BOM) Australian Gridded Climate Dataset (AGCD) rainfall analysis are combined to develop an improved satellite-gauge rainfall analysis over Australia that uses the strengths of the respective data sources. We investigated a variety of correction and blending methods with the aim of identifying the optimal blended dataset. The correction methods investigated were linear corrections to totals and anomalies, in addition to quantile-to-quantile matching. The blending methods tested used weights based on the error variance to MSWEP (Multi-Source Weighted Ensemble Product), distance to the closest gauge, and the error from a triple collocation analysis to ERA5 and Soil Moisture to Rain. A trade-off between away-from- and at-station performances was found, meaning there was a complementary nature between specific correction and blending methods. The most high-performance dataset was one corrected linearly to totals and subsequently blended to AGCD using an inverse error variance technique. This dataset demonstrated improved accuracy over its previous version, largely rectifying erroneous patches of excessive rainfall. Its modular use of individual datasets leads to potential applicability in other regions of the world.

Quantifying and correcting for pre-assay CO₂ loss in short-term carbon mineralization assays

The active fraction of soil organic carbon is an important component of soil health and often is quickly assessed as the pulse of CO2 released by re-wetting dried soils in short-term (24–72 h) assays. However, soils can lose carbon (C) as they dry and, if soil samples vary in moisture content at sampling, differential C loss during the pre-assay dry-down period may complicate the assay's interpretations. We examined the impact of pre-assay CO2 loss in a long-cultivated agricultural soil at initial moisture contents of 30 %, 50 %, and 70 % water-filled pore space (WFPS). We found that 50 % and 70 % WFPS treatments lost more C during drying than did those in the 30 % WFPS treatment and that dry-down losses led to a 26 %–32 % underestimate of their CO2 pulses. We developed a soil-specific correction factor to account for these initial soil moisture effects. Future C mineralization studies may benefit from similar corrections.

A New Moho Depth Model for Fennoscandia with Special Correction for the Glacial Isostatic Effect

In this study, we present a new Moho depth model in Fennoscandia and its surroundings. The model is tailored from data sets of XGM2019e gravitationl field, Earth2014 topography and seismic crustal model CRUST1.0 using the Vening Meinesz-Moritz model based on isostatic theory to a resolution of 1° × 1°. To that end, the refined Bouguer gravity disturbance is determined by reducing the observed field for gravity effect of topography, density heterogeneities related to bathymetry, ice, sediments, and other crustal components. Moreover, stripping of non-isostatic effects of gravity signals from mass anomalies below the crust due to crustal thickening/thinning, thermal expansion of the mantle, Delayed Glacial Isostatic Adjustment (DGIA), i.e., the effect of future GIA, and plate flexure has also been performed. As Fennoscandia is a key area for GIA research, we particularly investigate the DGIA effect on the gravity disturbance and gravimetric Moho depth determination in this area. One may ask whether the DGIA effect is sufficiently well removed in the application of the general non-isostatic effects in such an area, and to answer this question, the Moho depth is determined both with and without specific removal of the DGIA effect prior to non-isostatic effect and Moho depth determinations. The numerical results yield that the RMS difference of the Moho depth from our model HVMD19 vs. the seismic CRUST19 and GRAD09 models are 3.8/4.2 km and 3.7/4.0 km when the above strategy for removing the DGIA effect is/is not applied, respectively, and the mean value differences are 1.2/1.4 km and 0.98/1.4 km, respectively. Hence, our study shows that the specific correction for the DGIA effect on gravity disturbance is slightly significant, resulting in individual changes in the gravimetric Moho depth up to − 1.3 km towards the seismic results. On the other hand, our study shows large discrepancies between gravimetric and seismic Moho models along the Norwegian coastline, which might be due to uncompensated non-isostatic effects caused by tectonic motions.

Short Communication: Quantifying and Correcting for Pre-Assay CO₂ Loss in Short-Term Carbon Mineralization Assays

The active fraction of soil organic carbon (SOC) is an important component of soil health and often is quickly assessed as the amount of CO2 released by re-wetting dried soils in short-term (24–72 h) assays. However, soils can lose carbon (C) as they dry and if soil samples vary in moisture content at sampling, differential C loss during the pre-assay dry-down period may complicate interpretations of C availability. We examined pre-assay CO2 loss and its influence on apparent C availability in the same soil at initial moisture contents of 30, 50, and 70 % water-filled pore space (WFPS). We found that 50 and 70 % WFPS treatments lost more C during drying than those in the 30 % WFPS treatment, which led to a 26–32 % underestimate of C availability in wetter soil. We developed a soil-specific correction factor to account for these initial soil moisture effects. Future C mineralization studies may benefit from similar corrections.

N₂O isotopocule measurements using laser spectroscopy: analyzer characterization and intercomparison

For the past two decades, the measurement of nitrous oxide (N2O) isotopocules – isotopically substituted molecules 14N15N16O, 15N14N16O and 14N14N18O of the main isotopic species 14N14N16O – has been a promising technique for understanding N2O production and consumption pathways. The coupling of non-cryogenic and tuneable light sources with different detection schemes, such as direct absorption quantum cascade laser absorption spectroscopy (QCLAS), cavity ring-down spectroscopy (CRDS) and off-axis integrated cavity output spectroscopy (OA-ICOS), has enabled the production of commercially available and field-deployable N2O isotopic analyzers. In contrast to traditional isotope-ratio mass spectrometry (IRMS), these instruments are inherently selective for position-specific 15N substitution and provide real-time data, with minimal or no sample pretreatment, which is highly attractive for process studies. Here, we compared the performance of N2O isotope laser spectrometers with the three most common detection schemes: OA-ICOS (N2OIA-30e-EP, ABB – Los Gatos Research Inc.), CRDS (G5131-i, Picarro Inc.) and QCLAS (dual QCLAS and preconcentration, trace gas extractor (TREX)-mini QCLAS, Aerodyne Research Inc.). For each instrument, the precision, drift and repeatability of N2O mole fraction [N2O] and isotope data were tested. The analyzers were then characterized for their dependence on [N2O], gas matrix composition (O2, Ar) and spectral interferences caused by H2O, CO2, CH4 and CO to develop analyzer-specific correction functions. Subsequently, a simulated two-end-member mixing experiment was used to compare the accuracy and repeatability of corrected and calibrated isotope measurements that could be acquired using the different laser spectrometers. Our results show that N2O isotope laser spectrometer performance is governed by an interplay between instrumental precision, drift, matrix effects and spectral interferences. To retrieve compatible and accurate results, it is necessary to include appropriate reference materials following the identical treatment (IT) principle during every measurement. Remaining differences between sample and reference gas compositions have to be corrected by applying analyzer-specific correction algorithms. These matrix and trace gas correction equations vary considerably according to N2O mole fraction, complicating the procedure further. Thus, researchers should strive to minimize differences in composition between sample and reference gases. In closing, we provide a calibration workflow to guide researchers in the operation of N2O isotope laser spectrometers in order to acquire accurate N2O isotope analyses. We anticipate that this workflow will assist in applications where matrix and trace gas compositions vary considerably (e.g., laboratory incubations, N2O liberated from wastewater or groundwater), as well as extend to future analyzer models and instruments focusing on isotopic species of other molecules.

IFCC Working Group Recommendations for Correction of Bias Caused by Noncommutability of a Certified Reference Material Used in the Calibration Hierarchy of an End-User Measurement Procedure

Establishing metrological traceability to an assigned value of a matrix-based certified reference material (CRM) that has been validated to be commutable among available end-user measurement procedures (MPs) is central to producing equivalent results for the measurand in clinical samples (CSs) irrespective of the clinical laboratory MPs used. When a CRM is not commutable with CSs, the bias due to noncommutability will be propagated to the CS results causing incorrect metrological traceability to the CRM and nonequivalent CS results among different MPs. In a commutability assessment, a conclusion that a CRM is commutable or noncommutable for use with a specific MP is made when the difference in bias between the CRM and CSs meets or does not meet a criterion for that specific MP when compared to other MPs. A conclusion regarding commutability or noncommutability requires that the magnitude of the difference in bias observed in the commutability assessment remains unchanged over time. This conclusion requires the CRM to be stable and no substantive changes in the MPs. These conditions should be periodically reverified. If an available CRM is determined to be noncommutable for a specific MP, that CRM can be used in the calibration hierarchy for that MP when an appropriately validated MP-specific correction for the noncommutability bias is included. We describe with examples how a MP-specific correction and its uncertainty can be developed and applied in a calibration hierarchy to achieve metrological traceability of results for CSs to the CRM’s assigned value.

N₂O isotopocule measurements using laser spectroscopy: analyzer characterization and intercomparison

For the past two decades, the measurement of N2O isotopocules – isotopically substituted molecules 14N15N16O, 15N14N16O and 14N14N18O of the main isotopic species 14N14N16O – has been a promising technique for understanding N2O production and consumption pathways. The coupling of non-cryogenic and tuneable light sources with different detection schemes, such as direct absorption quantum cascade laser absorption spectroscopy (QCLAS), cavity ring-down spectroscopy (CRDS) and off-axis integrated cavity output spectroscopy (OA-ICOS), has enabled the production of commercially-available and field-deployable N2O isotopic analyzers. In contrast to traditional isotope-ratio mass-spectrometry (IRMS), these instruments are inherently selective for position-specific 15N substitution and provide real-time data, with minimal or no sample pretreatment, which is highly attractive for process studies. Here, we compared the performance of N2O isotope laser spectrometers with the three most common detection schemes: OA-ICOS (N2OIA-30e-EP, ABB-Los Gatos Research Inc.), CRDS (G5131-i, Picarro Inc.) and QCLAS (dual QCLAS and preconcentration (TREX)–mini QCLAS, Aerodyne Research Inc.). For each instrument, the precision, drift and repeatability of N2O mole fraction [N2O] and isotope data were tested. The analyzers were then characterized for their dependence on [N2O], gas matrix composition (O2, Ar) and spectral interferences caused by H2O, CO2, CH4 and CO to develop analyzer-specific correction functions. Subsequently, a simulated two end-member mixing experiment was used to compare the accuracy and repeatability of corrected and calibrated isotope measurements that could be acquired using the different laser spectrometers. Our results show that N2O isotope laser spectrometer performance is governed by an interplay between instrumental precision, drift, matrix effects and spectral interferences. To retrieve compatible and accurate results, it is necessary to include appropriate reference materials following the identical treatment (IT) principle during every measurement. Remaining differences between sample and reference gas compositions have to be corrected by applying analyzer-specific correction algorithms. These matrix and trace gas correction equations vary considerably according to N2O mole fraction, complicating the procedure further. Thus, researchers should strive to minimize differences in composition between sample and reference gases. In closing, we provide a calibration workflow to guide researchers in the operation of N2O isotope laser spectrometers in order to acquire accurate N2O isotope analyses. We anticipate that this workflow will assist in applications where matrix and trace gas compositions vary considerably (e.g. laboratory incubations, N2O liberated from wastewater or groundwater), as well as extending to future analyzer models and instruments focusing on isotopic species of other molecules.