Suppressing the negative temperature coefficient effect of resistance in polymer composites with positive temperature coefficients of resistance by coating with parylene

Thin parylene coating suppressed the negative temperature coefficient (NTC) effect of polymer thermistors with a positive temperature coefficient (PTC) while maintaining the PTC characteristics.

Heating-induced negative temperature coefficient effect in conductive graphene/polymer ternary nanocomposites with a segregated and double-percolated structure

A NTC effect has been developed upon heating in a ternary graphene/PA6/UHMWPE composite with a segregated and double-percolated structure.

Temperature Sensibility of Epoxy-Matrix Carbon Fiber Smart Layer

The paper deals with the temperature sensitivity of a new type strain sensor named carbon fiber smart layer (CFSL) made of epoxy-matrix composites with short carbon fiber mats. The experiment result indicated that the epoxy matrix CFSL is sensitive to temperature variation. It exhibits NTC effect in -5°C~25°C and exhibits PTC effect in 25°C~50°C. The NTC effect is relatively gentle and the PTC effect is relatively dramatic. The mechanism of both NTC effect and PTC effect is discussed based on the temperature sensitivities of carbon fiber itself and the fiber to fiber interface. Further experiment demonstrated its temperature sensing properties in the temperature scale in which the NTC effect or PTC effect exhibits individually.

Positive temperature coefficient effects of carbon blackfilled polytetrafluoroethylene composites

Carbon black (CB)-filled polytetrafluoroethylene (PTFE) composites were prepared by compact molding of a dry-mixture of CB and polymer powders followed by a sintering technology. The composites show a very low percolation threshold about 5 vol. %, which can be attributed to the segregated distribution of CB in the interfacial regions of PTFE particles. The PTFE/CB composites exhibit a high PTC transition temperature (>300 0C), high PTC intensity (3.5) and no NTC effects. The absence of NTC effect of the composites was attributed to the extremely high viscosity of PTFE at temperatures above its melting point, which restricts the migration of CB particles and prevents the formation of new conductive networks.

Preparation of Ni/BaTiO3 Composites and PTC Effect

Ni/BaTiO3 composite was prepared by decomposition of NiC2O4·2H2O/BaTiO3 precursor, which was prepared by precipitating of nickel in the form of oxalate into the BaTiO3 slurry. The composite must be sintered in reducing atmosphere. Otherwise NTC effect would be introduced. The prepared composite almost had no PTC effect. But PTC effect of the Ni/BaTiO3 composite can be effectively renewed by heat-treatment in air. Under a proper composition and method, the composite shows low room-temperature resistivity (ρRT=6.0 Ω·cm) and obvious PTC effect (ρmax/ρmin=102).