Possible causes of mass transfer acceleration of carbon atoms and alloying elements in the surface layers of steels and alloys under extreme heating, under pulsing laser irradiation in particular, are considered. The research shows that the anomaly accelerated mass transfer, including diffusion in particular, in steels and alloys under fast laser heating has a cooperative character and is a result of a simultaneous action of several processes of different physics. It is proved that the carbon atoms mass transfer parameters and alloying elements depend on the scale and the level of emerging tension, relaxation of which goes along with a local plastic deformation, and occurrence of increased number of linear defects in crystal structure.