Variability and trends in surface solar spectral ultraviolet irradiance in Italy: on the influence of geopotential height and lower-stratospheric ozone

The short- and long-term variability of the surface spectral solar ultraviolet (UV) irradiance is investigated across Italy using high-quality ground-based measurements from three locations: Aosta (45.7∘ N, 7.4∘ E, 570 m a.s.l.), Rome (41.9∘ N, 12.5∘ E, 15 75 m a.s.l.), and Lampedusa (35.5∘ N, 12.6∘ E, 50 m a.s.l.). The three sites are characterized by different environmental conditions and represent almost the full latitudinal extent of the Italian territory. Data of two periods were analysed: 2006–2020 (all sites) and 1996–2020 (Rome only). The main objective of this study is to quantify the effect of the geopotential height (GPH) at 250 hPa on total ozone, and spectral irradiance at 307.5 and 324 nm. We first show that monthly anomalies in GPH, total ozone, and spectral irradiances are correlated amongst the three sites, suggesting that Italy is often affected by the same synoptical weather systems. We further find statistically significant anticorrelations between GPH and monthly anomalies in total ozone for all stations and months. Conversely, we identify positive correlations between GPH and monthly anomalies in spectral irradiance at 307.5 nm for most months. The influence of GPH on short-term variability also hold for long-term trends. For example, long-term changes in total ozone over the period 2006–2020 were associated with changes in GPH for all stations. This suggests that observed negative trends in total ozone were mainly driven by changes in lower-stratospheric ozone as upper-stratospheric ozone was increasing over this period. For several months of the year, positive trends in UV irradiance were observed, and we found that these trends were predominantly caused by changes in clouds and/or aerosols instead of total ozone. For the longer period of 1996–2020, a statistically significant annualized decrease in total ozone of ∼ 0.1 % per year was identified for Rome and could subsequently be attributed to decreasing lower-stratospheric ozone. While positive trends in spectral irradiance at 307.5 nm were observed for several months of this extended period, the negative trend in total ozone did not lead to a positive trend in the spectral irradiance at 307.5 nm in the deseasonalized data. Our study provides evidence that dynamical processes taking place in the troposphere lead to significant variability in total ozone and surface solar UV irradiance.

Variability and trends of the surface solar spectral ultraviolet irradiance in Italy: a possible influence of lower and upper stratospheric ozone trends

In this study the short- and long-term variability of the surface spectral solar ultraviolet (UV) irradiance are investigated over Italy using high quality ground based measurements from three sites located at quite different environmental conditions, and covering the full latitudinal extent of the Italian territory: Aosta (45.7° N, 7.4° E, 570 m a.s.l.), Rome (41.9° N, 12.5° E, 75 m a.s.l.), and Lampedusa (35.5° N, 12.6° E, 50 m a.s.l.). The variability of the irradiances at 307.5 nm, 324 nm, and of the ratio between the 307.5 nm and the 324 nm irradiances were investigated with respect to the corresponding variability in total ozone and the geopotential height at 250 hPa (GPH). The study was performed for two periods: 2006–2020 for all stations, and 1996–2020 only for Rome. A statistically significant correlation between the GPH and total ozone monthly anomalies was found for all stations and all seasons of the year. A corresponding statistically significant correlation was also found in most cases between the GPH and the 307.5 nm irradiance monthly anomalies. The correlation between GPH anomalies at different sites was statistically significant, possibly explaining the strong and significant correlation between the total ozone monthly anomalies at the three sites. A statistically significant decrease of total ozone, of ~0.1 %/year was found for Rome for the period 1996–2020, which however did not induce increasing trends in irradiance at 307.5 nm (neither increasing trends in the ratio between the 307.5 nm and the 324 nm irradiances) at SZA = 67°. Further analyses revealed positive trends in the ratio and the 307.5 nm irradiance at smaller solar zenith angles (SZA), which can be attributed to the fact that total ozone decrease is driven by a decrease in the lower stratosphere while upper stratospheric ozone increases, and the effect of changes of upper stratospheric ozone becoming disproportionately larger for increasing SZA. It was also showed that long-term changes in total ozone follow changes in GPH, which is an additional indication that negative trends in total ozone are mainly driven by changes in lower stratospheric ozone. An anti-correlation between the GPH long-term changes and total ozone was also evident for all stations in 2006–2020. Positive trends in UV irradiance for this latter period which were possibly driven by changes in clouds and/or aerosols were found for Rome and Aosta. This study clearly points out the significance of dynamical processes which take place in the troposphere for the variability of total ozone and surface solar UV irradiance.

Influence of cosmic weather on the Earth’s atmosphere

The review generalizes experimental data on the relationships between the solar activity agents (space weather) and atmosphere constituents. It is shown that high-energy solar protons (SPE) make a powerful impact on photo-chemical processes in the polar areas and, correspondingly, on atmospheric circulation and planetary cloudiness. Variations of the solar UV irradiance modulate the descent rate of the zonal wind in the equatorial stratosphere in the course of quasi-biennial oscillation (QBO), and thus control the total duration (period) of the QBO cycle and, correspondingly, the seasonal ozone depletion in the Antarctic. The geo-effective solar wind impacts on the atmospheric wind system in the entire Southern Polar region, and influences the dynamics of the Southern Oscillation (ENSO).

SOLAR-v: A new solar spectral irradiance dataset based on SOLAR/SOLSPEC observations during solar cycle 24

Context. Solar spectral irradiance (SSI) is the wavelength-dependent energy input to the top of the Earth’s atmosphere. Solar ultraviolet (UV) irradiance represents the primary forcing mechanism for the photochemistry, heating, and dynamics of the Earth’s atmosphere. Hence, both temporal and spectral variations in solar UV irradiance represent crucial inputs to the modeling and understanding of the behavior of the Earth’s atmosphere. Therefore, measuring the long-term solar UV irradiance variations over the 11-year solar activity cycle (and over longer timescales) is fundamental. Thus, each new solar spectral irradiance dataset based on long-term observations represents a major interest and can be used for further investigations of the long-term trend of solar activity and the construction of a homogeneous solar spectral irradiance record. Aims. The main objective of this article is to present a new solar spectral irradiance database (SOLAR-v) with the associated uncertainties. This dataset is based on solar UV irradiance observations (165−300 nm) of the SOLAR/SOLSPEC space-based instrument, which provides measurements of the full-disk SSI during solar cycle 24. Methods. SOLAR/SOLSPEC made solar acquisitions between April 5, 2008 and February 10, 2017. During this period, the instrument was affected by the harsh space environment that introduces instrumental trends (degradation) in the SSI measurements. A new method based on an adaptation of the Multiple Same-Irradiance-Level (MuSIL) technique was used to separate solar variability and any uncorrected instrumental trends in the SOLAR/SOLSPEC UV irradiance measurements. Results. A new method for correcting degradation has been applied to the SOLAR/SOLSPEC UV irradiance records to provide new solar cycle variability results during solar cycle 24. Irradiances are reported at a mean solar distance of 1 astronomical unit (AU). In the 165−242 nm spectral region, the SOLAR/SOLSPEC data agrees with the observations (SORCE/SOLSTICE) and models (SATIRE-S, NRLSSI 2) to within the 1-sigma error envelope. Between 242 and 300 nm, SOLAR/SOLSPEC agrees only with the models.

Solar UV Irradiance in a Changing Climate: Trends in Europe and the Significance of Spectral Monitoring in Italy

Review of the existing bibliography shows that the direction and magnitude of the long-term trends of UV irradiance, and their main drivers, vary significantly throughout Europe. Analysis of total ozone and spectral UV data recorded at four European stations during 1996–2017 reveals that long-term changes in UV are mainly driven by changes in aerosols, cloudiness, and surface albedo, while changes in total ozone play a less significant role. The variability of UV irradiance is large throughout Italy due to the complex topography and large latitudinal extension of the country. Analysis of the spectral UV records of the urban site of Rome, and the alpine site of Aosta reveals that differences between the two sites follow the annual cycle of the differences in cloudiness and surface albedo. Comparisons between the noon UV index measured at the ground at the same stations and the corresponding estimates from the Deutscher Wetterdienst (DWD) forecast model and the ozone monitoring instrument (OMI)/Aura observations reveal differences of up to 6 units between individual measurements, which are likely due to the different spatial resolution of the different datasets, and average differences of 0.5–1 unit, possibly related to the use of climatological surface albedo and aerosol optical properties in the retrieval algorithms.

Solar UV Irradiance in a Changing Climate: Trends in Europe and the Significance of Spectral Monitoring in Italy

Review of the existing bibliography shows that the direction and magnitude of the long-term trends of UV irradiance, and their main drivers, vary significantly throughout Europe. Analysis of total ozone and spectral UV data recorded at four European stations during 1996 – 2017 reveals that long-term changes in UV are mainly driven by changes in aerosols, cloudiness, and surface albedo, while changes in total ozone play a less significant role. The variability of UV irradiance is large throughout Italy due to the complex topography and large latitudinal extension of the country. Analysis of the spectral UV records of the urban site of Rome, and the alpine site of Aosta reveals that differences between the two sites follow the annual cycle of the differences in cloudiness and surface albedo. Comparisons between the noon UV index measured at the ground at the same stations and the corresponding estimates from the DWD forecast model and OMI/Aura observations reveal differences of up to 6 units between individual measurements, which are likely due to the different spatial resolution of the different datasets, and average differences of 0.5 – 1 unit, possibly related to the use of climatological surface albedo and aerosol optical properties in the retrieval algorithms.

UV Monitoring for Public Health

Overexposure to solar ultraviolet (UV) radiation is a risk for public health. Therefore, it is important to provide information to the public about the level of solar UV. The UV-Index (UVI) is the relevant quantity, expressing the erythemally weighted irradiance to a horizontal plane on a simple scale. As solar UV irradiance is strongly variable in time and space, measurements within a network provide the best source of information, provided they can be made available rapidly. However, to ensure the information is reliable, strict quality assurance/quality control (QA/QC) procedures for the monitoring networks are necessary. Near real time presentation of the measured UVI on web-pages is the best way to inform the public. The interpretation of the data in terms of the individual ‘allowable’ exposure time is heavily impacted by skin type, behavior, and clothing, and must be learned for each person through experience and guidance. Nonetheless, reliable knowledge of the actual level of the intensity of erythemally weighted irradiance and its variability forms the basis of education and public awareness. The challenges and requirements in providing comprehensive UVI data for public health guidance are here considered.

EUBREWNET RBCC-E Huelva 2015 Ozone Brewer Intercomparison

From 25 May to 5 June 2015, the 10th regional intercomparison campaign of the Regional Brewer Calibration Center – Europe (RBCC-E) was held at El Arenosillo atmospheric sounding station of the Instituto Nacional de Técnica Aeroespacial (INTA). This campaign was jointly conducted by COST Action ES1207 EUBREWNET and the Area of Instrumentation and Atmospheric Research of INTA. A total of 21 Brewers, 11 single- and 10 double-monochromator instruments from 11 countries participated and were calibrated for total column ozone (TOC) and solar UV irradiance. In this 2015 campaign we have introduced a formal approach to the characterisation of the internal instrumental stray light, the filter non-linearity and the algorithm for correcting for its effects on the TOC calculations. This work shows a general overview of the ozone comparison and the evaluation of the correction of the spectral stray light effect for the single-monochromator Brewer spectrophotometer, derived from the comparison with a reference double-monochromator Brewer instrument. At the beginning of the campaign, 16 out of the 21 participating Brewer instruments agreed within better than ±1 %, and 10 instruments agreed within better than ±0.5 % considering data with ozone slant column between 100 and 900 DU, which does not require instrumental stray light correction.

Dead time effect on the Brewer measurements: correction and estimated uncertainties

Brewer spectrophotometers are widely used instruments which perform spectral measurements of the direct, the scattered and the global solar UV irradiance. By processing these measurements a variety of secondary products can be derived such as the total columns of ozone (TOC), sulfur dioxide and nitrogen dioxide and aerosol optical properties. Estimating and limiting the uncertainties of the final products is of critical importance. High-quality data have a lot of applications and can provide accurate estimations of trends.The dead time is specific for each instrument and improper correction of the raw data for its effect may lead to important errors in the final products. The dead time value may change with time and, with the currently used methodology, it cannot always be determined accurately. For specific cases, such as for low ozone slant columns and high intensities of the direct solar irradiance, the error in the retrieved TOC, due to a 10 ns change in the dead time from its value in use, is found to be up to 5 %. The error in the calculation of UV irradiance can be as high as 12 % near the maximum operational limit of light intensities. While in the existing documentation it is indicated that the dead time effects are important when the error in the used value is greater than 2 ns, we found that for single-monochromator Brewers a 2 ns error in the dead time may lead to errors above the limit of 1 % in the calculation of TOC; thus the tolerance limit should be lowered. A new routine for the determination of the dead time from direct solar irradiance measurements has been created and tested and a validation of the operational algorithm has been performed. Additionally, new methods for the estimation and the validation of the dead time have been developed and are analytically described. Therefore, the present study, in addition to highlighting the importance of the dead time for the processing of Brewer data sets, also provides useful information for their quality control and re-evaluation.

Quality assessment of solar UV irradiance measured with array spectroradiometers

The reliable quantification of ultraviolet (UV) radiation at the earth's surface requires accurate measurements of spectral global solar UV irradiance in order to determine the UV exposure to human skin and to understand long-term trends in this parameter. Array spectroradiometers (ASRMs) are small, light, robust and cost-effective instruments, and are increasingly used for spectral irradiance measurements. Within the European EMRP ENV03 project “Solar UV”, new devices, guidelines and characterization methods have been developed to improve solar UV measurements with ASRMs, and support to the end user community has been provided. In order to assess the quality of 14 end user ASRMs, a solar UV intercomparison was held on the measurement platform of the World Radiation Center (PMOD/WRC) in Davos, Switzerland, from 10 to 17 July 2014. The results of the blind intercomparison revealed that ASRMs, currently used for solar UV measurements, show a large variation in the quality of their solar UV measurements. Most of the instruments overestimate the erythema-weighted UV index – in particular at large solar zenith angles – due to stray light contribution in the UV-B range. The spectral analysis of global solar UV irradiance further supported the finding that the uncertainties in the UV-B range are very large due to stray light contribution in this wavelength range. In summary, the UV index may be detected by some commercially available ASRMs within 5 % compared to the world reference spectroradiometer, if well characterized and calibrated, but only for a limited range of solar zenith angles. Generally, the tested instruments are not yet suitable for solar UV measurements for the entire range between 290 and 400 nm under all atmospheric conditions.