Porous Ceramics Adsorbents Based on Glass Fiber-Reinforced Plastics for NOx and SOx Removal

To reuse waste glass fiber-reinforced plastics (GFRPs), porous ceramics (i.e., GFRP/clay ceramics) were produced by mixing crushed GFRP with clay followed by firing the resulting mixture under different conditions. The possibility of using ceramics fired under a reducing atmosphere as adsorbent materials to remove NOx and SOx from combustion gases of fossil fuels was investigated because of the high porosity, specific surface area, and contents of glass fibers and plastic carbides of the ceramics. NO2 and SO2 adsorption tests were conducted on several types of GFRP/clay ceramic samples, and the gas concentration reduction rates were compared to those of a clay ceramic and a volcanic pumice with high NO2 adsorption. In addition, to clarify the primary factor affecting gas adsorption, adsorption tests were conducted on the glass fibers in the GFRP and GFRP carbides. The reductively fired GFRP/clay ceramics exhibited high adsorption performance for both NO2 and SO2. The primary factor affecting the NO2 adsorption of the ceramics was the plastic carbide content in the clay structure, while that affecting the SO2 adsorption of the ceramics was the glass fiber content.

First-Principles Insight into Pd-Doped C3N Monolayer as a Promising Scavenger for NO, NO2 and SO2

The adsorption and sensing behavior of three typical industrial toxic gases NO, NO2 and SO2 by the Pd modified C3N monolayer were studied in this work on the basic first principles theory. Meanwhile, the feasibility of using the Pd doped C3N monolayer (Pd-C3N) as a sensor and adsorbent for industrial toxic gases was discussed. First, the binding energies of two doping systems were compared when Pd was doped in the N-vacancy and C-vacancy sites of C3N to choose the more stable doping structure. The result shows that the doping system is more stable when Pd is doped in the N-vacancy site. Then, on the basis of the more stable doping model, the adsorption process of NO, NO2 and SO2 by the Pd-C3N monolayer was simulated. Observing the three gases adsorption systems, it can be found that the gas molecules are all deformed, the adsorption energy (Ead) and charge transfer (QT) of three adsorption systems are relatively large, especially in the NO2 adsorption system. This result suggests that the adsorption of the three gases on Pd-C3N belongs to chemisorption. The above conclusions can be further confirmed by subsequent deformable charge density (DCD) and density of state (DOS) analysis. Besides, through analyzing the band structure, the change in electrical conductivity of Pd-C3N after gas adsorption was studied, and the sensing mechanism of the resistive Pd-C3N toxic gas sensor was obtained. The favorable adsorption properties and sensing mechanism indicate that the toxic gas sensor and adsorbent prepared by Pd-C3N have great application potential. Our work may provide some guidance for the application of a new resistive sensor and gas adsorbent Pd-C3N in the field of toxic gas monitoring and adsorption.

Utilization of Mendong Plants-Activated Charcoal as H2S and NO2 Gas Adsorbent: Preliminary Study

The study of exhaust H2S and NO2 gases using activated carbon has been conducted. In this study, activated carbon was prepared from mendong plant (Frimbistylis umbellaris), which was activated using zinc chloride (ZnCl2) with concentrations of 2.5; 5; 7.5; and 10 % w/v to determine the efficiency of H2S adsorption. Mendong charcoal was obtained from the process of using a modified tool. Activation was done by maceration using ZnCl2 activator (w/v) for 24 hours. The adsorption of H2S and NO2 was analyzed using UV-Vis spectrophotometry. Determinations of H2S gas carried out using the blue methylene’s method for 1 hour showed the highest effectiveness of mendong activated carbon was of that at the concentration of 2.5 % ZnCl2 w/v with 80% of H2S removal. Further, the mendong activated carbon with the concentration of 2.5% ZnCl2 w/v was used for NO2 adsorption. The adsorption of NO2 gas was conducted for 1 hour using Griess Saltzman’s method. The result showed that the largest concentration of NO2 gas was adsorbed when the HNO3 concentration was 1.5 M (0.057 µg/mL). The percentage of NO2 efficiency adsorbed was at 28%.

Enhanced NO2-Sensing Properties of Au-Loaded Porous In2O3 Gas Sensors at Low Operating Temperatures

NO2-sensing properties of semiconductor gas sensors using porous In2O3 powders loaded with and without 0.5 wt% Au (Au/In2O3 and In2O3 sensors, respectively) were examined in wet air (70% relative humidity at 25 °C). In addition, the effects of Au loading on the increased NO2 response were discussed on the basis of NO2 adsorption/desorption properties on the oxide surface. The NO2 response of the Au/In2O3 sensor monotonically increased with a decrease in the operating temperature, and the Au/In2O3 sensor showed higher NO2 responses than those of the In2O3 sensor at a temperature of 100 °C or lower. In addition, the response time of the Au/In2O3 sensor was much shorter than that of the In2O3 sensor at 30 °C. The analysis based on the Freundlich adsorption mechanism suggested that the Au loading increased the adsorption strength of NO2 on the In2O3 surface. Moreover, the Au loading was also quite effective in decreasing the baseline resistance of the In2O3 sensor in wet air (i.e., increasing the number of free electrons in the In2O3), which resulted in an increase in the number of negatively charged NO2 species on the In2O3 surface. The Au/In2O3 sensor showed high response to the low concentration of NO2 (ratio of resistance in target gas to that in air: ca. 133 to 0.1 ppm) and excellent NO2 selectivity against CO and ethanol, especially at 100 °C.