scholarly journals Progressive Low-Grade Metamorphism Reconstructed from the Raman Spectroscopy of Carbonaceous Material and an EBSD Analysis of Quartz in the Sanbagawa Metamorphic Event, Central Japan

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 854
Author(s):  
Hidetoshi Hara ◽  
Hiroshi Mori ◽  
Kohei Tominaga ◽  
Yuki Nobe
Keyword(s):  
Raman Spectroscopy ◽  
Carbonaceous Material ◽  
Metamorphic Event ◽  
Ebsd Analysis ◽  
Low Grade ◽  
Accretionary Complex ◽  
Metamorphic Complex ◽  
Central Japan ◽  
Grade Metamorphism ◽  
Quartz Grains

Low-grade metamorphic temperature conditions associated with the Sanbagawa metamorphic event were estimated by the Raman spectroscopy of carbonaceous material (RSCM) in pelitic rocks and an electron backscatter diffraction (EBSD) analysis of the quartz in siliceous rocks. Analytical samples were collected from the Sanbagawa metamorphic complex, the Mikabu greenstones, and the Chichibu accretionary complex in the eastern Kanto Mountains, central Japan. Previously, low-grade Sanbagawa metamorphism was only broadly recognized as pumpellyite–actinolite facies assigned to the chlorite zone. The RSCM results indicate metamorphic temperatures of 358 °C and 368 °C for the chlorite zone and 387 °C for the garnet zone of the Sanbagawa metamorphic complex, 315 °C for the Mikabu greenstones, and 234–266 °C for the Chichibu accretionary complex. From the EBSD analyses, the diameter of the quartz grains calculated by the root mean square (RMS) approximation ranges from 55.9 to 69.0 μm for the Sanbagawa metamorphic complex, 9.5 to 23.5 μm for the Mikabu greenstones, and 2.9 to 7.3 μm for the Chichibu accretionary complex. The opening angles of the c-axis fabric approximate 40–50°, presenting temperatures of 324–393 °C for the Sanbagawa metamorphic complex and the Mikabu greenstones. The temperature conditions show a continuous increase with no apparent gaps from these low-grade metamorphosed rocks. In addition, there exists an empirical exponential relationship between the estimated metamorphic temperatures and the RMS values of the quartz grains. In this study, integrated analyses of multiple rock types provided valuable information on progressive low-grade metamorphism and a similar approach may be applied to study other metamorphic complexes.

scholarly journals Clay diagenesis and low-grade metamorphism of Tithonian and Berriasian sediments in the Cameros Basin (Spain)

Clay Minerals ◽  
2001 ◽  
Vol 36 (3) ◽  
pp. 325-333 ◽  
Author(s):  
J. F. Barrenechea ◽  
M. Rodas ◽  
M. Frey ◽  
J. Alonso-Azcárate ◽  
J. R. Mas
Keyword(s):  
Clay Mineral ◽  
Mixed Layer ◽  
Sedimentary Facies ◽  
Metamorphic Grade ◽  
Metamorphic Event ◽  
Low Grade ◽  
Grade Metamorphism ◽  
Mineral Assemblages ◽  
Cameros Basin ◽  
Southern Border

AbstractThe clay mineral assemblages of the Tithonian and Berriasian sediments (Tera and Oncala Groups) in the eastern part of the Cameros basin are investigated at seven localities. The lowest-grade assemblage, located on the southern border of the basin, contains calcite + quartz + hematite + kaolinite + mixed-layer illite-smectite (R = 1, 65 85% illite layers) + discrete illite (IC = 0.5 0.65Δ°2θ). Systematic increases in the illite and chlorite crystallinities suggest increasing metamorphic grade from the northwest part of the basin to the southeast. This trend does not follow the pattern previously described for the overlying late Berriasian–early Aptian sediments (Urbión and Enciso Groups), which exhibit a higher metamorphic grade. This may result from local variations in sedimentary facies, as well as the circulation of hot migratory fluids. Tertiary compression occurring long after the main metamorphic event is considered to be responsible for the enhanced illite and chlorite crystallinities measured in the SE extreme of the basin.

scholarly journals Isotopic evidence for a Precambrian metamorphic event within the Charcot Land window, East Greenland Caledonian fold belt

1981 ◽  
Vol 29 ◽  
pp. 151-160
Author(s):  
B. T. Hansen ◽  
R. H. Steiger ◽  
A. K. Higgins
Keyword(s):  
Regional Metamorphism ◽  
Metamorphic Event ◽  
Low Grade ◽  
Fold Belt ◽  
Thrust Sheet ◽  
East Greenland ◽  
Grade Metamorphism ◽  
Isotopic Evidence ◽  
Tectonic Window

Rb-Sr, U-Pb and K-Ar analyses on rocks and minerals from a tectonic window below a Caledonian thrust sheet in the westernmost part of the Scoresby Sund region (70°-72°N) give evidence for a Precambrian age of formation. The Charco't Land supracrustal sequence rests on a basement that is probably of Archaean development and older than at least 2100 m.y. The major regional metamorphism of the supracrustal rocks is probably not much older than the intrusion of two post-kinematic bodies, i.e. about 1840 m.y. Low-grade metamorphism in a tillite and low-grade retrogressive overprinting of the supra­crustal rocks are related to Caledonian orogenesis.

Strain localization mechanism of graphitic carbon-bearing rocks: Constraints from microstructure, texture and graphite geothermometry

2021 ◽  
Author(s):  
Meixia Lyu ◽  
Shuyun Cao
Keyword(s):  
Shear Zone ◽  
Strain Localization ◽  
Carbonaceous Material ◽  
Shear Zones ◽  
Graphitic Carbon ◽  
Maximum Temperature ◽  
Low Grade ◽  
High Grade ◽  
Grade Metamorphism ◽  
Average Temperature

<p><strong>Abstracts:</strong></p><p>Graphitic carbon-bearing rocks can occur in low- to high-grade metamorphic units. In low-grade matamorphic rocks, graphitic carbon is often associated with brittle fault gouge whereas in middle- to high-grade metamorphic rocks, graphitic carbon commonly occurs in marble, schist or paragneiss. Previous studies showed that carbonaceous material gradually ordered from the amorphous stage, e.g. graphitization, is mainly controlled by increasing thermal metamorphism and has a good correlation with the metamorphic temperature. Besides, this ordered process is irreversible and the resulting structure is not affected by late metamorphism. Subsequently, the degree of graphitization is believed to be a reliable indicator of peak temperature conditions in the metamorphic rock. In this contribution, based on detailed field observations, the variably deformed and metamorphosed graphitic gneisses to phyllites, located within the footwall and hanging-walls unit of the Cenozoic Ailaoshan-Red River strike-slip shear zone are studied. According to lithological features and temperature determined by Raman spectra of carbonaceous material, these graphitic rocks and deformation fabrics are divided into three types. Type I is represented by medium–grade metamorphism and strongly deformed rocks with an average temperature of 509 °C and a maximum temperature of 604 °C. Type II is affected by low-grade metamorphism and deformed rocks with an average temperature of 420 °C. Type III is affected by lower–grade metamorphism and occurs in weakly deformed/undeformed rocks with an average temperature of 350 °C. Slip–localized micro–shear zone and laterally continuous or discontinuous slip planes constituted by graphitic carbon aggregates are developed in Types I and II. The electron back–scattered diffraction (EBSD) lattice preferred orientation (LPO) patterns of graphitic carbon grains were firstly observed in comparison with LPO patterns of quartz and switch from basal <a>, rhomb <a> to prism <a> slip systems, which indicate increasing deformation temperatures. According to the graphitic slip–planes, micro–shear zones and mylonitic foliation constituted by graphitic carbon minerals, we also propose that the development of fine–grained amorphous carbon plays an important role in rheological weakening of the whole rock during progressive ductile shearing.</p><p><strong>Key Words:</strong> graphitic carbon, strain localization, graphitic thermometry, slip–localized micro–shear zone, rheological weakening</p>

scholarly journals A new approach to develop the R aman carbonaceous material geothermometer for low‐grade metamorphism using peak width

Island Arc ◽  
2013 ◽  
Vol 23 (1) ◽  
pp. 33-50 ◽  
Author(s):  
Yui Kouketsu ◽  
Tomoyuki Mizukami ◽  
Hiroshi Mori ◽  
Shunsuke Endo ◽  
Mutsuki Aoya ◽  
...  
Keyword(s):  
Carbonaceous Material ◽  
Low Grade ◽  
Peak Width ◽  
New Approach ◽  
Grade Metamorphism

Albitized microcline grains of post-depositional and probable detrital origins in Brøttum Formation sandstones (Upper Proterozoic), Sparagmite Region of southern Norway

1988 ◽  
Vol 125 (3) ◽  
pp. 229-239 ◽  
Author(s):  
S. Morad
Keyword(s):  
Carbonaceous Material ◽  
Low Grade ◽  
Grade Metamorphism ◽  
Upper Proterozoic ◽  
Southern Norway

AbstractUntwinned albite (Ab99.4An0.4Or0.2) grains, forming during diagenesis and very low-grade metamorphism, are common in sandstones of the Brøttum Formation (Upper Proterozoic) in the Sparagmite Region of southern Norway. These untwinned albite grains are usually clouded by vacuoles and tiny inclusions which are mostly made of carbonaceous material (although some albite grains also contain some combination of carbonates, quartz, phengite, chlorite, pyrite, halite and anatase). The presence of microcline grains replaced partly by albite indicates that the albite grains are pseudomorphs after microcline. Chessboard albite which occurs in the Brøttum Formation is suggested to be detrital in origin.

scholarly journals Eoalpine (Cretaceous) very low- to low-grade metamorphism recorded on the illite-muscovite-rich fraction of metasediments from South Tisia (eastern Mt Papuk, Croatia)

2010 ◽  
Vol 61 (6) ◽  
pp. 469-481 ◽  
Author(s):  
Vanja Biševac ◽  
Kadosa Balogh ◽  
Dražen Balen ◽  
Darko Tibljaš
Keyword(s):  
Pannonian Basin ◽  
Regional Metamorphism ◽  
Eastern Alps ◽  
Low Grade ◽  
Metamorphic Complex ◽  
Grade Metamorphism ◽  
Sedimentary Sequences ◽  
Surrounding Areas ◽  
Temperature Time ◽  
Good Agreement

Eoalpine (Cretaceous) very low- to low-grade metamorphism recorded on the illite-muscovite-rich fraction of metasediments from South Tisia (eastern Mt Papuk, Croatia)Eoalpine very low- to low-grade metamorphism related to Cretaceous orogenesis has been investigated in the Slavonian Mts, Croatia. Samples belonging to the Psunj metamorphic complex (PMC), the Radlovac metamorphic complex (RMC) and Permian-Triassic and Triassic sedimentary sequences (PTSS) were studied. The Kübler and Árkai indices of all the analysed samples indicate high-anchizonal to epizonal metamorphism. The degree of Eoalpine metamorphism tends to be constant in all samples implying that the different complexes passed through and recorded the same event. Measurements of illite-white K-micab0-parameter of the RMC samples imply transitional low- to medium-pressure character of the metamorphism. These data together with K-Ar ages (~100-80 Ma) measured on illite-white K-mica rich < 2 μm grain-size fractions point to Late Cretaceous very low- to low-grade regional metamorphism presumably related to the main nappe-forming compressional events in the Pannonian Basin and the Carpathians. The P-T-t (pressure-temperature-time) evolution of the studied area is in good agreement with similar scenarios in the surrounding areas of Tisia, but also in Eastern Alps, Carpathians and Pannonian Basin (ALCAPA).

Direct Observation of Crystalline Ordering In Naturally Graphitized Carbon Produced by Low Grade Metamorphism

1977 ◽  
Vol 35 ◽  
pp. 162-163
Author(s):  
Thomas R. McKee ◽  
Peter R. Buseck
Keyword(s):  
Crystallite Size ◽  
Sedimentary Rocks ◽  
Carbonaceous Material ◽  
Low Grade ◽  
X Ray ◽  
Graphitized Carbon ◽  
Transmission Electron ◽  
Heat Treated ◽  
Commercial Carbon ◽  
Metamorphic Zone

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).

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