Seismic anisotropy of Opalinus Clay: tomographic investigations using the infrastructure of an underground rock laboratory (URL)

Seismic anisotropy and attenuation make claystone formations difficult to characterize. On the other hand, in many geotechnical environments, precise knowledge of structure and elastic properties of clay formations is needed. In crystalline and rock salt underground structures, high-resolution seismic tomography and reflection imaging have proven a useful tool for structural and mechanical characterization at the scale of underground infrastructure (several deca- to hundreds of meters). This study investigates the applicability of seismic tomography for the characterization of claystone formations from an underground rock laboratory under challenging on-site conditions including anisotropy, strong attenuation and restricted acquisition geometry. The seismic tomographic survey was part of a pilot experiment in the Opalinus Clay of the Mont Terri Rock Laboratory, using 3-component geophones and rock anchors, which are installed 2 m within the rock on two levels, thus suppressing effects caused by the excavation damage zone. As a source, a pneumatic impact source was used. The survey covers two different facies types (shaly and carbonate-rich sandy), for which the elliptical anisotropy is calculated for direct ray paths by fitting an ellipse to the separated data for each facies. The tomographic inversion was done with a code providing a good grid control and enabling to take the seismic anisotropy into account. A-priori anisotropy can be attributed to the grid points, taking various facies types or other heterogeneities into account. Tomographic results, compared to computations using an isotropic velocity model, show that results are significantly enhanced by considering the anisotropy and demonstrate the ability of the approach to characterize heterogeneities of geological structures between the galleries of the rock laboratory.

Palaeogeography and Palaeoenvironments – A Multifield Examination of the Devonian-Permian Evolution of the Dneipr-Donets Basin

Context is everything. Not all thick sands pay out and not all thin sands are poorly productive. It is important to understand a basin's palaeogeographical drivers, the resultant palaeoenvironments and their constituent sedimentary architecture. Development of a depositional model can be predictive with respect to the magnitude of accessible pore space for potential development. We present a multi-field study of the Dneipr-Donets basin. Over 600 wells were studied with >4500 lithostratigraphical picks being made. Over 7500 sedimentological picks were made allowing mapping of facies bodies and charting shifts in facies types. A facies classification scheme was developed and applied. The Devonian-Permian sedimentary section records the creation, fill, and terminal closure of the Dneipr-Donets Basin:Syn-rift brittle extension (late Frasnian-Famennian): intracratonic rifting between the Ukrainian Shield and Voronezh Massif formed a NW-SE orientated trough, with associated basaltic extrusion. Basin architecture consists of rotated fault blocks forming graben mini-basins. Sedimentation is dominantly upper shoreface but sand packages are poorly correlatable due to the faulted palaeotopography.Early Post-rift thermal subsidence (Visean-Lower Bashkirian): the faulted palaeotopography was filled and thermal subsidence drove basin deepening. Cyclical successions of offshore, lower shoreface and upper shoreface dominate. Sands are typically thin (<10m) but can be widely correlated and have high pore space connectivity.Mid Post-rift: the Bashkirian (C22/C23 boundary), paralic systems prograde over the shoreface. Changes in vertical facies are abrupt due to a low gradient to basin floor. Deltaic and fluvial facies can produce thick amalgamated sands (>30m), but access limited pore space because they are laterally restricted bodies.Terminal post-rift (Mykytivskan): above the lower Permian, the convergence of the Kazahkstanian and Siberian continents began to restrict the Dnieper-Donets basin's access to open ocean. The basin approached full conditions and deposition was dominated by evaporite precipitation, with periodic oceanic recharge. Ultimately, this sediment records the formation of Pangea. The successions examined were used to construct a basinal relative sea level curve, which can be applied elsewhere in the basin. This can be used to help provide palaeogeographical context to a field, which in turn controls the sedimentary architecture.

Composition of Oil after Hydrothermal Treatment of Cabonate-Siliceous and Carbonate Domanic Shale Rocks

The hydrocarbon compositions of shale oils, generated from two different lithological–facial Domanic deposits of the Tatarstan Republic (Russia), were studied under hydrothermal impact with 30% of water addition in a 350 °С and CO2 environment. The samples were extracted from carbonate–siliceous rocks of the Semiluky–Mendym deposits of the Berezovskaya area, and carbonate deposits of the Dankovo–Lebedyan horizon of the Zelenogorskaya area of the Romashkino oil field. The distinctive features of rocks are in the composition and content of organic matter (OM), its thermal stability, as well as the structural-group composition of the shale oil products. The hydrothermal treatment of the rock samples increased the content of saturates and decreased the content of aromatics, resins and asphaltenes in the composition of crude oil. The decomposition of the polymer-like kerogen structure and destruction processes of high-molecular compounds, such as resins and asphaltenes, are accompanied with the formation of substances highly rich in carbons—carbenes and carboids. The contents of n-alkanes and acyclic isoprenoids increase in the composition of saturated hydrocarbons. According to the chemical classification of Al. A. Petrov, the character of the molecular mass distribution of such substances corresponds to oil type A1, which is considered paraffinic. The contents of dibenzothiophene, naphthalene and phenanthrene are increased in the composition of aromatic hydrocarbons, while the contents of tri-methyl-alkyl-benzene and benzothiophene are decreased. The increase in the aryl isoprenoid ratio (AIR = С13–С17/С18–С22) and maturity parameter (4-MDBT/1-MDBT) under the influences of hydrothermal factors indicates the increasing thermal maturity degree of the hydrocarbon system. The differences in the distribution behavior of saturated and aromatic hydrocarbons—biomarkers in rocks of various lithological-facies types, which are reasoned by different conditions of initial organic matter transformation as well as under the impact of hydrothermal factors—were revealed.

Integrated Approach to Geostatistics For Optimal Reservoir Properties Distribution – Case Study of X-Reservoir in Niger Delta Basin

In-depth knowledge of geostatistical analysis, environment of deposition and reservoir facies types is important for optimal distribution of reservoir properties across the reservoir grid. Geostatistics is a veritable tool that is quantitatively used to model spatial continuity, anisotropy direction and capture reservoir heterogeneity for optimal distribution of reservoir properties. When spatial continuity and heterogeneity level of the reservoir are adequately understood and modeled, representative property distribution becomes possible. In the face of limited well data, modeling major and minor directions of horizontal variogram is highly impaired and it becomes difficult to adequately distribute properties within the reservoir grid with enough control. This study is focused on the integration of seismic data, core data, well logs and geological knowledge to carry out geostatistical analysis to optimally distribute facies, porosity and permeability properties within the grid. The degree of reservoir heterogeneity was determined quantitatively using semivariogram and Lorenz plots of core porosity and permeability data. Variogram map generated from seismic attribute was used in combination with the sparse well data points to determine the horizontal variogram. The available well data was adequate enough to model the vertical variogram. The environment of deposition was interpreted as lower to upper shoreface with channel deposits and some shallow marine influence. The properties were normal-scored and modeled with the determined variogram parameters while biasing them with facies. Results of the semivariogram and Lorenz plots showed that the reservoir is fairly heterogenous in terms of spatial continuity. Major direction of the geological continuity is in the Northeast-Southwest direction while the minor direction is orthogonal to it. Final result of the modeled properties was in consonance with the facies types described from the environment of deposition.

Transport Direction and Scandinavian Source Regions of the Saalian Glacial and Glaciofluvial Deposits in a Case Study of Łubienica-Superunki (Central Poland)

The article contains detailed petrographic studies, which covered a coarse and medium-grain gravel fraction of two layers of glacial till (units ŁS II and ŁS IV) and two layers of sand-gravelly outwash deposits (units ŁS I and ŁS III) related to the Odranian Glaciation (MIS6, Saalian) in Łubienica-Superunki, North Mazovian Lowland, central Poland. Additionally, the indicator erratics were identified to indicate their Scandinavian source areas and the directions of the ice sheet transgressions. This case study is discussed against the background of similar sediments and forms from the same age but from other places in the Polish Lowlands. Regardless of the facies types and fractions, crystalline rocks dominated over all other petrographic groups in all samples. The most common were the indicator erratics derived from the Åland Islands, followed by those from the south-eastern area of Sweden (Småland) and from Dalarna in central Sweden. Amongst the erratics of limited indicative significance, the most common were Lower Palaeozoic limestones and the Jotnian red sandstones. The complex petrographic analyses point to the dipartite nature of the studied profile. This separateness was confirmed by the TBC: 59.1–59.2° N and 18.0–18.2° E for the lower units and 58.8–59.4° N and 17.3–17.9° E for the upper ones.

Depositional setting and limiting factors of early Late Cretaceous glaucony formation: implications from Cenomanian glauconitic strata (Elbtal Group, Germany)

Cenomanian strata of the Elbtal Group (Saxony, eastern Germany) reflect a major global sea-level rise and contain, in certain intervals, a green authigenic clay mineral in abundance. Based on the integrated study of five new core sections, the environmental background and spatio-temporal patterns of these glauconitic strata are reconstructed and some general preconditions allegedly needed for glaucony formation are critically questioned. XRD analyses of green grains extracted from selected samples confirm their glauconitic mineralogy. Based on field observations as well as on the careful evaluation of litho- and microfacies, 12 glauconitc facies types (GFTs), broadly reflecting a proximal–distal gradient, have been identified, containing granular and matrix glaucony of exclusively intrasequential origin. When observed in stratigraphic succession, GFT-1 to GFT-12 commonly occur superimposed in transgressive cycles starting with the glauconitic basal conglomerates, followed up-section by glauconitic sandstones, sandy glauconitites, fine-grained, bioturbated, argillaceous and/or marly glauconitic sandstones; glauconitic argillaceous marls, glauconitic marlstones, and glauconitic calcareous nodules continue the retrogradational fining-upward trend. The vertical facies succession with upwards decreasing glaucony content demonstrates that the center of production and deposition of glaucony in the Cenomanian of Saxony was the nearshore zone. This time-transgressive glaucony depocenter tracks the regional onlap patterns of the Elbtal Group, shifting southeastwards during the Cenomanian 2nd-order sea-level rise. The substantial development of glaucony in the thick (60 m) uppermost Cenomanian Pennrich Formation, reflecting a tidal, shallow-marine, nearshore siliciclastic depositional system and temporally corresponding to only ~ 400 kyr, shows that glaucony formation occurred under wet, warm-temperate conditions, high accumulation rates and on rather short-term time scales. Our new integrated data thus indicate that environmental factors such as great water depth, cool temperatures, long time scales, and sediment starvation had no impact on early Late Cretaceous glaucony formation in Saxony, suggesting that the determining factors of ancient glaucony may be fundamentally different from recent conditions and revealing certain limitations of the uniformitarian approach.

Capturing the structural and compositional variability of Opalinus Clay: constraints from multidisciplinary investigations of Mont Terri drill cores (Switzerland)

Opalinus Clay is considered a potential host rock for radioactive waste disposal. The Jurassic claystone formation is composed of several facies and subfacies types, which are characterized by varying amounts of quartz, carbonates (cements and fossils) and clay minerals. To provide samples for ongoing experimental and numerical studies, a complete core section was drilled in the Mont Terri rock laboratory. The lithological and structural variability (including tectonic fault structures) from borehole BAD-2 was investigated using a multidisciplinary approach including high-resolution geoelectric in situ borehole measurements, mineralogical/geochemical and (micro)structural analyses.The lithological–compositional variability was captured by successfully applying a modified subfacies approach, which is independently confirmed by the geochemical data and ERT (Electrical Resistivity Tomography) measurements. The variability on the cm to dm scale perpendicular to bedding can be determined based on the mean resistivity and variation of amplitude. In particular, the facies transitions could be precisely located. The new results suggest that both shaly facies types form the homogenous part of the investigated section, whereas the sandy facies and especially the carbonate-rich sandy facies represent the more heterogeneous lithofacies types of the Opalinus Clay. The varying resistivity can be attributed to differences in clay mineral and carbonate content. Regarding the structural variability, brittle faults were observed with varying frequency throughout the investigated section. Most fault planes occur in the shaly facies types, some of them concentrate along heterogeneities on the subfacies scale. The striking reproducibility of the measurements and observations was confirmed by a comparison with boreholes drilled in parallel, indicating a rather low compositional–structural variability parallel to bedding. The applied multidisciplinary approach is well suited to depict the vertical and lateral variability of a claystone formation, allowing an assessment of the degree of homogeneity/heterogeneity based on the subfacies concept.

Upper Jurassic Bedded Limestones and Early Diagenetic Dolomitized Limestones in the Light of Mineralogical, Geochemical and Sedimentological Studies; Kraków Area, Poland

This paper describes and analyzes the Upper Jurassic (Lower Kimmeridgian) succession exposed in the Zakrzówek Horst, located in the Kraków area. Three distinguished facies types FT 1-FT 3 comprise several limestone varieties: sponge-microbial, pelitic-bioclastic, and partly dolomitized detrital-bioclastic. Their sedimentary environments varied from relatively deeper, attaining storm-wave base, to more shallower, probably close to normal-wave base. Characteristic features of limestones are changes in contents of CaCO3 and insoluble residuum as well as porosity values in vertical transitional zones between facies types. The investigated facies types differ in sediment porosity dependent on development of limestones and its susceptibility to mechanical compaction during the early diagenesis. The studied limestones show high CaCO3 contents and minor insoluble residuum contents comprising quartz, chalcedony and clay minerals. No distinct variability occurs in contents of magnesium, silica, alumina and iron accumulated in clay minerals, iron oxides and oxyhydroxides, as well as in the amounts of amorphous silica. Early diagenetic dolomites, which occur locally within the limestones, were unrelated to fracture systems as possible pathways responsible for transfer of solutions rich in Mg2+ ions. The possible source of Mg2+ ions might have been the pore solutions, which migrated from compacted basinal bedded facies towards reef facies or the grain-supported bedded facies developed in the adjacent areas. Microscopic studies revealed dedolomitization at the surfaces and in the inner parts of dolomite crystals. In many cases, dolomite crystals were replaced by calcite forming pseudomorphs.