Layered Cuprates Containing Flat Fragments: High-Pressure Synthesis, Crystal Structures and Superconducting Properties

High-pressure synthesis and crystal structures of the homologous series AuBa2(Ca,Ln)n−1CunO2n+3 (n = 1–4; Ln = rare-earth cations) are described. Their crystal structures and superconducting properties are compared with the corresponding members of the Hg-homologous series. Numerous cuprates containing flat structural fragments (CuO4, CO3 and BO3) synthesized mainly at high pressure are compared in terms of structural peculiarities and superconducting properties. Importance and future prospects of high-pressure application for the preparation of new superconducting oxides are discussed.

Non-linear Terahertz driving of plasma waves in layered cuprates

The hallmark of superconductivity is the rigidity of the quantum-mechanical phase of electrons, responsible for superfluid behavior and Meissner effect. The strength of the phase stiffness is set by the Josephson coupling, which is strongly anisotropic in layered cuprates. So far, THz light pulses have been used to achieve non-linear control of the out-of-plane Josephson plasma mode, whose frequency lies in the THz range. However, the high-energy in-plane plasma mode has been considered insensitive to THz pumping. Here, we show that THz driving of both low-frequency and high-frequency plasma waves is possible via a general two-plasmon excitation mechanism. The anisotropy of the Josephson couplings leads to markedly different thermal effects for the out-of-plane and in-plane response, linking in both cases the emergence of non-linear photonics across Tc to the superfluid stiffness. Our results show that THz light pulses represent a preferential knob to selectively drive phase excitations in unconventional superconductors.

Calcium-free double-layered cuprate superconductors with critical temperature above 100 K

Calcium is a vital constituent in multilayered cuprate superconductors with critical temperatures (Tc) above 100 K, because it plays a key role in separating CuO2 planes. Here, we demonstrate the synthesis of calcium-free double-layered cuprates: Sr2SrCu2O4(X,O)2(X = F, Cl, and Br) and M(Sr,Ba)2SrCu2Oy(M = Hg/Re, Tl, and B/C), where strontium exists between the CuO2 planes. Oxyfluoride and mercury-based materials show a Tc of 107 K and 110 K, respectively, which are high compared to existing calcium-free cuprates. These findings indicate Tc greater than 100 K can be realized by replacing both barium and calcium, which have been indispensable in conventional multilayered cuprates, with strontium. Furthermore, the non-toxicity of Sr2SrCu2O4F2 and (B,C)Sr2SrCu2Oy simplifies the synthesis process and ensures their safety in potential applications. We also perform a comparison of the characteristic structural parameters between the calcium-free and calcium-containing cuprates considering the number of CuO2 planes.

A Study of Partially Substituted Sr8Ca6Cu24O41 Samples

A systematic study of samples of nominal composition A14Cu24O41 (A = alkaline-earth metal) with partial replacement on the alkaline-earth metal sites and on the Cu sites was carried out. Layered cuprates of the (Sr,Ca)2Cu2O3-CuO2 series with partial substitution by Gd, Dy, and Er for Ca were obtained. X-ray powder diffraction analysis indicated that the solubility of the rare-earth metals in the Sr8Ca6Cu24O41 compound is limited to 2 atoms per formula unit. The Cu atoms in the structure of the spin-ladder phase can be replaced by Fe, Co, or Ni atoms up to the composition Sr8Ca6Cu23Fe1O41, Sr8Ca6Cu18Co6O41, or Sr8Ca6Cu23Ni1O41, respectively, whereas attempts to replace part of the Cu atoms by Mn or Zn atoms were not successful.

Multiple Electronic Components and Lifshitz Transitions by Oxygen Wires Formation in Layered Cuprates and Nickelates

There is growing compelling experimental evidence that a quantum complex matter scenario made of multiple electronic components and competing quantum phases is needed to grab the key physics of high critical temperature ( T c ) superconductivity in layered cuprates. While it is known that defect self-organization controls T c , the mechanism remains an open issue. Here we focus on the theoretical prediction of the multiband electronic structure and the formation of broken Fermi surfaces generated by the self-organization of oxygen interstitials O i atomic wires in the spacer layers in HgBa 2 CuO 4 ± δ , La 2 CuO 4 ± δ and La 2 NiO 4 ± δ , by means of self-consistent Linear Muffin-Tin Orbital (LMTO) calculations. The electronic structure of a first phase of ordered O i atomic wires and of a second glassy phase made of disordered O i impurities have been studied through supercell calculations. We show the common features of the influence of O i wires in the electronic structure in three types of materials. The ordering of O i into wires leads to a separation of the electronic states between the O i ensemble and the rest of the bulk. The wire formation first produces quantum confined localized states near the wire, which coexist with, Second, delocalized states in the Fermi surface (FS) of doped cuprates. A new scenario emerges for high T c superconductivity, where Kitaev wires with Majorana bound states are proximity-coupled to a 2D d-wave superconductor.

Periodically driven adiabatic bipolarons

Small lattice bipolarons driven by external harmonic fields are considered in the adiabatic approximation. Resonant excitation of ions modulates the trapping potential and promotes hole transfer between neighboring atomic layers. It leads to a dramatic decrease of the apparent bipolaron mass compared to the undriven case. This effect offers an explanation for dynamic stabilization of superconductivity at high temperatures recently observed in layered cuprates.