Elastic-viscous properties of acrylic acid 2-propenamide gel

The rheological properties of the gel-like material, the monomer of which is a crosslinked and modified 2-propenamide of acrylic acid, were determined by relaxation rheometry methods. The values of its elastic modulus and modulus of losses and complex viscosity depending on: deforming stress and its frequency are determined; relative deformation; temperature in the range (20-100) ° C and the regularities of these dependences are noted. It is established that: 1) the dependence of the modulus of elasticity (G'); modulus of loss (G'') and complex viscosity from: relative deformation; voltage; temperature; frequencies indicate that in the linear scale they change according to nonlinear dependencies, and in the transition to the logarithmic scale contain plateau-like areas; 2) analytical dependences of the above parameters on stress, strain rate and temperature are complex and difficult to establish; 3) in the range (20-80) ° C and relative deformations (10-100)% hydrogel has a virtually unchanged value of the modulus (G ') ten times greater than the modulus (G' '), whichdetermines the uniqueness of its rheological and biophysical properties ; 4) in the region (20-80) ° C hydrogel in terms of modulus of elasticity and tangent of the angle of loss is close to a completely elastic body; 5) when the frequency of the deforming voltage is more than 15.8 Hz and the relative deformation ≥100%, the gel is brittlely deformed; while the modulus of its elasticity decreases abruptly and the modulus of losses increases rapidly with increasing frequency of the deforming stress. 6) the dependence of the elastic-viscosity characteristics of the samples washed and unwashed in saline gel in the temperature range (20-80) ° C differ little and indicate that the equilibrium structure of the hydrogel 2-propenamide acrylic acid belongs to the typical colloidal dispersed structure of gelatinous substances.

The radiation properties of burning clouds of metal dust. 3. Modification of the emission spectrum

In this work we studied the emission spectra of the combustion products of low-volume dust clouds (V = 5 L) from aluminum (ASD-4), as well as clouds from mixed compositions of aluminum with inorganic powdery oxidizing agents (NaNO3, NaCl, Na2CO3·10H2O, Sr(NO3)2, Ba(NO3)2, KNO3, CuSO4, CuSO4·10H2O) and combustible (B, AlB2, Cu). This article discusses the possibilities of purposeful modification of the emission spectrum of the base composition using various inert and optically active dispersed additives that shift the maximum of the emission spectrum of the fuel composition to the region of longer waves or cause a local change in the emission spectrum in the corresponding spectral regions. In the course of the experiments, it was revealed that the introduction of additives into the basic composition of dispersed fuel does not significantly change the dynamic characteristics of the suspension. However, the additives lead to a decrease in temperature (by about 100–200°K in the presence of an additive up to 25% by weight) and to a corresponding shift in the maximum of the radiation spectrum. The possibility of a significant local modification of the spectrum in the yellow region with the help of inorganic additives to the fuel of sodium salts with a low decomposition temperature (additives Na2CO3·10H2O) was shown experimentally. Boron additives and boron compounds (B, AlB2) leads to a significant increase in the luminosity of the flame in the green region of the spectrum with a maximum radiation in the range Δλ = 530 ÷ 580 nm. The article presents the lighting characteristics (luminous intensity, light sum) of large clouds (V ≥ 10 m3) of mixed compositions based on PAP-2 aluminum powder. It was found that the introduction of inorganic additives to the base fuel does not lead to a noticeable change in the lighting characteristics, but somewhat increases the time of the cloud glow both in the visible and infrared parts of the spectrum.

The elastics – viscosity propertis of printing role offset inks according to relacxation rheometry

Dire relacxation rheometry methods carried out quantitative measurements and established quvalitative patterns of the dependencies of the main elastic-viscous characteristics for the Cybo black ink system in the temperature range of ( 293-333)°K of its technological resistence, namely : the equilibrium elastic modulus and the angle loss modulus and loss angle tangent; complex viscosity and full reological flow curves of the first shear rate and second (viscosity) of the species; degree of destraction of elastic and viscous properties depending on the value: shear stress; shear strain rate ; relative or absolute deformation on the sample and its temperature.

Influence of diffusion and viscosity on the field asymmetry of the effect of gravity in the critical fluid

A brief review of the results of studies of the effect of gravity in inhomogeneous substance near a critical state of a critical fluid (CF) has been presented in paper, based on the data of light scattering, refractometry, and slow neutron transmission methods.Based on these data, the field-altitude asymmetry of various properties of an inhomogeneous substance has been analyzed, namely order parameter Dr(z), scattered light intensity I(z), density gradient dr(z)/dz of the substance. It had been shown that the field-altitude asymmetries of the scattered light intensity I(z)~dr/dm(h) and the density gradient dr(z)/dz~dr/dh(h) of the substance are diametrically opposite. The different altitudinal asymmetry of these quantities dr/dh(h) and dr/dm(h) is explained in paper by the altitude asymmetry of the derivative of the chemical potential dm/dh, and hence with the altitude asymmetry of the chemical potential Dm(h)>>h in the external field h.To the present time, the physical mechanism of the altitude asymmetry of the gravity effect has not been studied. In this regard the mechanism of the formation of the vertical asymmetry of the internal critical field Dm(h) has proposed in paper to be associated with the kinetic characteristics of the inhomogeneous critical fluid: the diffusion coefficients D (h) and viscosity coefficients h(h), when the system passes from a homogeneous state to an inhomogeneous one under the action of an internal asymmetric fields |DU(z)|= |Dm(z)|>>|h=rcgz/Pc|. For this purpose, a high-pressure cell with a height L, with a critical filling density of the substance is considered in paper.It has been shown that when the system is under critical density filling by substance =rc the critical level of substance z = 0 with the critical density rc at the critical temperature Tc is realized above the middle of the sample with an inhomogeneous substance. Based on the literature data of P-V-T-measurements and the gravity effect in benzene and ethane, the values of the altitudinal change in the internal critical field have been found. It has been shown that the value of the critical internal inhomogeneous field in the inhomogeneous critical fluid significantly exceeds the variable of the Earth's gravity |DU(h,Tc)|= |Dm(h,Tc)>>|h| It has been also shown that the magnitude of this field according to the cubic law depends on the critical temperature Tc of the substance: |Dm(z,Tc1)/|Dm(z,Tc2) » (Tc1/Tc2)3.

Ionization equilibrium in a highly imperfect smoke plasma

The ionization equilibrium in a heterogeneous strongly nonideal smoky plasmas containing condensed particles and an easily ionized addition of cesium atoms in the gas phase is considered. To determine the charges of particles, the nonlinear Poisson-Boltzmann equation was used, and for the ionization of atoms of the gas phase, the Saha equation taking into account the effect of the displacement of the ionization equilibrium. The dependences of the concentration of electrons and particle charges, as well as the interface between the regions of positive and negative charges of particles, on the concentration of cesium atoms and the concentration of aluminum oxide particles are obtained.

Fractionation of solid component of welding aerosol

The design of portable filtration device with electrostatic filter and description of its work, which provides the trapping efficiency about 99.5% and fractionation of the polydisperse aerosol to four fractions via particles’ electrical mobility, are presented. The samples of aerosol particles’ fractions are obtained under usual welding regimes by welding wire Св08Г2С in CO2 and their specific surface area, element and phase compositions, phase ratio and crystallite sizes are determined. The correlation between fraction’s element composition and its specific surface area is demonstrated – the iron content is decreased, and manganese and silicon contents are increased when specific surface area is increased. The polyphase content (Fe3O4, FeO, FeMn2O4 и a-Fe are determined) and presence of the monocrystal nanosized magnetite particles, wustite and iron-manganese spinel in the fraction samples are confirmed by the X-ray analysis. The silicon compounds in particles are in amorphous state. The possibility of utilization of the nanostructured aerosol particles are proposed as a result of experimental data analysis.

An experimental investigation of the saturated vapor pressure of solutions proL pane in compressor oils in the presence of fullerene C60 in oil

An investigation of the saturated vapor pressure for the solutions of propane in the two type of industrial compressor oils ProEco®RF22S and RENISO SP46, also as in oil ProEco®RF22S containing fullerene C60 6.837·10-4kg·kg-1is presented in this paper. The measurement of the saturated vapor pressure was conducted using a static method in a temperature range (273…333) K and thepropanemass fraction (0.11…0.595) kg·kg-1. An analysis revealed that the expanded uncertainties of the measured saturated vapor pressure do not exceed 0.0419·105Pafor solutionpropane/ProEco®RF22S,0.0716·105Pa for solution propane /RENISO SP46, and 0.0095·105Pa for solution propane/ProEco®RF22 Scontaining C60.The temperature and concentration dependences of the saturated vapor pressure for the object of study have been discussed. The excess of saturated vapor pressure for the solution of propane in oil ProEco®RF22S over the pressure of the solution of propane in oil RENISO SP46 reaches 1.5 105 Pa at a temperature of 330 K and propane fractionof 0.1 kg·kg-1. This effect decreases with temperature decreasing and propane fraction increasing.It was proven that the additive of the fullerene C60 increase the saturated vapor pressure of the solution propane/ProEco® RF22S up to 0.4·105Pa at low temperature and low propane mass fraction insolution. The results obtained proved the expediency of the introduction in the industry the solution of propane/compressor oil ProEco® RF22Scontaining the fullerene C60 as working fluid of vapor compression refrigeration system. The ability of C60additive in oil to increase the saturated vapor pressure of considered working fluid will contribute to increasing the energy efficiency of refrigeration systems.

Advanced Laser-Photoionization Scheme of Separation of Heavy Isotopes in the Gases Separator Devices

An effective approach to determining the parameters of the optimal schemes of the method of laser selective photoionization of atoms (elements and isotopes) with finite ionization due to collisions, ionization by a pulsed electric field, ionization through high (Rydberg) states and narrow autoionization resonances for the separation of heavy isotopes has been proposed. in gas separator devices. On the basis of the theory of optimal control and previously developed quantum models for calculating the characteristics of elementary atomic processes, optimization models of isotope separation are numerically implemented in the scheme of selective laser photoionization with ionization due to collisions in gas mixtures, ionization by a pulsed electric field, autoionization, etc. etc. The data obtained quantitatively confirm the promise of the method of laser photoionization with finite ionization due to collisions, ionization by a pulsed electric field, ionization through high-lying (Rydberg) states and narrow autoionization resonances and give a set of parameters for the desired optimal schemes, in particular, the laser pulse optimal shape for rubidium and uranium isotopes.

The role of the critical compressibility factor in the equation of state for the critical fluid

Based on the literature data of PVT measurements, the amplitudes of the equations of the critical isotherm D0(Zk), the critical isochore Г0(Zk), the phase boundaries В0(Zk) are expressed in terms of the critical factor of compressibility of the substance Zk=PkVk/RTk in the entire fluctuation region near the critical point. By doing so, a phenomenological method has been used for calculating the values of the critical exponents of the fluctuation theory of phase transitions based on the introduction of small parameters into the equations of the fluctuation theory. It has been shown that, within the limits of the PVT measurement errors, these dependences D0(Zk) and В0(Zk) on the compressibility factor are linear, and Г0 practically does not depend on the compressibility factor Zk. The relationship of these amplitudes with the amplitudes a and k of the linear model of the system of parametric scale equations of state of substance near the critical point has been established. It has been shown that the dependences k(Zk) and а(Zk) are also linear in the entire fluctuation region near the critical point. The obtained dependences k(Zk) and а(Zk) agree with the known relationship between the amplitudes of the critical isotherm D0(Zk), critical isochore Г0(Zk), phase boundaries В0(Zk) Aerospace Institute of the National Academy of Sciences of Ukrainewithin the framework of the system of parametric scaling equations. The relations а(Zk), k(Zk) make it possible, on the basis of a linear model of the system of parametric scale equations of state of substance, to determine such important characteristics of the critical fluid as the temperature and field dependences of the correlation length Rc(T,m) and the fluctuation part of the thermodynamic potential Ф(T,m) in the entire fluctuation region near the critical point. Then, based on the form of the fluctuation part of the thermodynamic potential Ф(T,m)~Rc(T,m)-3, the results obtained allow one to calculate the field and temperature dependences of the thermodynamic quantities for a wide class of molecular liquids in the close vicinity of the critical point (DP<10-3, Dr<10-2, t<10-4), where precision experiments are significantly complicated, and its can also be used when choosing the conditions for the most effective practical application of the unique properties of the critical fluid in the newest technologies.

Radiation protection technologies using granular materials

Technological overcoming of the potential threat of a decrease in the quality of radiation monolithic structures of protective shields, which are under constant influence of ionizing radiation (due to radiation embitterment) is one of the most urgent tasks of ensuring protection against radiation exposure. The aim of the work is to carry out a comparative analysis of the quality (in terms of radiation protection) of monolithic and granular protective screens. In contrast to monolithic prototypes, granular conglomeration has clear advantages, which are to avoid destructive processes of radiation embitterment, simplify replacement and handling (compaction and compaction), and disposal. It is important to emphasize that the protective properties of granular screens hardly differ from their monolithic counterparts, and the economic advantages of the corresponding technologies are significant at the same time. The material provided is actually the formulation of the problem on the theoretical substantiation of the advantages of using granular materials (in comparison with monolithic ones) in radiation protection technologies based on analysis as physical mechanisms and form factors of interaction neutron and gamma radiation with a substance with a developed morphology on a micro-scale.