Full Recovery of Fracture Toughness Using a Nontoxic Solvent‐Based Self‐Healing System

2008 ◽  
Vol 18 (13) ◽  
pp. 1898-1904 ◽  
Author(s):  
Mary M. Caruso ◽  
Benjamin J. Blaiszik ◽  
Scott R. White ◽  
Nancy R. Sottos ◽  
Jeffrey S. Moore
2011 ◽  
Vol 9 (70) ◽  
pp. 1020-1028 ◽  
Author(s):  
A. R. Hamilton ◽  
N. R. Sottos ◽  
S. R. White

An emerging strategy for creating self-healing materials relies on embedded vascular networks of microchannels to transport reactive fluids to regions of damage. Here we investigate the use of active pumping for the pressurized delivery of a two-part healing system, allowing a small vascular system to deliver large volumes of healing agent. Different pumping strategies are explored to improve the mixing and subsequent polymerization of healing agents in the damage zone. Significant improvements in the number of healing cycles and in the overall healing efficiency are achieved compared with prior passive schemes that use only capillary forces for the delivery of healing agents. At the same time, the volume of the vascular system required to achieve this superior healing performance is significantly reduced. In the best case, nearly full recovery of fracture toughness is attained throughout 15 cycles of damage and healing, with a vascular network constituting just 0.1 vol% of the specimen.


Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4139
Author(s):  
Yanju Wang ◽  
Zhiyang Lin ◽  
Can Tang ◽  
Wenfeng Hao

The amounts of the components in a microcapsule self-healing system significantly impact the basic performance and self-healing performance of concrete. In this paper, an orthogonal experimental design is used to investigate the healing performance of microcapsule self-healing concrete under different pre-damage loads. The strength recovery performance and sound speed recovery performance under extensive damage are analyzed. The optimum factor combination of the microcapsule self-healing concrete is obtained. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) are carried out on the concrete samples before and after healing to determine the healing mechanism. The results show that the healing effect of self-healing concrete decreases with an increase in the pre-damage load, and the sound speed recovery rate increases with an increase in the damage degree. The influence of the sodium silicate content on the compressive strength and compressive strength recovery rate of the self-healing concrete increases, followed by a decrease. The optimum combination of factors of the microcapsule self-healing system is 3% microcapsules, 30% sodium silicate, and 15% sodium fluosilicate. The results can be used for the design and preparation of self-healing concrete.


Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 583
Author(s):  
Yangyang Pan ◽  
Bo Liang ◽  
Yaran Niu ◽  
Dijuan Han ◽  
Dongdong Liu ◽  
...  

In this study, a new coating material for thermal barrier coating (TBC) or environment barrier coating (EBC) application, Ca3ZrSi2O9 (CZSO), was synthesized and prepared by atmospheric plasma spray (APS) technology. The evolution of the phases and microstructures of the coatings with different thermal-aged were characterized by XRD, XRF, EDS and SEM, respectively. The thermal stability was measured by TG-DTA and DSC. The mechanical and thermal properties, including Vickers hardness (HV), fracture toughness (KIC), thermal conductivity () and coefficient of thermal expansion (CTE) were focused on. It was found that the as-sprayed CZSO coating contained amorphous phase. Crystalline transformation happened at 900–960 ∘C and no mass changes took place from room temperature (RT) to 1300 ∘C. The phenomena of microcrack self-healing and composition uniformity were observed during thermal aging. The of coating was very low at about 0.57–0.80 Wm−1K−1 in 200–1200 ∘C. The combined properties indicated that the CZSO coating might be a potential T/EBC material.


RSC Advances ◽  
2015 ◽  
Vol 5 (27) ◽  
pp. 21023-21032 ◽  
Author(s):  
Sepideh Khoee ◽  
Zahra Kachoei

Recovery of fracture toughness of a self-healing epoxy adhesive is achieved by using a novel amine nanocontainer.


2021 ◽  
pp. 105678952110112
Author(s):  
Kaihang Han ◽  
Jiann-Wen Woody Ju ◽  
Yinghui Zhu ◽  
Hao Zhang ◽  
Tien-Shu Chang ◽  
...  

The cementitious composites with microencapsulated healing agents have become a class of hotspots in the field of construction materials, and they have very broad application prospects and research values. The in-depth study on multi-scale mechanical behaviors of microencapsulated self-healing cementitious composites is critical to quantitatively account for the mechanical response during the damage-healing process. This paper proposes a three-dimensional evolutionary micromechanical model to quantitatively explain the self-healing effects of microencapsulated healing agents on the damage induced by microcracks. By virtue of the proposed 3 D micromechanical model, the evolutionary domains of microcrack growth (DMG) and corresponding compliances of the initial, extended and repaired phases are obtained. Moreover, the elaborate studies are conducted to inspect the effects of various system parameters involving the healing efficiency, fracture toughness and preloading-induced damage degrees on the compliances and stress-strain relations. The results indicate that relatively significant healing efficiency, preloading-induced damage degree and the fracture toughness of polymerized healing agent with the matrix will lead to a higher compressive strength and stiffness. However, the specimen will break owing to the nucleated microcracks rather than the repaired kinked microcracks. Further, excessive higher values of healing efficiency, preloading-induced damage degree and the fracture toughness of polymerized healing agent with the matrix will not affect the compressive strength of the cementitious composites. Therefore, a stronger matrix is required. To achieve the desired healing effects, the specific parameters of both the matrix and microcapsules should be selected prudently.


Author(s):  
H R Williams ◽  
R S Trask ◽  
I P Bond

Design and certification of novel self-healing aerospace structures was explored by reviewing the suitability of conventional deterministic certification approaches. A sandwich structure with a vascular network self-healing system was used as a case study. A novel probabilistic approach using a Monte Carlo method to generate an overall probability of structural failure yields notable new insights into design of self-healing systems, including a drive for a faster healing time of less than two flight hours. In the case study considered, a mature self-healing system could be expected to reduce the probability of structural failure (compared to a conventional damage-tolerant construction) by almost an order of magnitude. In a risk-based framework this could be traded against simplified maintenance activity (to save cost) and/or increased allowable stress (to allow a lighter structure). The first estimate of the increase in design allowable stresses permitted by a self-healing system is around 8 per cent, with a self-healing system much lighter than previously envisaged. It is thought these methods and conclusions could have wider application to self-healing and conventional high-performance composite structures.


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