Extreme Flexibility in a Zeolitic Imidazolate Framework: Porous to Dense Phase Transition in Desolvated ZIF-4

We present a mean-field theory for the multiphase organization of multi-component biomolecular condensates and validate the theory by molecular dynamics simulations of model mixtures. A first phase transition results in the separation of the dense phase from the bulk phase. In a second phase transition, the components in the dense phase demix to localize in separate regions that attach to each other. The second phase transition occurs when the strength of cross- species attraction goes below the mean strength of the self-attraction of the individual species and reaches a critical value. At a given strength of cross-species attraction, both of the phase transitions can be observed by decreasing temperature, leading first to phase separation and then to demixing of the dense phase. The theory and simulations establish the disparity in strength between self and cross-species attraction as a main driver for the multiphase organization of multi-component biomolecular condensates.

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CFD-DEM study of a spouted bed operating in dense-phase, transition, and jet-spouting regimes

Drying Technology ◽

10.1080/07373937.2021.2009851 ◽

2021 ◽

pp. 1-16

Author(s):

Natalia P. Almeida ◽

Kassia G. Santos ◽

Cláudio R. Duarte ◽

Marcos A. S. Barrozo

Keyword(s):

Phase Transition ◽

Spouted Bed ◽

Dense Phase

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Phase transition of two-dimensionalHe3from a dilute to a dense phase

Physical Review B ◽

10.1103/physrevb.31.2719 ◽

1985 ◽

Vol 31 (5) ◽

pp. 2719-2724 ◽

Cited By ~ 40

Author(s):

Bidyut K. Bhattacharyya ◽

Francis M. Gasparini

Keyword(s):

Phase Transition ◽

Dense Phase

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Convection in a fluid with two phases

Journal of Fluid Mechanics ◽

10.1017/s0022112071000867 ◽

1971 ◽

Vol 46 (4) ◽

pp. 801-812 ◽

Cited By ~ 41

Author(s):

F. H. Busse ◽

G. Schubert

Keyword(s):

Phase Transition ◽

Phase Transitions ◽

Gravitational Instability ◽

Fluid Layer ◽

Dense Phase ◽

Opposite Case ◽

Two Phases ◽

Horizontal Fluid Layer

The gravitational instability of a horizontal fluid layer with a univariant phase transition is considered. It is found that the layer can be unstable even when the less dense phase lies above the dense phase and can be stable in the opposite case. Applications of the theory to convection with phase transitions in astrophysical and geophysical problems are briefly discussed.

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Microstructure of laser-irradiated, conducting Kapton polyimide

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100138889 ◽

1995 ◽

Vol 53 ◽

pp. 502-503

Author(s):

D. L. Callahan ◽

Z. Ball ◽

H. M. Phillips ◽

R. Sauerbrey

Keyword(s):

Electron Microscopy ◽

Phase Transition ◽

Transmission Electron Microscopy ◽

Cross Section ◽

Film Surface ◽

Cross Sectional ◽

General Utility ◽

Transmission Electron ◽

Considerable Debate ◽

Potential Applications

Ultraviolet laser-irradiation can be used to induce an insulator-to-conductor phase transition on the surface of Kapton polyimide. Such structures have potential applications as resistors or conductors for VLSI applications as well as general utility electrodes. Although the percolative nature of the phase transformation has been well-established, there has been little definitive work on the mechanism or extent of transformation. In particular, there has been considerable debate about whether or not the transition is primarily photothermal in nature, as we propose, or photochemical. In this study, cross-sectional optical microscopy and transmission electron microscopy are utilized to characterize the nature of microstructural changes associated with the laser-induced pyrolysis of polyimide.Laser-modified polyimide samples initially 12 μm thick were prepared in cross-section by standard ultramicrotomy. Resulting contraction in parallel to the film surface has led to distortions in apparent magnification. The scale bars shown are calibrated for the direction normal to the film surface only.

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The structure of membranes and membrane proteins embedded in amorphous ice

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100122563 ◽

1992 ◽

Vol 50 (1) ◽

pp. 432-433

Author(s):

Uwe Lücken ◽

Joachim Jäger

Keyword(s):

Phase Transition ◽

Transition Temperature ◽

Membrane Proteins ◽

Phase Transition Temperature ◽

Lipid Vesicles ◽

Freezing Stress ◽

Amorphous Ice ◽

Different Temperatures ◽

Band Pass ◽

Lipid Polymorphism

TEM imaging of frozen-hydrated lipid vesicles has been done by several groups Thermotrophic and lyotrophic polymorphism has been reported. By using image processing, computer simulation and tilt experiments, we tried to learn about the influence of freezing-stress and defocus artifacts on the lipid polymorphism and fine structure of the bilayer profile. We show integrated membrane proteins do modulate the bilayer structure and the morphology of the vesicles.Phase transitions of DMPC vesicles were visualized after freezing under equilibrium conditions at different temperatures in a controlled-environment vitrification system. Below the main phase transition temperature of 24°C (Fig. 1), vesicles show a facetted appearance due to the quasicrystalline areas. A gradual increase in temperature leads to melting processes with different morphology in the bilayer profile. Far above the phase transition temperature the bilayer profile is still present. In the band-pass-filtered images (Fig. 2) no significant change in the width of the bilayer profile is visible.

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