Synthesis and Physicochemical Properties of Low Viscosity 2‐Ethylhexyl Alkyl Ethers Made from Palm‐based Esters as Potential Biolubricant

2021 ◽  
pp. 2100072
Author(s):  
Sook Wah Tang ◽  
Chung‐Hung Chan ◽  
Noor Khairin Mohd ◽  
Wen Huei Lim ◽  
Seng Soi Hoong ◽  
...  
Keyword(s):  
Physicochemical Properties ◽  
Low Viscosity ◽  
Alkyl Ethers

scholarly journals A Mesoproterozoic continental flood rhyolite province, the Gawler Ranges, Australia: the end member example of the Large Igneous Province clan

Solid Earth ◽  
2011 ◽  
Vol 2 (1) ◽  
pp. 25-33 ◽  
Author(s):  
M. J. Pankhurst ◽  
B. F. Schaefer ◽  
P. G. Betts ◽  
N. Phillips ◽  
M. Hand
Keyword(s):  
Physicochemical Properties ◽  
Large Scale ◽  
South Australia ◽  
Large Igneous Province ◽  
Melt Viscosity ◽  
Volcanic Province ◽  
Low Viscosity ◽  
Geophysical Interpretation ◽  
The Family ◽  
Igneous Province

Abstract. Rhyolite and dacite lavas of the Mesoproterozoic upper Gawler Range Volcanics (GRV) (>30 000 km3 preserved), South Australia, represent the remnants of one of the most voluminous felsic magmatic events preserved on Earth. Geophysical interpretation suggests eruption from a central cluster of feeder vents which supplied large-scale lobate flows >100 km in length. Pigeonite inversion thermometers indicate eruption temperatures of 950–1100 °C. The lavas are A-type in composition (e.g. high Ga/Al ratios) and characterised by elevated primary halogen concentrations (~1600 ppm fluorine, ~400 ppm chlorine). These depolymerised the magma such that temperature-composition-volatile non-Arrhenian melt viscosity modelling suggests they had viscosities of <3.5 log η (Pa s). These physicochemical properties have led to the emplacement of a Large Rhyolite Province, which has affinities in emplacement style to Large Basaltic Provinces. The low viscosity of these felsic magmas has produced a unique igneous system on a scale which is either not present or poorly preserved elsewhere on the planet. The Gawler Range Volcanic Province represents the erupted portion of the felsic end member of the family of voluminous, rapidly emplaced terrestrial magmatic provinces.

scholarly journals A mesoproterozoic continental flood rhyolite province, the Gawler Ranges, Australia: the end member example of the Large Igneous Province clan

2010 ◽  
Vol 2 (2) ◽  
pp. 251-274 ◽  
Author(s):  
M. J. Pankhurst ◽  
B. F. Schaefer ◽  
P. G. Betts ◽  
N. Phillips ◽  
M. Hand
Keyword(s):  
Physicochemical Properties ◽  
Large Scale ◽  
South Australia ◽  
Large Igneous Province ◽  
Melt Viscosity ◽  
Volcanic Province ◽  
Low Viscosity ◽  
Geophysical Interpretation ◽  
The Family ◽  
Igneous Province

Abstract. Rhyolite and dacite lavas of the Mesoproterozoic upper Gawler Range Volcanics (GRV) (>30 000 km3 preserved), South Australia, represent the remnants of one of the most voluminous felsic magmatic events preserved on Earth. Geophysical interpretation suggests eruption from a central cluster of feeder vents which supplied large-scale lobate flows >100 km in length. Pigeonite inversion thermometers indicate eruption temperatures of 950–1100 °C. The lavas are A-type in composition (e.g. high Ga/Al ratios) and characterised by elevated primary halogen concentrations (~1600 ppm Fluorine, ~400 ppm Chlorine). These depolymerised the magma such that temperature-composition-volatile non-Arrhenian melt viscosity modelling suggests they had viscosities of <3.5 log η (Pa s). These physicochemical properties have led to the emplacement of a Large Rhyolite Province, which has affinities in emplacement style to Large Basaltic Provinces. The low viscosity of these felsic magmas has produced a unique igneous system on a scale which is either not present or poorly preserved elsewhere on the planet. The Gawler Range Volcanic Province represents the erupted portion of the felsic end member of the family of voluminous, rapidly emplaced terrestrial magmatic provinces.

Preparation and physicochemical properties of F-tert-butyl alkyl ethers

1998 ◽  
Vol 92 (2) ◽  
pp. 167-171 ◽  
Author(s):  
Naoto Takada ◽  
Takashi Abe ◽  
Akira Sekiya
Keyword(s):  
Physicochemical Properties ◽  
Tert Butyl ◽  
Alkyl Ethers

Decylglucoside Microemulsion Systems Containing Coenzyme Q10: Formulation, Physicochemical Characterization and Stability

2014 ◽  
Vol 1060 ◽  
pp. 70-73
Author(s):  
Natthida Pakpayat ◽  
Prapaporn Boonme
Keyword(s):  
Liquid Crystals ◽  
Physicochemical Properties ◽  
Coenzyme Q10 ◽  
Physicochemical Characterization ◽  
Stability Study ◽  
Stability Test ◽  
Newtonian Flow ◽  
Freeze Thaw ◽  
Low Viscosity ◽  
Alkyl Polyglycosides

This study aimed to develop green microemulsions (MEs) for loading coenzyme Q10 (CoQ10). Decylglucoside, a surfactant in the group of alkyl polyglycosides (APG), was used in the formulations since it is biodegradable and non-ionic, leading to low toxic products and friendly properties to the environment. Two blank MEs, i.e., M1 and M2 were prepared by simple mixing dicaprylyl ether, decylglucoside, sorbotan monolaurate and water in the concentrations of 70%, 2.5%, 22.5% and 5%, respectively for M1 and 60%, 6%, 24% and 10%, respectively for M2. Afterwards, M1 and M2 were incorporated with 5% CoQ10 to obtained QM1 and QM2, respectively. All samples were studied for physicochemical properties and stability under accelerated condition. It was found that they were transparence and absence of liquid crystals. Their rheological profiles indicated low viscosity and Newtonian flow. After stability test by freeze thaw for 5 cycles, physicochemical properties of M1, M2, QM1 and QM2 were not obviously different from those at the initial. In addition, more than 97% of label amount of CoQ10 were found in both QM1 and QM2 after stability study. The results indicated that the investigated decylglucoside MEs were suitable systems for incorporation with CoQ10.

The Use of Styrenes as Embedding Media for Electron Microscopy

1971 ◽  
Vol 29 ◽  
pp. 488-489
Author(s):  
Edward D. De-Lamater ◽  
Eric Johnson ◽  
Thad Schoen ◽  
Cecil Whitaker
Keyword(s):  
Electron Microscopy ◽  
Surface Tension ◽  
Ultraviolet Light ◽  
Methyl Ethyl Ketone Peroxide ◽  
Methyl Ethyl ◽  
Styrene Polymerization ◽  
Radical Initiation ◽  
Tertiary Butyl ◽  
Low Viscosity ◽  
Free Radical Initiation

Monomeric styrenes are demonstrated as excellent embedding media for electron microscopy. Monomeric styrene has extremely low viscosity and low surface tension (less than 1) affording extremely rapid penetration into the specimen. Spurr's Medium based on ERL-4206 (J.Ultra. Research 26, 31-43, 1969) is viscous, requiring gradual infiltration with increasing concentrations. Styrenes are soluble in alcohol and acetone thus fitting well into the usual dehydration procedures. Infiltration with styrene may be done directly following complete dehydration without dilution.Monomeric styrenes are usually inhibited from polymerization by a catechol, in this case, tertiary butyl catechol. Styrene polymerization is activated by Methyl Ethyl Ketone peroxide, a liquid, and probably acts by overcoming the inhibition of the catechol, acting as a source of free radical initiation.Polymerization is carried out either by a temperature of 60°C. or under ultraviolet light with wave lengths of 3400-4000 Engstroms; polymerization stops on removal from the ultraviolet light or heat and is therefore controlled by the length of exposure.

Preparation and characterisation of vanadium pentoxide supported rhodium catalyst

1988 ◽  
Vol 46 ◽  
pp. 946-947
Author(s):  
A. Legrouri
Keyword(s):  
Aqueous Solution ◽  
Thermal Decomposition ◽  
Physicochemical Properties ◽  
Surface Area ◽  
Vanadium Pentoxide ◽  
High Purity ◽  
Gas Adsorption ◽  
Rhodium Catalyst ◽  
Optical Methods ◽  
Reducible Oxides

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.

Some quantitative applications of vascular corrosion casting

1992 ◽  
Vol 50 (1) ◽  
pp. 738-739
Author(s):  
Fred E. Hossler
Keyword(s):  
Blood Vessels ◽  
Nuclear Orientation ◽  
Three Dimensional ◽  
Surrounding Tissue ◽  
Confocal Laser ◽  
Corrosion Casting ◽  
Venous Valve ◽  
Casting Technique ◽  
Low Viscosity ◽  
Quantitative Measurements

Preparation of replicas of the complex arrangement of blood vessels in various organs and tissues has been accomplished by infusing low viscosity resins into the vasculature. Subsequent removal of the surrounding tissue by maceration leaves a model of the intricate three-dimensional anatomy of the blood vessels of the tissue not obtainable by any other procedure. When applied with care, the vascular corrosion casting technique can reveal fine details of the microvasculature including endothelial nuclear orientation and distribution (Fig. 1), locations of arteriolar sphincters (Fig. 2), venous valve anatomy (Fig. 3), and vessel size, density, and branching patterns. Because casts faithfully replicate tissue vasculature, they can be used for quantitative measurements of that vasculature. The purpose of this report is to summarize and highlight some quantitative applications of vascular corrosion casting. In each example, casts were prepared by infusing Mercox, a methyl-methacrylate resin, and macerating the tissue with 20% KOH. Casts were either mounted for conventional scanning electron microscopy, or sliced for viewing with a confocal laser microscope.

Investigation of thin sections of biological standards by EDX, EELS, and Auger electron spectroscopy

1990 ◽  
Vol 48 (2) ◽  
pp. 184-185
Author(s):  
S. Lehner ◽  
H.E. Bauer ◽  
R. Wurster ◽  
H. Seiler
Keyword(s):  
Processing System ◽  
Beam Current ◽  
Beam Diameter ◽  
Thin Sections ◽  
Biologically Relevant ◽  
Energy Filtering ◽  
Low Viscosity ◽  
Carbon Foils ◽  
Electron Microscopical ◽  
Exchange Membrane

In order to compare different microanalytical techniques commercially available cation exchange membrane SC-1 (Stantech Inc, Palo Alto), was loaded with biologically relevant elements as Na, Mg, K, and Ca, respectively, each to its highest possible concentration, given by the number concentration of exchangeable binding sites (4 % wt. for Ca). Washing in distilled water, dehydration through a graded series of ethanol, infiltration and embedding in Spurr’s low viscosity epoxy resin was followed by thin sectioning. The thin sections (thickness of about 50 nm) were prepared on carbon foils and mounted on electron microscopical finder grids.The samples were analyzed with electron microprobe JXA 50A with transmitted electron device, EDX system TN 5400, and on line operating image processing system SEM-IPS, energy filtering electron microscope CEM 902 with EELS/ESI and Auger spectrometer 545 Perkin Elmer.With EDX, a beam current of some 10-10 A and a beam diameter of about 10 nm, a minimum-detectable mass of 10-20 g Ca seems within reach.

Ultrastructural autoradiography of L6 skeletal-muscle cells exposed to a tritiated macrolide antibiotic (LY237216) in vitro

1992 ◽  
Vol 50 (1) ◽  
pp. 612-613
Author(s):  
S.L. White ◽  
C.B. Jensen ◽  
D.D. Giera ◽  
D.A. Laska ◽  
M.N. Novilla ◽  
...  
Keyword(s):  
Skeletal Muscle ◽  
Quantitative Analysis ◽  
Macrolide Antibiotic ◽  
Circle Method ◽  
Apical Surface ◽  
Polycarbonate Membrane ◽  
L6 Cells ◽  
Low Viscosity ◽  
Erythromycin A

In vitro exposure to LY237216 (9-Deoxo-11-deoxy-9,11-{imino[2-(2-methoxyethoxy)ethylidene]-oxy}-(9S)-erythromycin), a macrolide antibiotic, was found to induce cytoplasmic vacuolation in L6 skeletal muscle myoblast cultures (White, S.L., unpubl). The present study was done to determine, by autoradiographic quantitative analysis, the subcellular distribution of 3H-LY237216 in L6 cells.L6 cells (ATCC, CRL 1458) were cultured to confluency on polycarbonate membrane filters (Millipore Corp., Bedford, MA) in M-199 medium (GIBCO® Labs) with 10% fetal bovine serum. The cells were exposed from the apical surface for 1-hour to unlabelled-compound (0 μCi/ml) or 50 (μCi/ml of 3H-LY237216 at a compound concentration of 0.25 mg/ml. Following a rapid rinse in compound-free growth medium, the cells were slam-frozen against a liquid nitrogen cooled, polished copper block in a CF-100 cryofixation unit (LifeCell Corp., The Woodlands, TX). Specimens were dried in the MDD-C Molecular Distillation Drier (LifeCell Corp.), vapor osmicated and embedded in Spurrs low viscosity resin. Ultrathin sections collected on formvar coated stainless steel grids were counter-stained, then individually mounted on corks. A monolayer of Ilford L4 nuclear emulsion (Polysciences, Inc., Warrington, PA) was placed on the sections, utilizing a modified “loop method”. The emulsions were exposed for 7-weeks in a light-tight box at 4°C. Autoradiographs were developed in Microdol-X developer and examined on a Philips EM410LS transmission electron microscope. Quantitative analysis of compound localization employed the point and circle approach of Williams; incorporating the probability circle method of Salpeter and McHenry.

The concerted use of SEM, TEM, and SCM for examination of resin-dentin interfaces

1994 ◽  
Vol 52 ◽  
pp. 476-477
Author(s):  
B. Van Meerbeek ◽  
L. J. Conn ◽  
E. S. Duke
Keyword(s):  
Surface Layer ◽  
Stress Distribution ◽  
Phosphoric Acid ◽  
Bonding Mechanism ◽  
Restorative Dentistry ◽  
Dental Adhesive ◽  
Low Viscosity ◽  
Dentin Adhesives ◽  
Acid Etch ◽  
Tooth Tissue

Restoration of decayed teeth with tooth-colored materials that can be bonded to tooth tissue has been a highly desirable property in restorative dentistry for many years. Advantages of such an adhesive restorative technique over conventional techniques using non-adhesive metal-based restoratives include improved restoration retention with minimal sacrifice of sound tooth tissue for retention purposes, superior adaptation and sealing of the restoration margins in prevention of caries recurrence, improved stress distribution across the tooth-restoration interface throughout the whole tooth, and even reinforcement of weakened tooth structures. The dental adhesive technology is rapidly changing. An efficient resin bond to enamel has already long been achieved. Its bonding mechanism has been fully elucidated and has proven to be a durable and reliable clinical treatment. However, bonding to dentin represents a greater challenge. After the failures of a dentin acid-etch technique in imitation of the enamel phosphoric-acid-etch technique and a bonding procedure based on chemical adhesion, modern dentin adhesives are currently believed to bond to dentin by a micromechanical hybridization process. This process is developed by an initial demineralization of the dentin surface layer with acid etchants exposing a collagen fibril arrangement with interfibrillar microporosities that subsequently become impregnated by low-viscosity monomers. Although the development of such a hybridization process has well been documented in the literature, questions remain with respect to parameters of-primary importance to adhesive efficacy.

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