scholarly journals Investigating the Effects of Soil Clay Fraction on Ammonium Migration through Porous Media

2021 ◽  
Author(s):  
Pooja Agarwal
Keyword(s):  
2018 ◽  
Vol 19 (1) ◽  
Author(s):  
Tingting Fan ◽  
Chengbao Li ◽  
Juan Gao ◽  
Dongmei Zhou ◽  
Marcelo Eduardo Alves ◽  
...  
Keyword(s):  

2020 ◽  
Author(s):  
Nga T. Mai ◽  
Nga T. T. Pham ◽  
Anh T. Q. Nguyen ◽  
Anh T. N. Nguyen ◽  
Anh M. Nguyen ◽  
...  

<p>In soils clay loss by leaching and surface runoff is one of the initial steps increasing the risk of erosion. Here we set out to determine the effect of fine-sized biochar amendment on colloidal dynamics of soil clay, with the aim of answering whether biochar addition enhances or curbs soil erosion. Fine-sized biochar samples were prepared from fern Dicranopteris linearis’s biomass under non-biochar-oriented pyrolysis (open heating) and biochar-oriented pyrolysis (N<sub>2</sub>-supported heating) over a temperature range from 400 to 900°C. The clay fraction (< 2 µm) separated from a clay-rich soil in a hilly area of the Red River basin containing relatively high amounts of kaolinite was tested for its dispersion properties under the presence of the prepared biochars. Surface charge of biochar-soil clay mixtures was determined by polyelectrolyte titration using a particle charge detector, while corresponding colloidal properties of the mixtures were examined by the test tube method. Both, the soil clay fraction and biochar samples showed strongly negative surface charge and their surface charge was variable depending on pH. In a pH range from 3 to 10 and at an electrolyte background of 0.01 M NaCl, surface charge of the clay fraction decreased from -1.68 to -44.75 mmol<sub>c</sub> Kg<sup>-1</sup>, while the biochars surface charge varied from -0.6 to -48.8 mmol<sub>c</sub> Kg<sup>-1</sup>. Soil clays were more strongly dispersed in the presence of biochars by increasing electrostatic repulsive forces. The biochar preparation method had a crucial role for surface charge properties of biochars and in consequence colloidal dynamics of biochar-clay mixtures. The N<sub>2</sub>-supported pyrolysis at lower temperatures does not increase charge density but creates a more porous structure, thereby increasing the total negative net charges. As a result, the N<sub>2</sub>-supported biochars favor clay dispersion more effectively, while the open-pyrolysis biochars showed lesser effects. Our results indicate that fine-sized biochar amendments generally enhance the risk of clay loss, however, such techniques for creating low-charged biochars can help to decrease clay dispersibility when applying biochar for soil.</p>


2001 ◽  
Vol 77 (6) ◽  
pp. 1006-1013 ◽  
Author(s):  
James D. Stewart ◽  
Simon M. Landhäusser ◽  
Kenneth J. Stadt ◽  
Victor J. Lieffers

Successful mixedwood management in the boreal forest of Alberta requires better knowledge of the occurrence and success of natural white spruce regeneration. In this study we developed statistical models to predict the natural establishment and height growth of understory white spruce (Picea glauca (Moench) Voss) in the boreal mixedwood forest in Alberta using data from 148 provincial permanent sample plots, supplemented by measurements of the amount and height growth of regenerating white spruce, and the amount and type of available substrate. A discriminant model correctly classified 73% of the sites as to presence or absence of a white spruce understory based on the amount of spruce basal area, rotten wood, ecological nutrient regime, soil clay fraction and elevation, although it explained only 30% of the variation in the data. On sites with a white spruce understory, a regression model related the abundance of regeneration to rotten wood cover, spruce basal area, pine basal area, soil clay fraction, and grass cover (R2 = 0.36). About half of the seedlings surveyed grew on rotten wood, and only 3% on mineral soil, and seedlings were 10 times more likely to have established on these substrates than on litter. Exposed mineral soil was rare, covering only 0.3% of the observed transect area, rotten wood covered 4.5%, and litter/undisturbed forest floor covered the remainder. The regression models developed for average relative height growth rate included feather moss cover, stand age and birch basal area for seedlings ≤ 1 m (R2 = 0.23), and feather moss cover, elevation, other moss cover and soil clay fraction for seedlings between 1 m and 3 m (R2 = 0.27). Key words: Picea glauca, seedling establishment, seedbeds, site factors, coarse woody debris, predictive models, mixedwood management


2015 ◽  
Vol 12 (6) ◽  
pp. 731 ◽  
Author(s):  
Nanci Kloster ◽  
Marcelo Avena

Environmental context Humic acids, important components of natural organic matter in soils, sediments and aquatic media, can interact with the surface of minerals affecting key environmental processes. In the presence of calcium, humic acids can also interact among themselves leading to molecular aggregates. We demonstrate that a solid mineral surface facilitates the formation of humic acid aggregates, and thus surface aggregation occurs under conditions where normal aggregation in solution does not occur. Abstract Humic acids (HAs) interact with the surface of mineral particles leading to the formation of clay–humic complexes that affect the transport of nutrients and contaminants in the environment, soil structure, soil erosion and carbon sequestration by soils. The interaction is influenced by the presence of multivalent ions, such as Ca2+, which enhances the uptake of HAs by the particles. This article reports the effects of Ca2+ on the interaction between a HA and a soil clay fraction, both obtained from the same soil sample. The study was performed by using zeta potential measurements, HA adsorption isotherms, Ca2+ adsorption isotherms and microscopy. The results show that at low HA concentrations and low Ca2+ concentrations HA adsorption takes place, but that at high concentrations surface aggregation and precipitation also takes place, a process that is seldom reported or analysed in the literature. HA adsorption isotherms only give the overall HA uptake by the solid but they do not allow differentiation of HA adsorption from surface aggregation. However, HA adsorption v. Ca2+ concentration plots and Ca2+ adsorption isotherms at different HA concentrations can distinguish these two processes quite clearly. In addition, surface aggregation could be undoubtedly observed with optical microscopy. Surface aggregation starts to take place at a 0.7mM Ca2+ concentration, which is lower than the Ca2+ concentration needed to start HA aggregation in solution. This indicates that the surface of soil minerals acts as a nucleation centre for HA aggregation.


Soil Research ◽  
2007 ◽  
Vol 45 (3) ◽  
pp. 224 ◽  
Author(s):  
M. E. Alves ◽  
Y. P. Mascarenhas ◽  
D. H. French ◽  
C. P. M. Vaz

Although the mineralogical quantitative analysis of the soil clay fraction can provide useful information for the improvement of soil management practices, the quantitation of all clay components normally requires a combination of different analytical techniques, which makes this determination expensive and time-consuming. One alternative for more expeditious mineralogical quantitations consists of using the Rietveld method for the treatment of X-ray diffraction (XRD) data. In this study we evaluate the accuracy of the mineralogical quantitative analyses of oxisol deferrified clays carried out with the application of the Rietveld method to XRD data obtained for both non-spray- and spray-dried samples. Linear regression analyses were carried out for comparing the XRD-Rietveld results with those calculated from X-ray fluorescence spectroscopy (XRF) data. Correspondence was observed between the XRD-Rietveld and XRF-derived data, confirming the potential utility of the Rietveld method for soil clay mineralogical quantitative analysis. Although sample preparation by using the spray drying procedure tended to improve XRD mineralogical quantitation, accurate results can be also achieved when this procedure is not available in the XRD laboratory.


2010 ◽  
Vol 42 (5) ◽  
pp. 739-747 ◽  
Author(s):  
Mark R. Liles ◽  
Ozgur Turkmen ◽  
Brian F. Manske ◽  
Mingzi Zhang ◽  
Jean-Marie Rouillard ◽  
...  

2013 ◽  
Vol 241 ◽  
pp. 36-42 ◽  
Author(s):  
Nivea M.P. Dias ◽  
Daniele Gonçalves ◽  
Wellington C. Leite ◽  
André M. Brinatti ◽  
Sérgio C. Saab ◽  
...  

Clay Minerals ◽  
1993 ◽  
Vol 28 (1) ◽  
pp. 145-148
Author(s):  
B. Jańczuk ◽  
G. Józefaciuk ◽  
M. Hajnos ◽  
T. Bialopiotrowicz ◽  
A. Kliszcz

When studying surface free energies of clays in relation to clay composition, we calculated that in some instances the aggregate stability should be higher for Na- then for Ca-forms. This raised the question as to whether the results obtained with the surface free energy approach are reliable for estimation of soil aggregate stability. The aim of the present work was to measure the surface free energy components and attractive forces for a clay calculated from measurements of the contact angle of glycerol, diiodomethane and cis-decalin and to compare them with results of penetrometrical measurements.


Soil Research ◽  
1999 ◽  
Vol 37 (5) ◽  
pp. 913 ◽  
Author(s):  
Alexander Neaman ◽  
Arieh Singer ◽  
Karl Stahr

The influence of clay mineralogy on disaggregation in some palygorskite-containing soils of the Jordan and Bet-She'an Valleys was examined. The disaggregation potential of different minerals in the soil clay fraction was investigated by establishing differences in the mineral suite between the original and disaggregated clay fractions. By shaking the soil with distilled water, calcite, dolomite, feldspar, and palygorskite were disaggregated preferentially. The pattern for quartz was inconsistent. Among phyllosilicates, palygorskite was the most strongly, disaggregated, while smectite was the least disaggregated mineral. The disaggregation potential of kaolinite was of intermediate value. By shaking the soil with 0 ⋅ 01 N NaCl, calcite and dolomite were released preferentially, and were the dominant minerals in the disaggregated clay fraction. Scanning electron microscopy observations indicate that palygorskite fibres do not associate into aggregates in soils and suspensions, even when saturated with calcium ions. The present findings are relevant for soils with low exchangeable sodium percentage. These soils can be expected under rain-fed agriculture or irrigation with high quality water which has a low sodium adsorption ratio.


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