Variation in the analytical figure of merit for in‐situ Hf isotopic measurements by LA‐MC‐ICPMS in zircon standards at variable spatial resolutions

Author(s):  
Saurabh Singhal ◽  
Sandeep Singh ◽  
Dharmendra Singh
Author(s):  
Kota Yamamoto ◽  
Hisashi Asanuma ◽  
Hiroaki Takahashi ◽  
Takafumi Hirata

New data reduction method for isotopic measurements using high-gain Faraday amplifiers enables precise uranium isotopic analysis even from transient signals.


2007 ◽  
Vol 1044 ◽  
Author(s):  
Xiaoting Jia ◽  
Vincent Berube ◽  
Shuo Chen ◽  
Bed Poudel ◽  
Son Hyungbin ◽  
...  

AbstractNanostructured thermoelectric materials have attracted lots of interest in recent years, due to their enhanced performance determined by their thermoelectric dimensionless figure of merit. However, because of equipment limitations, not much work has been done on combining simultaneous transport measurements and structural characterization on individual nanostructured thermoelectric materials. With an integrated TEM-STM system, we studied the structural behavior and electrical properties of bismuth (Bi) nanobelts and nanoparticles. Results showed that clean Bi nanostructures free of oxides can be produced by in-situ high temperature electro-migration and Joule annealing processes occurring within the electron microscope. Preliminary electrical measurements indicate a conductivity of two orders of magnitude lower for Bi nanoparticles than that for bulk Bi. Such in-situ studies are highly advantageous for studying the semimetal-semiconductor transition and how this transition could enhance thermoelectric properties.


2019 ◽  
Vol 7 (25) ◽  
pp. 15181-15189 ◽  
Author(s):  
Khasim Saheb Bayikadi ◽  
Raman Sankar ◽  
Chien Ting Wu ◽  
Chengliang Xia ◽  
Yue Chen ◽  
...  

The thermoelectric figure-of-merit (ZT) for GeTe powder is able to be raised from ∼0.8 to 1.37 at high temperature near ∼500 °C by tuning the Ge vacancy level through a reversible in situ route.


1998 ◽  
pp. 1057-1064
Author(s):  
P. R. Mahaffy ◽  
S. K. Atreya ◽  
H. B. Niemann ◽  
T. C. Owen

2016 ◽  
Vol 16 (4) ◽  
pp. 3841-3847 ◽  
Author(s):  
Lijie Guo ◽  
Zhengwei Cai ◽  
Xiaolong Xu ◽  
Kunling Peng ◽  
Guiwen Wang ◽  
...  

p-type skutterudites NdxFe3CoSb12 with x equaling 0.8, 0.85, 0.9, 0.95, 1.0 have been synthesized by solid state reaction followed by spark plasma sintering. The influence of Nd filling on electrical and thermal transport properties has been investigated in the Nd-filled skutterudite compounds in the temperature range from room temperature to 800 K. It was found that the Seebeck coefficient is drastically enhanced via filling Nd in p-Type skutterudites as well as the corresponding power factor although electrical conductivity is reduced. In addition, a large reduction in thermal conductivity is achieved by Nd fillers through rattling effect along with the In-Situ nanostructured precipitate through scattering phonons with much wider frequency. These concomitant effects result in an enhanced thermoelectric performance with the dimensionless figure of merit ZT. These observations demonstrate an exciting scientific opportunity to raise the figure-of-merit of p-type skutterudites.


2008 ◽  
Vol 1074 ◽  
Author(s):  
Sadik Guner ◽  
Satilmis Budak ◽  
Claudiu I Muntele ◽  
Cydale C Smith ◽  
Daryush Ila

ABSTRACTWe have grown 100 periodic SiO2/SiO2+Ag multi-nano-layered systems where the SiO2+Ag layers were 7.26 nm and SiO2 buffer layer were 4 nm, total thickness is 563 nm. Using interferometer as well as in-situ thickness monitoring, we measured the thickness of the layers; using Rutherford Backscattering Spectrometry (RBS) measured the concentration and distribution of Ag in SiO2. The electrical conductivity, thermal conductivity and the Seebeck coefficient of the layered structure were measured at room temperature before and after bombardment by 5 MeV Si ions. The energy of the Si ions were chosen such that the ions are stopped in the silicon substrate and only electronic energy due to ionization is deposited in the layered structure. The electrical conductivity measured using Van der Pauw method. Thermal conductivity of the thin films was measured using an in-house built 3ω thermal conductivity measurement system. Using the measured Seebeck coefficient, thermal conductivity and electrical conductivity we calculated the figure of merit (ZT). We will report our findings of change in the figure of merit as a function of the bombardment fluence.


2015 ◽  
Vol 08 (05) ◽  
pp. 1550059 ◽  
Author(s):  
Samuel P. Balch ◽  
Roderic S. Lakes

Indium–zinc in situ composites were fabricated and their viscoelastic properties studied over 8.5 decades of frequency. Material with 5% indium by weight was found to have a stiffness damping product (the figure of merit for damping layers) of 1.9 GPa at 10 Hz; 3 times better than the peak of polymer damping layers and over a wider frequency range. Material with 15% indium had a stiffness damping product of 1.8 GPa. The indium segregated in a platelet morphology, particularly favorable for attaining high damping from a small concentration, as predicted by viscoelastic composite theory.


RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16824-16831 ◽  
Author(s):  
Kang Yin ◽  
Xianli Su ◽  
Yonggao Yan ◽  
Ctirad Uher ◽  
Xinfeng Tang

The relationship between the temperature and the composition as well as the microstructure of a Sb-doped Mg2Si0.30Sn0.70 solid solution was systematically studied according to the Mg2Si–Mg2Sn pseudo-binary phase diagram.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Bushra Jabar ◽  
Fu Li ◽  
Zhuanghao Zheng ◽  
Adil Mansoor ◽  
Yongbin Zhu ◽  
...  

AbstractNanocomposite engineering decouples the transport of phonons and electrons. This usually involves the in-situ formation or ex-situ addition of nanoparticles to a material matrix with hetero-composition and hetero-structure (heC-heS) interfaces or hetero-composition and homo-structure (heC-hoS) interfaces. Herein, a quasi homo-composition and hetero-structure (hoC-heS) nanocomposite consisting of Pnma Bi2SeS2 - Pnnm Bi2SeS2 is obtained through a Br dopant-induced phase transition, providing a coherent interface between the Pnma matrix and Pnnm second phase due to the slight structural difference between the two phases. This hoC-heS nanocomposite demonstrates a significant reduction in lattice thermal conductivity (~0.40 W m−1 K−1) and an enhanced power factor (7.39 μW cm−1 K−2). Consequently, a record high figure-of-merit ZTmax = 1.12 (at 773 K) and a high average figure-of-merit ZTave = 0.72 (in the range of 323–773 K) are achieved. This work provides a general strategy for synergistically tuning electrical and thermal transport properties by designing hoC-heS nanocomposites through a dopant-induced phase transition.


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