Toughening of polyvinylchloride by methyl methacrylate-butadiene-styrene core-shell rubber particles: Influence of rubber particle size

2012 ◽  
Vol 52 (12) ◽  
pp. 2523-2529 ◽  
Author(s):  
Chao Zhou ◽  
Hua Liu ◽  
Ming Chen ◽  
Guangfeng Wu ◽  
Huixuan Zhang
2020 ◽  
Vol 850 ◽  
pp. 107-111
Author(s):  
Laimonis Mālers ◽  
Agnija Cirvele

Functional properties of composite material based on mechanically grinded scrap tires with different particle size of fractioned crumb and polyurethane type polymer binder were investigated to estimate influence of rubber particles size and content on composite material properties (Shore C hardness, compressive stress at 10 % deformation, tensile strength, elastic modulus and elongation at break, apparent density). Optimization possibilities of composite material consisting of rubber particles with different sizes or fractions were investigated. The obtained results show that variation of composition of the composite material by changing size of rubber granulate have definite influence on selected properties of the material. Purposeful selection and mutual combination of rubber particles size included in material can ensure desirable and predictable mechanical properties of composite material.


Polymer ◽  
1997 ◽  
Vol 38 (16) ◽  
pp. 4247-4252 ◽  
Author(s):  
A.M. Aerdts ◽  
G. Groeninckx ◽  
H.F. Zirkzee ◽  
H.A.M. van Aert ◽  
J.M. Geurts

Soft Matter ◽  
2017 ◽  
Vol 13 (38) ◽  
pp. 6905-6912 ◽  
Author(s):  
Roy l'Abee ◽  
Martin van Duin ◽  
Han Goossens

The rubber particle size as well as chemical grafting onto the surface of cross-linked rubber particles control the mechanical deformation behavior of sub-μm thermoplastic vulcanizates (TPVs).


e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Chao Zhou ◽  
Lili Sun ◽  
Shulin Sun ◽  
Zhiyong Tan ◽  
Guangfeng Wu ◽  
...  

AbstractPolyamide-6 (PA6)/montmorillonite (MMT) nanocomposites were prepared via melt compounding. Maleated acrylonitrile-butadiene-styrene (ABS-g- MA) core-shell structural rubber particles were first introduced to toughen PA6/MMT nanocomposites. Before melt intercalation, MMT was treated with an organic surfactant agent. XRD and TEM results showed that MMT platelets were completely exfoliated in the PA6 matrix. And when the core-shell rubber particles were introduced into the nanocomposites, they were well dispersed in the matrix. Tensile and impact tests showed that a small amount of MMT could increase the yield strength but sacrifice the toughness. However when core-shell rubber particles were added into the nanocomposites, the tensile ductility and impact strength improved greatly. It was reasonable to say that the addition of core-shell particles could make the balance of the stiffness and toughness of nanocomposites.


Polimery ◽  
2021 ◽  
Vol 66 (2) ◽  
pp. 112-118
Author(s):  
Lining Song ◽  
Zhenxu Li ◽  
Lina Yang ◽  
Ning Wang ◽  
Jie Zhao ◽  
...  

The attapulgite core-shell microcapsule type flame retardant was prepared by in situ polymerization. Attapulgite (ATP) was used as a core material with poly(methyl methacrylate) (PMMA) and poly(methyl methacrylate-co-acrylic acid) [P(MMA-co-AA)] as shell materials. The attapulgite was modified by the silane coupling agent. The effects of different shell materials and modification methods on the structure and properties of attapulgite core-shell microcapsules were studied by scanning electron microscopy, particle size distribution, infrared analysis and thermogravimetric analysis. The results showed that the coating effect was best when the amount of silane coupling agent was 1% of the attapulgite mass. The particle size of the microcapsule prepared with PMMA as shell material was uniform and the coating efficiency was better. After the copolymerization of acrylic acid (AA) in MMA shell materials, the cladding efficiency was improved. At the same time, the thermal decomposition temperature of the microcapsule shell material was greatly reduced, which is beneficial to the performance of attapulgite flame retardant.


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