Cobalt Electrodeposition from Cobalt Chloride Using Urea and Choline Chloride Ionic Liquid: Effect of Temperature, Applied Voltage, and Cobalt Chloride Concentration on Current Efficiency and Energy Consumption

Author(s):  
Andrea R. Kim ◽  
Ramana G. Reddy
2013 ◽  
Vol 295-298 ◽  
pp. 1327-1332 ◽  
Author(s):  
Chun Rong Wang ◽  
Sha Chang ◽  
Min Ye ◽  
Qin Yi Ren

The electrochemical treatment of ammonia using born-doped diamond (BDD) as advanced treatment of coking wastewater was investigated. The effects of chloride ion concentration and current density on current efficiency and energy consumption were also analyzed. The results show that the current efficiency increases with chloride ion concentration increase and current density decrease. And 30% of current efficiency is obtained when current density is less than 19.7mA cm-2, and it decreases above 19.7mA cm-2. The energy consumption decreases with the chloride ion concentration increase and current density decrease. And energy consumption of 0.50kWh g-1 and ammonia removal rate of 84.7% can be achieved at initial ammonia concentration of 100mg L-1, chloride concentration of 900mg L-1 and current density of 29.6mA cm-2.Therefore, BDD electrodes have high current efficiency and low energy consumption, which attributed to its high oxygen evolution overvoltage (2.6V vs. SCE) and low chloride evolution overvoltage (1.5V vs. SCE).


2020 ◽  
Vol 26 (12) ◽  
pp. 110-130
Author(s):  
Duaa R. Saad ◽  
Ziad T. Alismaeel ◽  
Ali H. Abbar

In this research, the removal of cadmium (Cd) from simulated wastewater was investigated by using a fixed bed bio-electrochemical reactor. The effects of the main controlling factors on the performance of the removal process such as applied cell voltage, initial Cd concentration, pH of the catholyte, and the mesh number of the cathode were investigated. The results showed that the applied cell voltage had the main impact on the removal efficiency of cadmium where increasing the applied voltage led to higher removal efficiency. Meanwhile increasing the applied voltage was found to be given lower current efficiency and higher energy consumption.  No significant effect of initial Cd concentration on the removal efficiency of cadmium but increasing the initial concentration would be given higher current efficiency and lower energy consumption. The results established that using a pH value lower than three results in a sharp decrease in the removal efficiency as well as  using a pH value higher than seven results in decreasing the removal efficiency. Using a mesh number higher than 30 gave a lower removal efficiency. The best operating conditions were found to be an applied potential of 1.8 V, an initial Cd concentration of 125 ppm, and a pH of 7. Under these operating conditions with the using a stack of stainless with mesh number 30 as a packed bed cathode, a complete removal efficiency of Cd(100%)  was obtained at a current efficiency of 83.57% and energy consumption of 0.57 kWh/kg Cd.


Author(s):  
Eiji Kamio ◽  
Hiroki Kurisu ◽  
Tomoki Takahashi ◽  
Atsushi Matsuoka ◽  
Tomohisa Yoshioka ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (17) ◽  
pp. 10081-10091 ◽  
Author(s):  
T. Preethi ◽  
M. P. Padmapriya ◽  
B. Abarna ◽  
G. R. Rajarajeswari

Choline chloride–zinc chloride ionic liquid has been used as a green template to synthesis highly crystalline mesoporou anatase titania.


2016 ◽  
Vol 13 (2) ◽  
pp. 58-65
Author(s):  
Baghdad Science Journal

In this research local wheat peel was used as an adsorbent surface for removal of Azure B (AB) dye from the aqueous solution. The adsorption process was performed at different experimental parameters, equilibrium time, temperature, ionic strength and solution pH. The isotherms of adsorption are of H-type as compared with Giles curves and the adsorption data were coincide with Freundlich equation. The adsorption kinetic data were analyzed using pseudo- first and second order kinetic models. The effect of temperature was studied and the amount of dye adsorbed was found to increase with the increasing of temperature from 25 to 50 oC. The values of thermodynamic functions like enthalpy and entropy have been estimated. The quantity of adsorbed dye on the wheat peel increase according to the sequence follows: pH 9.3? 8 ? 7 ?6 ?5.2.The adsorption phenomenon is influenced by the sodium chloride concentration of solution. The obtained data refer to a decrease in amount of Azure B adsorbed in the existence of electrolyte.


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