Hydrothermal Petroleum Generation from Immature Organic Matter-Implications to the Oceanic Carbon Cycle

1990 ◽  
pp. 365-387 ◽  
Author(s):  
B. R. T. Simoneit
2020 ◽  
Author(s):  
Minkyoung Kim ◽  
Jeomshik Hwang ◽  
Timothy I. Eglinton ◽  
Ellen R. M. Druffel

<p>Despite the potential importance in the oceanic carbon cycle and benthic ecosystem, global feature of lateral supply of aged organic matter hosted on lithogenic particles derived from sediment resuspension has not been systematically examined. We compiled concentrations and fluxes of lithogenic material in the ocean in a global-scale by using literature data of sediment trap studies to understand the contribution of resuspended sediment to sinking particulate matter. We find that these contributions are significant in various oceanic settings, particularly over continental margins. Lithogenic material flux decreased with increasing distance from the margins and above the seafloor. Examination of Δ<sup>14</sup>C values of sinking POC revealed strong relationships with parameters that represent contribution of resuspended sediment. We then derive estimates for the contribution of aged POC from sediment resuspension to sinking POC based on these relationships and global lithogenic material flux data.</p>


2021 ◽  
Vol 9 ◽  
Author(s):  
Gen Wang ◽  
Yongli Wang ◽  
Zhifu Wei ◽  
Zepeng Sun ◽  
Wei He ◽  
...  

Uplift of the Tibetan Plateau plays a significant and lasting role in the variations of climate conditions and global carbon cycle. However, our knowledge is limited due to the lack of long-sequence records revealing rates of CO2 and CH4 production, hampering our understanding of the relationship between paleoclimatic conditions, carbon cycling and greenhouse gas flux. Here, we present a combination of paleoclimate records and low-temperature thermal simulation results from sediments of the Xiaolongtan Basin at the southeastern margin of the Qinghai-Tibetan Plateau, spanning the late Miocene (14.1 ∼ 11.6 Ma). The n-alkane-derived proxies suggested that the sources of organic matter were obviously different: a mixed source including lower organisms and terrestrial higher plants for the Dongshengqiao Formation from 14.1 to 12.6 Ma, and a predominant contribution from terrestrial higher plants for Xiaolongtan Formation between 12.6 and 11.6 Ma. The paleoclimate was generally warm and humid as reflected by the lipid biomarkers, consistent with previous studies. In addition, the carbon gases (including CO2 and hydrocarbon gases) generated by the low-temperature thermal simulation experiments indicated a production rate of CO2 and CH4 were as high as 88,000 ml/kg rock and 4,000 ml/kg rock, respectively, implying there were certain amounts of carbon gases generated and released into the atmosphere during their shallow burial stage. Besides, the calculated production rate of carbon gases and the estimated burial flux of organic carbon varied in response to the variations of paleoclimate conditions. Based on these observations, we propose that the climate conditions predominantly controlled the formation and accumulation of organic matter, which consequently affected the production of carbon gases and burial flux of organic carbon. The results presented here may provide a significant insight into the carbon cycle in the southeast of the Tibetan Plateau.


2021 ◽  
Vol 9 ◽  
Author(s):  
Kuo Wang ◽  
Han Zhang ◽  
Gao-Feng Fan ◽  
Zheng-Quan Li ◽  
Zhen-Yan Yu ◽  
...  

Since preindustrial times, atmospheric CO2 content increased continuously, leading to global warming through the greenhouse effect. Oceanic carbon sequestration mitigates global warming; on the other hand, oceanic CO2 uptake would reduce seawater pH, which is termed ocean acidification. We perform Earth system model simulations to assess oceanic CO2 uptake, surface temperature, and acidification for Zhejiang offshore, one of the most vulnerable areas to marine disasters. In the last 40 years, atmospheric CO2 concentration increased by 71 ppm, and sea surface temperature (SST) in Zhejiang offshore increased at a rate of 0.16°C/10a. Cumulative oceanic CO2 uptake in Zhejiang offshore is 0.3 Pg C, resulting in an increase of 20% in sea surface hydrogen ion concentration, and the acidification rate becomes faster in the last decade. During 2020–2040, under four RCP scenarios, SST in Zhejiang offshore increases by 0.3–0.5°C, whereas cumulative ocean carbon sequestration is 0.150–0.165 Pg C. Relative to RCP2.6, the decrease of surface pH in Zhejiang offshore is doubled under RCP8.5. Furthermore, simulated results show that the relationship between CO2 scenario and oceanic carbon cycle is nonlinear, which hints that deeper reduction of anthropogenic CO2 emission may be needed if we aim to mitigate ocean acidification in Zhejiang offshore under a higher CO2 concentration scenario. Our study quantifies the variation characteristics of oceanic climate and carbon cycle fields in Zhejiang offshore, and provides new insight into the responses of oceanic carbon cycle and the climate system to oceanic carbon sequestration.


2021 ◽  
Author(s):  
Pia Müller ◽  
Ulrich Heimhofer ◽  
Christian Ostertag-Henning

<p>The Oceanic Anoxic Event (OAE) 2 spanning the Cenomanian-Turonian boundary (93.5 Ma)<br>represents a major perturbation of the global carbon cycle and is marked by organic-rich<br>sediments deposited under oxygen-depleted conditions. In many studies the eruption of the<br>Caribbean LIP is considered to be the cause for rapidly increasing CO2 concentrations and<br>resulting global warming accompanied by widespread oceanic anoxia. In the Lower Saxony<br>Basin of northern Germany, the deposits of the OAE 2 are exposed in several industry drill<br>cores. In this study, the lower part of the OAE 2 has been studied in the HOLCIM 2011-3 drill<br>core. Sedimentary rocks are composed of limestones, marly limestones, marls and black<br>shales and have been analysed with a high-resolution stable isotope approach<br>(approximately one sample every 2 cm) combined with geochemical modelling. Using stable<br>carbon isotopes, bulk rock parameters and petrographic analysis, the onset of OAE 2 has<br>been investigated in detail. The high-resolution δ<sup>13</sup>C curve exhibits overall stable values<br>around 3 ‰ before the onset of the Plenus event. This background level is interrupted by<br>three short-lived and small but significant negative carbon isotope excursions (CIEs) down to<br>δ<sup>13</sup>C values of 2.5 ‰, 2.7 ‰ and 1.9 ‰. Immediately before the main rise in the Plenus bed,<br>a longer-lasting negative CIE down to 2.8 ‰ is observed, preceding the large positive CIE of<br>the OAE 2 to values of 5.2 ‰ over 33 ka. Thereafter, the δ<sup>13</sup>C values decrease to 3.5 ‰ over<br>a period of approximately 130 ka. The results can be correlated with the lower-resolution<br>data set of Voigt et al. (2008) but enable a more accurate characterization of the subtle<br>features of the CIE and hence events before and during this time interval. Carbon cycle<br>modelling with the modelling software SIMILE using a model based on Kump & Arthur (1999)<br>reveals that the negative excursion before the Plenus bed can be explained by a massive<br>volcanic pulse releasing of 0.95*10<sup>18</sup> mol CO2 within 14 ka. This amount corresponds to only<br>81 % of the calculated volume of CO<sub>2</sub> release during emplacement of the Caribbean LIP by<br>Joo et al. (2020). In the model the volcanic exhalation increases atmospheric CO<sub>2</sub><br>concentrations. This will increase global temperatures, intensify the hydrological cycle and<br>thus increase nutrient input into the ocean, resulting in an expansion of the oxygen minimum<br>zone, the development of anoxic conditions and an increase in the preservation potential for<br>organic material. In the model enhanced primary productivity and organic matter preservation<br>can be controlled by the implemented riverine phosphate input and the preservation factor for<br>organic matter. For the positive anomaly, the riverine phosphate input must be nearly<br>doubled (from 0.01 μmol/kg PO<sub>4 </sub>to 0.019 μmol/kg) for the period of the increasing δ<sup>13</sup>C<br>values (app. 33 ka), with a concomitant rise of the preservation factor from 1 % to 2 %. This<br>model scenario accurately reproduces the major features of the new high-resolution δ<sup>13</sup>C<br>record over the onset of the OAE 2 CIE.</p>


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