A phosphorous/nitrogen-containing flame retardant with UV-curing for polyester/cotton fabrics

Cellulose ◽  
2022 ◽  
Author(s):  
Xianwen Yang ◽  
Xiaohui Liu ◽  
Xuan Yang ◽  
Qiuyan Zhang ◽  
Yunbo Zheng ◽  
...  
Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1348
Author(s):  
Pamela Miśkiewicz ◽  
Magdalena Tokarska ◽  
Iwona Frydrych ◽  
Marcin Makówka

Innovative textile materials can be obtained by depositing different coatings. To improve the thermal properties of textiles, aluminum and zirconium (IV) oxides were deposited on the Nomex® fabric, basalt fabric, and cotton fabric with flame-retardant finishing using the magnetron sputtering method. An assessment of coating quality was conducted. Evenly coated fabric ensures that there are no places on the sample surface where the values of thermal parameters such as resistance to contact heat and radiant heat deviate significantly from the specified ones. Energy-dispersive spectroscopy was used for the analysis of modified fabric surfaces. Non-contact digital color imaging system DigiEye was also used. The criterion allowing one to compare surfaces and find which surface is more evenly coated was proposed. The best fabrics from the point of view of coating quality were basalt and cotton fabrics coated with aluminum as well as basalt fabric coated with zirconia. The probability of occurrence of places on the indicated sample surfaces where the values of thermal parameters (i.e., resistance to contact heat and radiant heat) deviated significantly from the specified ones was smaller for Nomex® and cotton fabrics coated with zirconia and Nomex® fabric coated with aluminum.


Cellulose ◽  
2015 ◽  
Vol 22 (4) ◽  
pp. 2787-2796 ◽  
Author(s):  
Wei-Wei Gao ◽  
Guang-Xian Zhang ◽  
Feng-Xiu Zhang

1983 ◽  
Vol 1 (2) ◽  
pp. 145-154 ◽  
Author(s):  
John V. Beninate ◽  
Brenda J. Trask ◽  
Timothy A. Calamari ◽  
George L. Drake

Durable phosphorus-based flame retardants were applied to twill fabrics con taining cotton and wool to study the effect of wool on the flame retardancy and physical properties of the blend fabrics. The presence of wool in untreated blend fabrics caused burning rates to decrease and oxygen index values to increase as wool content increased in the blends. These effects were also observed in cotton/ wool blends treated with low levels of the Thps-urea-TMM flame retardant, but were less pronounced in fabrics treated at high levels. Thermogravimetric analyses were conducted to study the thermal degradation of the treated and untreated fabrics. The presence of wool in treated blend fabrics did not sig nificantly change strength retention, area shrinkage and wrinkle recovery values in comparison to similarly treated 100% cotton fabrics.


2017 ◽  
Vol 48 (1) ◽  
pp. 87-118 ◽  
Author(s):  
MD Teli ◽  
Pintu Pandit

As far as the value addition of textile is concerned, flame retardancy of textile materials is considered to be one of the most important properties in textile finishing by both industries as well as academic researchers. Flame-retardant property with thermal stability was imparted to cotton by using green coconut ( Cocos nucifera Linn) shell extract, a natural waste source of coconut. Coconut shell extract was analyzed by high-performance liquid chromatography, Fourier transform infrared spectroscopy, energy-dispersive spectrometry and its phytochemical analysis was also carried out. The coconut shell extract (acidic after extraction) was applied in three different pH (acidic, neutral, and alkaline) conditions to the cotton fabric. Flame-retardant properties of the untreated and the treated cotton fabrics were analyzed by limiting oxygen index and vertical flammability. The study showed that all the treated fabrics had good flame resistance property compared to that of the untreated fabric. The limiting oxygen index value was found to increase by 72.2% after application of the coconut shell extract from alkaline pH. Pyrolysis and char formation behavior of the concerned fabrics were studied using thermogravimetric analysis and differential scanning calorimetric analysis in a nitrogen atmosphere. The physicochemical composition of the untreated and coconut shell extract treated cotton fabrics were analyzed by attenuated total reflection–Fourier transform infrared, scanning electron microscope, and energy-dispersive X-ray spectroscopy. Also, treated cotton fabric showed natural brown color and antibacterial property against both Gram-positive and Gram-negative bacteria. The durability of the flame-retardant functionality to washing with soap solution has also been studied and reported in this paper.


2018 ◽  
Vol 136 (13) ◽  
pp. 47280 ◽  
Author(s):  
Dongdong Wei ◽  
Chaohong Dong ◽  
Zhaohua Chen ◽  
Jian Liu ◽  
Qun Li ◽  
...  

1964 ◽  
Vol 34 (8) ◽  
pp. 691-700 ◽  
Author(s):  
Joel B. Bullock ◽  
Clark M. Welch ◽  
John D. Guthrie

Tekstilec ◽  
2017 ◽  
Vol 60 (1) ◽  
pp. 29-35 ◽  
Author(s):  
Giuseppe Rosace ◽  
◽  
Claudio Colleoni ◽  
Emanuela Guido ◽  
Giulio Malucelli ◽  
...  

1966 ◽  
Vol 36 (5) ◽  
pp. 441-451 ◽  
Author(s):  
Joel B. Bullock ◽  
Clark M. Welch

1983 ◽  
Vol 1 (3) ◽  
pp. 165-176 ◽  
Author(s):  
William E. Franklin

Volatile products evolved during the pyrolysis of cotton fabrics treated with various add-ons of THPS-urea-phosphate flame retardant were measured by pyrolysis-mass spectrometry. Molar fractions of nine primary, volatile pyrolysis products were determined, accounting for 82-89 mole percent of the products. Three classes of volatile products were distinguished on the basis of the response of the product fractions to add-on of the flame retardant. Increasing add-on decreased the anhydroglucose fractions. Small add-ons increased the "furan" fractions and large add-ons decreased them. Nonfuel fractions increased with increasing add-on. Inverse relations were found between anhydroglucose fractions and water fractions and between "furan" fractions and carbon dioxide fractions. The flame retardancy of the cotton fabrics had the best correlation with the water fractions. These results are compared and contrasted with data from the pyrolysis of cotton fabrics treated with another flame retardant, THPOH-ammonia.


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