Towards a better control of the wastewater treatment process: excitation-emission matrix fluorescence spectroscopy of dissolved organic matter as a predictive tool of soluble BOD5 in influents of six Parisian wastewater treatment plants

2018 ◽  
Vol 25 (9) ◽  
pp. 8765-8776 ◽  
Author(s):  
Angélique Goffin ◽  
Sabrina Guérin ◽  
Vincent Rocher ◽  
Gilles Varrault



2021 ◽  
Vol 33 (1) ◽  
Author(s):  
Benxin Yu ◽  
Dongping Liu ◽  
Jian Wang ◽  
Yingxue Sun

Abstract Background Most particulate organic matter (POM) cannot be directly degraded in the conventional wastewater treatment, which should be transformed into dissolved organic matter (DOM) through a hydrolysis process. However, non-hydrolyzed POM in the biological treatment can limit treated efficiencies for the wastewater treatment plants (WWTPs) facilities. Hence an operational tool is indispensable for insight into removals of DOM and POM factions in the WWTP. In this study, excitation-emission matrix fluorescence spectroscopy (EEM) combined parallel factor analysis (PARAFAC), two-dimensional correlation (2D-COS) and structural equation modeling (SEM) was employed to evaluate removals of DOM and POM in a wastewater treatment plant. Results Four fluorescence components were identified in DOM and POM substances from the WWTP by EEM combined with PARAFAC, i.e., tyrosine-like (TYLF), tryptophan-like (TRLF), microbial byproduct-like (MBLF), and fulvic acid-like (FALF). In A2/O process, the TYLF and TRLF of DOM were removed to a larger extent than those of MBLF and FALF in anaerobic tank, while TYLF and MBLF of POM were removed to a great extent than those of TRLF and FALF in primary sedimentation and aerobic tanks. By the 2D-COS, a decreasing variation order of DOM fractions in the wastewater treatment process was UV-FALF → MBLF2 → Vis-FALF → TRLF → TYLF, while the decreasing order of POM fractions was Vis-FALF → UV-FALF → MBLF2 → TYLF → MBLF1 → TRLF. SEM revealed that TRLF and TYLF of DOM were degraded by anaerobic microorganism, and TRLF could be transformed partially into FALF. However, TRFL and TYLF of POM were discomposed by aerobic microorganism. Conclusions The 2D-COS and SEM can be practicable tools as EEM-PARAFAC for monitoring DOM and POM in the WWTP. The study could present a theoretical support to improving the retrofit of WWTP and formulating emission standards for organic pollutants.





2004 ◽  
Vol 4 (1) ◽  
pp. 23-33
Author(s):  
H. Ødegaard ◽  
Z. Liao ◽  
E. Melin ◽  
H. Helness

Many cities need to build compact wastewater treatment plants because of lack of land. This paper discusses compact treatment methods. An enhanced primary treatment process based on coarse media filtration is analysed. A high-rate secondary wastewater treatment process has specifically been investigated, consisting of a highly loaded moving bed biofilm reactor directly followed by a coagulation and floc separation step. The objective with this high-rate process is to meet secondary treatment effluent standards at a minimum use of chemicals, minimum sludge production and minimum footprint. It is demonstrated that the biofilm in the bioreactor mainly deals with the soluble organic matter while coagulation deals with the colloidal matter. The bioreactor may, therefore, be designed based on the soluble COD loading only, resulting in a very compact plant when a compact biomass/floc separation reactor (i.e. flotation or direct filtration) is used. The paper reports specifically on the coagulant choice in flotation and filter run time in direct filtration.



2019 ◽  
Vol 11 (23) ◽  
pp. 6658 ◽  
Author(s):  
I-Tae Kim

This study was conducted to secure the sustainability of biogas plants for generating resources from food waste (FW) leachates, which are prohibited from marine dumping and have been obligated to be completely treated on land since 2013 in South Korea. The aim of this study is to reduce the nitrogen load of the treatment process while producing bio-methanol using digested FW leachate diverted into wastewater treatment plants. By using biogas in conditions where methylobacter (M. marinus 88.2%) with strong tolerance to highly chlorinated FW leachate dominated, 3.82 mM of methanol production and 56.1% of total nitrogen (TN) removal were possible. Therefore, the proposed method can contribute to improving the treatment efficiency by accommodating twice the current carried-in FW leachate amount based on TN or by significantly reducing the nitrogen load in the subsequent wastewater treatment process. Moreover, the produced methanol can be an effective alternative for carbon source supply for denitrification in the subsequent process.



2013 ◽  
Vol 48 (3) ◽  
pp. 255-265 ◽  
Author(s):  
Kerry McPhedran ◽  
Rajesh Seth ◽  
Min Song ◽  
Shaogang Chu ◽  
Robert J. Letcher

Municipal wastewater treatment plants (MWTPs) are impacted by down-the-drain influents of anthropogenic chemicals. These chemicals are in consumer products and include the flame retardant tetrabromobisphenol A (TBBPA) and antimicrobial triclosan (TCS). Characterization of the distribution of TBBPA, TCS and the TBBPA product tribromobisphenol A (tri-BBPA) was determined at five stages along the treatment process of a typical Canadian MWTP facility. Overall, the TCS concentrations for both liquid (influents, primary effluents and final effluents (FEs)) and solid samples (primary and waste activated sludges) were similar to reported ranges in the literature. In contrast to TCS, both TBBPA and tri-BBPA concentrations were scarcely available in the literature. The TBBPA concentrations were within literature ranges for both influents and sludges, while the tri-BBPA sludge concentrations were markedly higher than a single available previous study. Mass balances for TCS, TBBPA and tri-BBPA indicated 7, 9 and 42%, respectively, of each chemical remaining in the FEs. The resultant annual mass loadings into the Detroit River were estimated to be 3.3 kg, 6.57 g, and 21.5 g for TCS, TBBPA and tri-BBPA, respectively.



2012 ◽  
Vol 178-181 ◽  
pp. 599-602
Author(s):  
Shu Xin Du ◽  
Yuan Qing Wu ◽  
Zhi Bao Yuan

In the wastewater treatment process, it is necessary to detect the concentrations of organic matter in order to monitor the operation and adjust the process parameters. Based on fluorescence excitation-emission matrix spectrometry, Chemical oxygen demand (COD) of effluent wastewater in the primary sedimentation tank, the secondary sedimentation tank and the final sedimentation tank of Hengdian Wastewater Treatment Plant, Zhejiang Province, is detected respectively based on fluorescence excitation-emission matrix spectrometry. In order to compare the modeling performance, principal component regression (PCR), partial least squares (PLS), parallel factor analysis (PARAFAC) and multi-way partial least squares (N-PLS) are respectively used to build the calibration models between the fluorescence spectrometry and COD. Experimental results show PLS is better than PARAFAC and N-PLS in the aspect of modeling performance for detecting COD in the wastewater.



2015 ◽  
Vol 91 (3) ◽  
pp. 684-695 ◽  
Author(s):  
Malak M. Tfaily ◽  
Jane E. Corbett ◽  
Rachel Wilson ◽  
Jeffrey P. Chanton ◽  
Paul H. Glaser ◽  
...  


2021 ◽  
Author(s):  
Denis Matiichine

One of the disposal methods for biosolids (nutrient rich organic matter that settles out of the wastewater during wastewater treatment process) is through application on agricultural fields as organic fertilizer. In order to determine the effects of runoff originating from biosolids treated fields on the nitrogen biogeochemical cycle and eutrophication of surface water, a lab-scale mesocosm experiment was carried out, simulating agricultural fields and thermally stratified water systems receiving agricultural runoff. A significant difference was found between the effects of the runoff from unfertilized soil plots and plots fertilized with biosolids. The findings indicate that the majority of incoming nitrogen is either denitrifed, lost to the sediment or is accumulated in the water column as nitrate. Further, it is hypothesised that the majority of incoming organic nitrogen was rapidly mineralized to ammonium in the hypolimnion, which has the potential to increase nitrogen bioavailability to primary producers in the epilimnion.



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