Micro-structure, Mechanical Properties and Dielectric Properties of Bisphenol A Allyl Compound-Bismaleimide Modified by Super-Critical Silica and Polyethersulfone Composite

2017 ◽  
Vol 46 (7) ◽  
pp. 4656-4661 ◽  
Author(s):  
Yufei Chen ◽  
Botao Wang ◽  
Fangliang Li ◽  
Chengjun Teng
2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Yufei Chen ◽  
Qiwang Dai ◽  
Xiwang Zhang ◽  
Tao Feng

SCE-Al2O3was the nano-Al2O3modified by supercritical ethanol and the surface of SCE-Al2O3was coated with active group. 4,4′-diaminodiphenylmethane bismaleimide (MBMI) was used as matrix; 3,3′-diallyl bisphenol A (BBA) and bisphenol-A diallyl ether (BBE) were used as reactive diluent, polyethersulfone (PES) as toughening agent, and SCE-Al2O3as modifier; SCE-Al2O3/PES-MBAE nanocomposite was prepared through in situ sol-gel method. The mechanism of composite toughened by PES was observed and analyzed. FTIR indicated that the reaction between MBMI and allyl compound occurred and SCE-Al2O3had doped into the polymer matrix. SEM showed that PES particle was inlaid in matrix and presented as a two-phase structure in matrix. The heat resistance, dielectric properties, and mechanical properties of SCE-Al2O3/PES-MBAE nanocomposites were evaluated. The results showed that with the incorporation of PES, although the toughness of the material improved, the heat resistance and dielectric properties of material declined, meanwhile. The adulteration of SCE-Al2O3could remedy the harmful effect caused by PES, while the content of SCE-Al2O3was reasonable. The decomposition temperature, dielectric constant, and dielectric loss of composite were 441.23°C, 3.63 (100 Hz), and 1.52 × 10−3(100 Hz); the bending strength and impact strength were 129.22 MPa and 13.19 kJ/mm2, respectively, when the content of SCE-Al2O3was 3 wt% and PES was 5 wt%.


2019 ◽  
Vol 16 (2) ◽  
Author(s):  
Amin Suhadi ◽  
Seodihono

Production technology of metal casting industry in Indonesia needs to be improved, especially in the manufacturing of spare parts and box engine made of gray cast iron which has various wall thick such as dove tale construction. Microstructure of gray cast iron is influenced by cooling rate during casting, chemical composition and melting treatment process (inoculation). The part which has the thinnest thickness has the fastest cooling therefore, the grain boundary is smaller compared to other section. As a result this part has highest hardness and difficult to be machined. This research is conducted to solve this problem by modifying melting and solidification treatment process. The research starting from micro structure analysis, composition and mechanical properties tests on the product, and then conducting modification treatment through Taguchi method approach. Experimental results obtained show that the best level settings to control factors which affect to the uniformity of the microstructure and mechanical properties in gray cast iron is the addition of seed inoculation super ® 75, as much as 0.25% with the method of inoculation material entering into the Transfer Ladle.Teknologi produksi pada industri pengecoran di Indonesia masih membutuhkan perbaikan terutama dalam pembuatan komponen mesin perkakas dan peralatan pabrik yang terbuat dari besi tuang kelabu yang mempunyai variasi ketebalan yang besar seperti konstruksi ekor burung (dove tale). Pada pengecoran, struktur mikro dari besi tuang kelabu sangat dipengaruhi oleh kecepatan pendinginan, komposisi kimia dan proses perlakuan pada logam cair (inokulasi). Bagian yang mempunyai ukuran paling tipis mempunyai kecepatan pendinigan paling tinggi karena itu ukuran butirnya jauh lebih kecil dari bagian lain, akibatnya bagian ini mempunyai kekerasan lebih tinggi dan sulit dilakukan pengerjaan mesin. Penelitian ini bertujuan untuk memperbaiki hal ini yang terjadi pada dove taledengan cara memodifikasi proses perlakuan pada cairan besi dan proses pendinginan. Penelitian dimulai dari analisa struktur mikro, pengujian komposisi kimia, pengujian sifat mekanis pada produk kemudian dilakukan modifikasi menggunakan pendekatan metode statistik Taguchi. Hasil penelitian menunjukkan bahwa pengaturan terbaik yang dapat diperoleh untuk mendapatkan keseragaman struktur mikro dan sifat mekanis pada pengecoran besi tuang kelabu adalah penambahan seed inoculation super ® 75, sebesar 0.25% dengan metode pemasukan inokulasi kedalam Ladle pengangkut logam cair.Keywords: carbon, micro structure, hardness, inoculation


2021 ◽  
Vol 2 (2) ◽  
pp. 419-430
Author(s):  
Ankur Bajpai ◽  
James R. Davidson ◽  
Colin Robert

The tensile fracture mechanics and thermo-mechanical properties of mixtures composed of two kinds of epoxy resins of different chemical structures and functional groups were studied. The base resin was a bi-functional epoxy resin based on diglycidyl ether of bisphenol-A (DGEBA) and the other resins were (a) distilled triglycidylether of meta-amino phenol (b) 1, 6–naphthalene di epoxy and (c) fluorene di epoxy. This research shows that a small number of multifunctional epoxy systems, both di- and tri-functional, can significantly increase tensile strength (14%) over neat DGEBA while having no negative impact on other mechanical properties including glass transition temperature and elastic modulus. In fact, when compared to unmodified DGEBA, the tri-functional epoxy shows a slight increase (5%) in glass transition temperature at 10 wt.% concentration. The enhanced crosslinking of DGEBA (90 wt.%)/distilled triglycidylether of meta-amino phenol (10 wt.%) blends may be the possible reason for the improved glass transition. Finally, the influence of strain rate, temperature and moisture were investigated for both the neat DGEBA and the best performing modified system. The neat DGEBA was steadily outperformed by its modified counterpart in every condition.


Author(s):  
Abhijit Sadhu ◽  
Sagar Sarkar ◽  
Angshuman Chattopadhyay ◽  
Omkar Mypati ◽  
Surjya K. Pal ◽  
...  

Author(s):  
Lubomir Anestiev ◽  
Jordan Georgiev ◽  
Seryozha Valkanov ◽  
Marcela Selecká ◽  
Sabine Cherneva ◽  
...  

Abstract The influence of the carbon introduction method on the microstructure and the mechanical properties of sinters produced from iron-based powders by diffusion-alloying sintering has been studied. Two methods of carbon introduction were tested: (1) Premixing of the base powder with graphite, and (2) Coating of the base powder with a carbon-containing substance. The results obtained could be summarized as (1) The microstructure and the mechanical properties depend on the method of carbon introduction; (2) The sinters produced from coated powders possess finer micro-structure, improved homogeneity, and in two out of three of the studied compositions, better mechanical properties. Based on the results obtained, a reasonable assumption was made that the method of carbon introduction affects the dissolution rate of the carbon additive, thus affecting the micro-structure and the mechanical properties of the sinter.


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