Effect of the Angle Between Sn Grain c-Axis and Electron Flow Direction on Cu-Reinforced Composite Solder Joints Under Current Stressing

2017 ◽  
Vol 47 (1) ◽  
pp. 96-102 ◽  
Author(s):  
Yan Wang ◽  
Jing Han ◽  
Yishu Wang ◽  
Limin Ma ◽  
Fu Guo
Keyword(s):  
Composite Solder ◽  
Solder Joints ◽  
Flow Direction ◽  
Electron Flow ◽  
Reinforced Composite ◽  
Current Stressing

scholarly journals The In-Situ Observation of Grain Rotation and Microstructure Evolution Induced by Electromigration in Sn-3.0Ag-0.5Cu Solder Joints

Materials ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 5497
Author(s):  
Xing Fu ◽  
Min Liu ◽  
KeXin Xu ◽  
Si Chen ◽  
YiJun Shi ◽  
...  
Keyword(s):  
Solder Joints ◽  
Flow Direction ◽  
Electron Flow ◽  
Critical Role ◽  
In Situ Observation ◽  
Fast Diffusion ◽  
Electron Backscattered Diffraction ◽  
Grain Rotation ◽  
Current Stressing

The in-situ observation of Sn-3.0Ag-0.5Cu solder joints under electromigration was conducted to investigate the microstructure and grain orientation evolution. It was observed that there was a grain rotation phenomenon during current stressing by in-situ electron backscattered diffraction (EBSD). The rotation angle was calculated, which indicated that the grain reorientation led to the decrease of the resistance of solder joints. On the other hand, the orientation of β-Sn played a critical role in determining the migration of Cu atoms in solder joints under current stressing migration. When the angle between the electron flow direction and the c-axis of Sn (defined as α) was close to 0°, massive Cu6Sn5 intermetallic compounds were observed in the solder bulk; however, when α was close to 90°, the migration of the intermetallic compound (IMC) was blocked but many Sn hillocks grew in the anode. Moreover, the low angle boundaries were the fast diffusion channel of Cu atoms while the high grain boundaries in the range of 55°–65° were not favorable to the fast diffusion of Cu atoms.

Performance of 96.5Sn–3Ag–0.5Cu/fullerene composite solder under isothermal ageing and high-current stressing

2020 ◽  
Vol 33 (1) ◽  
pp. 35-46 ◽  
Author(s):  
Guang Chen ◽  
Xinzhan Cui ◽  
Yaofeng Wu ◽  
Wei Li ◽  
Fengshun Wu
Keyword(s):  
Solder Joint ◽  
Composite Solder ◽  
Solder Joints ◽  
Experimental Results ◽  
High Current ◽  
Sac305 Solder ◽  
Content Type ◽  
Interfacial Imcs ◽  
Current Stressing ◽  
Isothermal Ageing

Purpose The purpose of this paper is to investigate the effect of fullerene (FNS) reinforcements on the microstructure and mechanical properties of 96.5Sn3Ag0.5Cu (SAC305) lead-free solder joints under isothermal ageing and electrical-migration (EM) stressing. Design/methodology/approach In this paper, SAC305 solder alloy doped with 0.1 Wt.% FNS was prepared via the powder metallurgy method. A sandwich-like sample and a U-shaped sample were designed and prepared to conduct an isothermal ageing test and an EM test. The isothermal ageing test was implemented under vacuum atmosphere at 150°C, whereas the EM experiment was carried out with a current density of 1.5 × 104 A/cm2. The microstructural and mechanical evolutions of both plain and composite solder joints after thermal ageing and EM stressing were comparatively studied. Findings A growth of Ag3Sn intermetallic compounds (IMCs) in solder matrix and Cu-Sn interfacial IMCs in composite solder joints was notably suppressed under isothermal ageing condition, whereas the hardness and shear strength of composite solder joints significantly outperformed those of non-reinforced solder joints throughout the ageing period. The EM experimental results showed that for the SAC305 solder, the interfacial IMCs formulated a protrusion at the anode after 360 h of EM stressing, whereas the surface of the composite solder joint was relatively smooth. During the stressing period, the interfacial IMC on the anode side of the plain SAC305 solder showed a continuous increasing trend, whereas the IMC at the cathode presented a decreasing trend for its thickness as the stressing time increased; after 360 h of stressing, some cracks and voids had formed on the cathode side. For the SAC305/FNS composite solder, a continuous increase in the thickness of the interfacial IMC was found on both the anode and cathode sides; the growth rate of the interfacial IMC at the anode was higher than that at the cathode. The nanoindentation results showed that the hardness of the SAC305 solder joint presented a gradient distribution after EM stressing, whereas the hardness data showed a relatively homogeneous distribution in the SAC305/FNS solder joint. Originality/value The experimental results showed that the FNS reinforcement could effectively mitigate the failure risk in solder joints under isothermal ageing and high-current stressing. Specifically, the FNS particles in solder joints can work as a barrier to suppress the diffusion and migration of Sn and Cu atoms. In addition, the nanoidentation results also indicated that the addition of the FNS reinforcement was very helpful in maintaining the mechanical stability of the solder joint. These findings have provided a theoretical and experimental basis for the practical application of this novel composite solder with high-current densities.

Effect of Sn Grain c-Axis on Cu Atomic Motion in Cu Reinforced Composite Solder Joints Under Electromigration

2020 ◽  
Vol 49 (3) ◽  
pp. 2159-2163 ◽  
Author(s):  
Yan Wang ◽  
Yishu Wang ◽  
Limin Ma ◽  
Jing Han ◽  
Fu Guo
Keyword(s):  
Composite Solder ◽  
Solder Joints ◽  
Atomic Motion ◽  
Reinforced Composite

Effect of electromigration on mechanical shear behavior of flip chip solder joints

2006 ◽  
Vol 21 (3) ◽  
pp. 698-702 ◽  
Author(s):  
Jae-Woong Nah ◽  
Fei Ren ◽  
Kyung-Wook Paik ◽  
K.N. Tu
Keyword(s):  
Flip Chip ◽  
Shear Failure ◽  
Solder Joints ◽  
Electron Flow ◽  
Shear Behavior ◽  
Cathode Side ◽  
Current Stressing ◽  
Large Growth ◽  
Electroless Ni ◽  
Solder Interface

Effect of electromigration on mechanical shear behavior of flip chip solder joints consisting of 97Pb3Sn and 37Pb63Sn composite solder joints was studied. The under bump metallurgy (UBM) on the chip side was TiW/Cu/electroplated Cu, and the bond pad on the board side was electroless Ni/Au. It was found that the mode of shear failure has changed after electromigration and the mode depends on the direction of electron flow during electromigration. The shear induced fracture occurs in the bulkof 97Pb3Sn solder without current stressing, however, after 10 h current stressing at 2.55 × 104 A/cm2 at 140 °C, it occurs alternately at the cathode interfaces between solder and intermetallic compounds (IMCs). In the downward electron flow, from the chip to substrate, the failure site was at the Cu–Sn IMC/solder interface near the Si chip. However, in the upward electron flow, from the substrate to chip, failure occurred at the Ni–Sn IMC/solder interface near the substrate. The failure mode has a strong correlation to microstructural change in the solder joint. During the electromigration, while Pb atoms moved to the anode side in the same direction as with the electron flow, Sn atoms diffused to the cathode side, opposite the electron flow. In addition, electromigration dissolves and drives Cu or Ni atoms from UBM or bond pad at the cathode side into the solder. These reactions resulted in the large growth of Sn-based IMC at the cathode sides. Therefore, mechanical shear failure occurs predominantly at the cathode interface.

Effects of Sn grain c-axis on electromigration in Cu reinforced composite solder joints

2018 ◽  
Vol 29 (7) ◽  
pp. 5954-5960 ◽  
Author(s):  
Yan Wang ◽  
Yishu Wang ◽  
Jing Han ◽  
Shihai Tan ◽  
Fu Guo
Keyword(s):  
Composite Solder ◽  
Solder Joints ◽  
Reinforced Composite

scholarly journals Study on the Reliability of Sn–Bi Composite Solder Pastes with Thermosetting Epoxy under Thermal Cycling and Humidity Treatment

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 733
Author(s):  
Lu Liu ◽  
Songbai Xue ◽  
Ruiyang Ni ◽  
Peng Zhang ◽  
Jie Wu
Keyword(s):  
Solder Joint ◽  
Thermal Cycling ◽  
Composite Solder ◽  
Solder Joints ◽  
Solder Paste ◽  
Epoxy System ◽  
Mechanical Reinforcement ◽  
Microstructure Observation ◽  
Temperature And Humidity ◽  
Thermosetting Epoxy

In this study, a Sn–Bi composite solder paste with thermosetting epoxy (TSEP Sn–Bi) was prepared by mixing Sn–Bi solder powder, flux, and epoxy system. The melting characteristics of the Sn–Bi solder alloy and the curing reaction of the epoxy system were measured by differential scanning calorimeter (DSC). A reflow profile was optimized based on the Sn–Bi reflow profile, and the Organic Solderability Preservative (OSP) Cu pad mounted 0603 chip resistor was chosen to reflow soldering and to prepare samples of the corresponding joint. The high temperature and humidity reliability of the solder joints at 85 °C/85% RH (Relative Humidity) for 1000 h and the thermal cycle reliability of the solder joints from −40 °C to 125 °C for 1000 cycles were investigated. Compared to the Sn–Bi solder joint, the TSEP Sn–Bi solder joints had increased reliability. The microstructure observation shows that the epoxy resin curing process did not affect the transformation of the microstructure. The shear force of the TSEP Sn–Bi solder joints after 1000 cycles of thermal cycling test was 1.23–1.35 times higher than the Sn–Bi solder joint and after 1000 h of temperature and humidity tests was 1.14–1.27 times higher than the Sn–Bi solder joint. The fracture analysis indicated that the cured cover layer could still have a mechanical reinforcement to the TSEP Sn–Bi solder joints after these reliability tests.

Effects of Current Stressing on Shear Properties of Sn-3.8Ag-0.7Cu Solder Joints

2010 ◽  
Vol 26 (8) ◽  
pp. 737-742 ◽  
Author(s):  
X.J. Wang ◽  
Q.L. Zeng ◽  
Q.S. Zhu ◽  
Z.G. Wang ◽  
J.K. Shang
Keyword(s):  
Solder Joints ◽  
Shear Properties ◽  
Current Stressing
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