scholarly journals Hydrogen Production via Hydrolysis and Alcoholysis of Light Metal-Based Materials: A Review

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Liuzhang Ouyang ◽  
Jun Jiang ◽  
Kang Chen ◽  
Min Zhu ◽  
Zongwen Liu
Keyword(s):  
Hydrogen Production ◽  
Large Scale ◽  
Fossil Fuels ◽  
Hydrogen Generation ◽  
Low Cost ◽  
Light Metal ◽  
Hydrogen Yield ◽  
Hydrogen Economy ◽  
The One ◽  
And Storage

AbstractAs an environmentally friendly and high-density energy carrier, hydrogen has been recognized as one of the ideal alternatives for fossil fuels. One of the major challenges faced by “hydrogen economy” is the development of efficient, low-cost, safe and selective hydrogen generation from chemical storage materials. In this review, we summarize the recent advances in hydrogen production via hydrolysis and alcoholysis of light-metal-based materials, such as borohydrides, Mg-based and Al-based materials, and the highly efficient regeneration of borohydrides. Unfortunately, most of these hydrolysable materials are still plagued by sluggish kinetics and low hydrogen yield. While a number of strategies including catalysis, alloying, solution modification, and ball milling have been developed to overcome these drawbacks, the high costs required for the “one-pass” utilization of hydrolysis/alcoholysis systems have ultimately made these techniques almost impossible for practical large-scale applications. Therefore, it is imperative to develop low-cost material systems based on abundant resources and effective recycling technologies of spent fuels for efficient transport, production and storage of hydrogen in a fuel cell-based hydrogen economy.

The Hydrogen Alternative

2015 ◽  
Vol 49 ◽  
pp. 15-26
Author(s):  
Debajyoti Bose
Keyword(s):  
Fuel Cells ◽  
Hydrogen Production ◽  
Everyday Life ◽  
Fossil Fuels ◽  
Hydrogen Economy ◽  
Deep Time ◽  
Free Gas ◽  
Energy Needs ◽  
Near Future ◽  
And Storage

Hydrogen is the cleanest fuel known to man and the most prominent alternative to carbon-based fuels, although it is not available as a free gas on earth, it can be produced from various sources using the correct combination of pressure and temperature. The deep time that our planet has given life has allowed it to grow from a tiny seed of genetic possibility to a planet wide web of complexity we are part of today, where today heating, refrigeration, telecommunication and appliances have become vital in everyday life. Production of electricity using fossil fuels has been under the scanner for quite some time now because of their availability and effects on the environment hydrogen emerges out in this scenario as the future fuel and setting the stage towards the hydrogen economy. The clean nature of hydrogen and the efficiency of fuel cells taken together offer an appealing alternative to fossil fuels. This paper reviews the existing infrastructure of hydrogen production and storage, while simultaneously explores the reason why it will be an inevitability in the near future to meet our ever increasing energy needs.

scholarly journals Hydrogen as a Clean Energy Source

2021 ◽  
Author(s):  
Vikram Rama Uttam Pandit
Keyword(s):  
Energy Source ◽  
Hydrogen Production ◽  
Large Scale ◽  
Fossil Fuels ◽  
Hydrogen Generation ◽  
Clean Energy ◽  
Green Energy ◽  
Main Challenge ◽  
Clean Energy Source ◽  
Energy Challenge

Sustainable development of the world is mainly dependent on the use of present energy resources, which primarily includes water, wind, solar, geothermal, and nuclear power. Hydrogen as a clean and green energy source can be the resolution of the energy challenge and may satisfy the demands of several upcoming generations. Hydrogen when used it does not produce any type of pollutant and this makes it a best candidate as a clean energy. Hydrogen energy can be generated from natural gas, oil, biomass, and fossil fuels using thermochemical, photocatalytic, microbiological and electrolysis processes. Large scale hydrogen production is also testified up to some extent with proper engineering for multi applications. Alas, storage and transportation of hydrogen are the main challenge amongst scientific community. Photocatalytic hydrogen production with good efficiencies and amount is well discussed. Till date, using a variety of metal oxide-sulfide, carbon-based materials, metal organic frameworks are utilized by doping or with their composites for enhance the hydrogen production. Main intents of this chapter are to introduce all the possible areas of hydrogen applications and main difficulties of hydrogen transportation, storage and achievements in the hydrogen generation with its applications.

scholarly journals Solar Thermochemical Hydrogen Production in the USA

2021 ◽  
Vol 13 (14) ◽  
pp. 7804
Author(s):  
Christoph Falter ◽  
Andreas Sizmann
Keyword(s):  
Hydrogen Production ◽  
Large Scale ◽  
Low Cost ◽  
The United States ◽  
Solar Irradiation ◽  
Transport Sector ◽  
Fossil Energy ◽  
The Us ◽  
The Usa ◽  
Solar Thermochemical

Hydrogen produced from renewable energy has the potential to decarbonize parts of the transport sector and many other industries. For a sustainable replacement of fossil energy carriers, both the environmental and economic performance of its production are important. Here, the solar thermochemical hydrogen pathway is characterized with a techno-economic and life-cycle analysis. Assuming a further increase of conversion efficiency and a reduction of investment costs, it is found that hydrogen can be produced in the United States of America at costs of 2.1–3.2 EUR/kg (2.4–3.6 USD/kg) at specific greenhouse gas emissions of 1.4 kg CO2-eq/kg. A geographical potential analysis shows that a maximum of 8.4 × 1011 kg per year can be produced, which corresponds to about twelve times the current global and about 80 times the current US hydrogen production. The best locations are found in the Southwest of the US, which have a high solar irradiation and short distances to the sea, which is beneficial for access to desalinated water. Unlike for petrochemical products, the transport of hydrogen could potentially present an obstacle in terms of cost and emissions under unfavorable circumstances. Given a large-scale deployment, low-cost transport seems, however, feasible.

Opportunities and Challenges in Converting Existing Natural Gas Infrastructure for Hydrogen Operation

2021 ◽  
Author(s):  
Peter Adam
Keyword(s):  
Hydrogen Production ◽  
Natural Gas ◽  
Energy Transition ◽  
Building Blocks ◽  
Hydrogen Economy ◽  
Storage Network ◽  
The World ◽  
Drive Trains ◽  
Regulatory Bodies ◽  
And Storage

Abstract Hydrogen holds enormous potential in helping the world achieve its decarbonization goals and is set to play a key role in the Energy Transition. However, two central building blocks are needed to make the hydrogen economy a reality: 1) a sufficient source of emissions-free (i.e., blue or green) hydrogen production and 2) a needs-based transportation and storage network that can reliably and cost-effectively supply hydrogen to end-users. Given the high costs associated with developing new transportation infrastructure, many governments, pipeline operators, and regulatory bodies have begun exploring if it is both possible and economical to convert existing natural gas (i.e., methane) infrastructure for hydrogen operation. This paper outlines opportunities and technical challenges associated with such an endeavor – with a particular focus on adaptation requirements for rotating equipment/compressor drive trains and metallurgical and integrity considerations for pipelines.

Techno-Economic Assessment of Utilizing Wind Energy for Hydrogen Production Through Electrolysis

2017 ◽  
Author(s):  
Reza Ziazi ◽  
Kasra Mohammadi ◽  
Navid Goudarzi
Keyword(s):  
Hydrogen Production ◽  
Wind Energy ◽  
Wind Turbines ◽  
Alternative Energy ◽  
Large Scale ◽  
Fossil Fuels ◽  
Combustion Engine ◽  
Economic Assessment ◽  
Large Cities ◽  
North East

Hydrogen as a clean alternative energy carrier for the future is required to be produced through environmentally friendly approaches. Use of renewables such as wind energy for hydrogen production is an appealing way to securely sustain the worldwide trade energy systems. In this approach, wind turbines provide the electricity required for the electrolysis process to split the water into hydrogen and oxygen. The generated hydrogen can then be stored and utilized later for electricity generation via either a fuel cell or an internal combustion engine that turn a generator. In this study, techno-economic evaluation of hydrogen production by electrolysis using wind power investigated in a windy location, named Binaloud, located in north-east of Iran. Development of different large scale wind turbines with different rated capacity is evaluated in all selected locations. Moreover, different capacities of electrolytic for large scale hydrogen production is evaluated. Hydrogen production through wind energy can reduce the usage of unsustainable, financially unstable, and polluting fossil fuels that are becoming a major issue in large cities of Iran.

scholarly journals Research on hydrogen generation from rapid hydrolysis of aluminum in sodium fluoride solution

2019 ◽  
Vol 118 ◽  
pp. 03048
Author(s):  
Changchun Li ◽  
Yuxin Wu
Keyword(s):  
Hydrogen Production ◽  
Kinetic Model ◽  
Sodium Fluoride ◽  
Hydrogen Generation ◽  
Hydrogen Yield ◽  
Shrinking Core Model ◽  
Fluoride Solution ◽  
Shrinking Core ◽  
Rapid Hydrolysis ◽  
Hydrolysis Of

Hydrogen generation from rapid hydrolysis of aluminum in sodium fluoride solution was investigated through a hydrolysis experiment. Rapid and instant hydrogen yield were observed using sodium fluoride as additive. The experimental results demonstrate that the increase of temperature and the amount of additives in a certain range will boost the hydrogen production. The amount of additives outside the range only has an effect on the rapid hydrolysis of the aluminum during the initial stage, but the total amount of hydrogen produced doesn’t increased significantly. Theoretical analysis of the effects of the mixing ratio and the temperature on the hydrogen production rates were performed using the shrinking core model and the kinetic model. The shrinking core model parameter a and k indicate the film change degree of porosity and thickness and the effect of time on the diffusion coefficient. the kinetic model is verified and the activation energy confirming hydrogen yield control by a molecular diffusion process. Correspondingly, mechanisms of Al corrosion in NaF solutions under low and high alkalinity were proposed, respectively.

A review of transition-metal boride/phosphide-based materials for catalytic hydrogen generation from hydrolysis of boron-hydrides

2018 ◽  
Vol 5 (4) ◽  
pp. 760-772 ◽  
Author(s):  
Hongming Sun ◽  
Jing Meng ◽  
Lifang Jiao ◽  
Fangyi Cheng ◽  
Jun Chen
Keyword(s):  
Transition Metal ◽  
Hydrogen Generation ◽  
Metal Boride ◽  
Hydrogen Economy ◽  
Boron Hydrides ◽  
Catalytic Hydrogen ◽  
And Storage ◽  
Hydrolysis Of ◽  
Essential Prerequisite

Efficient hydrogen generation and storage is an essential prerequisite of a future hydrogen economy.

Graphite Electrodes for Hydrogen Production by Acid Electrolysis

2020 ◽  
Vol 1012 ◽  
pp. 158-163
Author(s):  
Oliveira Marilei de Fátima ◽  
Mazur Viviane Teleginski ◽  
Virtuozo Fernanda ◽  
Junior Valter Anzolin de Souza
Keyword(s):  
Hydrogen Production ◽  
Fossil Fuels ◽  
High Efficiency ◽  
Low Cost ◽  
Electric Energy ◽  
Gas Production ◽  
Hydrogen Fuel Cells ◽  
Graphite Electrodes ◽  
Alkaline Electrolysis ◽  
Selection Of

Nowadays, humanity has become aware of the consequences that the use of fossil fuels entails, and the latest developments in the energy sector are leading to a diversification of energy resources. In this context, researching on alternative forms of producing electric energy is being conducted. At the transportation level, a possible solution for this matter may lie in hydrogen fuel cells. The electrolysis of water is one of the possible processes for hydrogen production, but the reaction to break the water molecule requires a great amount of energy and this is precisely the biggest issue involving this process. In this work, low cost electrodes of 254 stainless steel and electrolytic graphite were used for hydrogen production, allowing high efficiency and reduced oxidation during the process. The selection of these materials allows to obtain a high corrosion resistance electrolytic pair, by replacing the high cost platinum electrode usually employed in the alkaline electrolysis process. The formic acid of biomass origin was used as an electrolyte. It was observed that the developed reactor have no energy losses through heat and it was possible to obtain approximately 82% conversion efficiency in the gas production process.

A Novel Chemical-Looping Hydrogen Generation System With Multi-Input Fossil Fuels

2013 ◽  
Author(s):  
Xiaosong Zhang ◽  
Hongguang Jin
Keyword(s):  
Hydrogen Production ◽  
Natural Gas ◽  
Fossil Fuels ◽  
Hydrogen Generation ◽  
Chemical Looping ◽  
Generation System ◽  
System A ◽  
Energy Penalty ◽  
Burning Coal ◽  
Chemical Looping Hydrogen Generation

This paper proposes a multi-input chemical looping hydrogen generation system (MCLH), which generates hydrogen, through the use of natural gas and coal. In this system, a new type of oven, burning coal instead of natural gas as heating resource for hydrogen production reaction, is adopted. Coal can be converted to hydrogen indirectly without gasification. Benefits from the chemical looping process, the CO2 can be captured without energy penalty. With the same inputs of fuel, the new system can product about 16% more hydrogen than that of individual systems. As a result, the energy consumption of the hydrogen production is about 165J/mol-H2. Based on the exergy analyses, it is disclosed that the integration of synthetic utilization of natural gas and coal plays a significant role in reducing the exergy destruction of the MCLH system. The promising results obtained may lead to a clean coal technology that will utilize natural gas and coal more efficiently and economically.

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