Characterization of the structure of porous silver films by optical measurements in the near infrared

1986 ◽  
Vol 166 (1) ◽  
pp. L126-L130
Author(s):  
H.-U. Finzel ◽  
P. Wissmann ◽  
E. Wittmann
2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Olivier Carton ◽  
Jaouad Ghaymouni ◽  
Michaël Lejeune ◽  
Andreas Zeinert

The optical properties of various porous silver films, grown with a commercial DC sputter coater, were investigated and compared for different plasma parameters. Effective Drude models were successfully used for those films whose spectra did not show particular resonance peaks. For the other films, neither an effective Drude model nor effective medium models (Maxwell Garnett, Bruggeman, and Looyenga) can describe the optical properties. It turns out that a more general approach like the Bergman representation describes the optical data of these films accurately adopting porosity values consistent with physical measurements.


Sensors ◽  
2018 ◽  
Vol 18 (11) ◽  
pp. 3755 ◽  
Author(s):  
Mariano Gioffré ◽  
Giuseppe Coppola ◽  
Mario Iodice ◽  
Maurizio Casalino

This paper presents the design, fabrication, and characterization of Schottky erbium/silicon photodetectors working at 1.55 µm. These erbium/silicon junctions are carefully characterized using both electric and optical measurements at room temperature. A Schottky barrier ΦB of ~673 meV is extrapolated; the photodetectors show external responsivity of 0.55 mA/W at room temperature under an applied reverse bias of 8 V. In addition, the device performance is discussed in terms of normalized noise and noise-equivalent power. The proposed devices will pave the way towards the development of Er-based photodetectors and light sources to be monolithically integrated in the same silicon substrate, and both operating at 1.55 µm.


2019 ◽  
Vol 10 ◽  
pp. 1973-1982 ◽  
Author(s):  
William W Bryan ◽  
Riddhiman Medhi ◽  
Maria D Marquez ◽  
Supparesk Rittikulsittichai ◽  
Michael Tran ◽  
...  

This paper describes the preparation and characterization of a new type of core–shell nanoparticle in which the structure consists of a hydrogel core encapsulated within a porous silver shell. The thermo-responsive hydrogel cores were prepared by surfactant-free emulsion polymerization of a selected mixture of N-isopropylacrylamide (NIPAM) and acrylic acid (AAc). The hydrogel cores were then encased within either a porous or complete silver shell for which the localized surface plasmon resonance (LSPR) extends from visible to near-infrared (NIR) wavelengths (i.e., λmax varies from 550 to 1050 nm, depending on the porosity), allowing for reversible contraction and swelling of the hydrogel via photothermal heating of the surrounding silver shell. Given that NIR light can pass through tissue, and the silver shell is porous, this system can serve as a platform for the smart delivery of payloads stored within the hydrogel core. The morphology and composition of the composite nanoparticles were characterized by SEM, TEM, and FTIR, respectively. UV–vis spectroscopy was used to characterize the optical properties.


Author(s):  
Mariano Gioffrè ◽  
Giuseppe Coppola ◽  
Mario Iodice ◽  
Maurizio Casalino

This paper presents the design, fabrication and characterization of Schottky erbium/silicon photodetectors working at 1.55 µm. These erbium/silicon junctions are carefully characterized using both electric and optical measurements at room temperature. A Schottky barrier ΦB of ~673 meV is extrapolated; the photodetectors show external responsivity of 0.55 mA/W at room temperature under a 8 V of reverse bias applied. In addition, the device performance is discussed in terms of normalized noise and noise equivalent power. To the best of our knowledge, these are the first Er/Si photodetectors designed for operation in free space at 1.55 µm. The proposed devices will pave the way towards development of Er-based photodetectors and light sources to be monolithically integrated in the same silicon substrate and both operating at 1.55 µm.


1991 ◽  
Vol 240 ◽  
Author(s):  
Lei Wang ◽  
N. M. Haegel

ABSTRACTOptical measurements have been performed on heavily carbon doped GaAs layers grown on semi-insulating GaAs substrates by MOMBE (metal-organic molecule beam epitaxy). Photoluminescence excitation (PLE) spectroscopy was used to measure the onsets of optical absorption in these GaAs:C epilayers. It was found that in samples with free carrier concentrations of 6.2×1019, 1.6×1020, and 4.1×1020cm−3, optical absorption begins at 1.40, 1.52, and 1.53 ev, respectively. Combined with the band gap narrowing data from photoluminescence (PL) spectra, we estimated Fermi level locations relative to the top of the valence band. We also measured reflectance in the near infrared region and estimated the effective mass of free holes using a classical two-oscillator model.


Author(s):  
W. E. Lee

An optical waveguide consists of a several-micron wide channel with a slightly different index of refraction than the host substrate; light can be trapped in the channel by total internal reflection.Optical waveguides can be formed from single-crystal LiNbO3 using the proton exhange technique. In this technique, polished specimens are masked with polycrystal1ine chromium in such a way as to leave 3-13 μm wide channels. These are held in benzoic acid at 249°C for 5 minutes allowing protons to exchange for lithium ions within the channels causing an increase in the refractive index of the channel and creating the waveguide. Unfortunately, optical measurements often reveal a loss in waveguiding ability up to several weeks after exchange.


2018 ◽  
Author(s):  
Dinesh Mishra ◽  
Sisi Wang ◽  
Zhicheng Jin ◽  
Eric Lochner ◽  
Hedi Mattoussi

<p>We describe the growth and characterization of highly fluorescing, near-infrared-emitting nanoclusters made of bimetallic Au<sub>25-x</sub>Ag<sub>x</sub> cores, prepared using various monothiol-appended hydrophobic and hydrophilic ligands. The reaction uses well-defined triphenylphosphine-protected Au<sub>11</sub> clusters (as precursors), which are reacted with Ag(I)-thiolate complexes. The prepared nanoclusters are small (diameter < 2nm, as characterized by TEM) with emission peak at 760 nm and long lifetime (~12 µs). The quantum yield measured for these materials was 0.3 - 0.4 depending on the ligand. XPS measurements show the presence of both metal atoms in the core, with measured binding energies that agree with reported values for nanocluster materials. The NIR emission combined with high quantum yield, small size and ease of surface functionalization afforded by the coating, make these materials suitable to implement investigations that address fundamental questions and potentially useful for biological sensing and imaging applications.<br></p>


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