Mineralization parameters from organic materials added to soil as a function of their chemical composition

Soil samples were obtained from the surface horizons of five untilled sites and adjacent sites under short- and long-term cultivation. The soil samples were fractionated based on density and organic materials were concentrated in various fractions which enabled comparative chemical composition of the organic materials in cultivated and uncultivated sites by solid-state C-13 CP/MAS NMR spectroscopy. Changes in the nature of organic carbon with cultivation were different in different soils and resulted from variations in the chemistry of carbon inputs to the soils and a greater extent of decomposition of organic materials in cultivated soils. Differences in the chemical composition of organic carbon between cultivated and uncultivated soils resided mostly in organic materials occluded within aggregates, whereas the chemistry of organic matter associated with clay particles showed only small changes. The results indicate a faster decomposition of O-alkyl C in the cultivated soils. Wet aggregate stability, mechanically dispersible clay and modulus of rupture tests were used to assess the effects of cultivation on structural stability of soils. In four of five soils, the virgin sites and sites which had been under long-term pasture had a greater aggregate stability than the cultivated sites. Neither total organic matter nor total O-alkyl C content was closely correlated with aggregate stability, suggesting that only a part of soil carbon or carbohydrate is involved in aggregate stability. The fractions of carbon and O-alkyl C present in the form of particulate organic matter occluded within aggregates were better correlated with aggregate stability (r = 0.86** and 0.88**, respectively). Cultivation was not the dominant factor influencing water-dispersible clay across the range of soil types used in this study. The amount of dispersible clay was a function of total clay content and the percentage of clay dispersed was controlled by factors such as clay mineralogy, CaCO3 and organic matter content of soils. The tendency of different soils for hard-setting and crusting, as a result of structural collapse, was reflected in the modulus of rupture (MOR). The cultivated sites had significantly higher MOR than their non-tilled counterparts. The soils studied had different MOR due to differences in their physical and chemical properties.

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Assessing the extent of decomposition of natural organic materials using solid-state 13C NMR spectroscopy

Soil Research ◽

10.1071/s97004 ◽

1997 ◽

Vol 35 (5) ◽

pp. 1061 ◽

Cited By ~ 428

Author(s):

J. A. Baldock ◽

J. M. Oades ◽

P. N. Nelson ◽

T. M. Skene ◽

A. Golchin ◽

...

Keyword(s):

Chemical Composition ◽

Solid State ◽

Nmr Spectroscopy ◽

13C Nmr ◽

Organic Materials ◽

Chemical Changes ◽

Diverse Range ◽

Sensitive Index ◽

Mineral Soils ◽

Solid State 13C Nmr

Solid-state 13C nuclear magnetic resonance (NMR) spectroscopy has become an important tool for examining the chemical structure of natural organic materials and the chemical changes associated with decomposition. In this paper, solid-state 13C NMR data pertaining to changes in the chemical composition of a diverse range of natural organic materials, including wood, peat, composts, forest litter layers, and organic materials in surface layers of mineral soils, were reviewed with the objective of deriving an index of the extent of decomposition of such organic materials based on changes in chemical composition. Chemical changes associated with the decomposition of wood varied considerably and were dependent on a strong interaction between the species of wood examined and the species composition of the microbial decomposer community, making the derivation of a single general index applicable to wood decomposition unlikely. For the remaining forms of natural organic residues, decomposition was almost always associated with an increased content of alkyl C and a decreased content of O-alkyl C. The concomitant increase and decrease in alkyl and O-alkyl C contents, respectively, suggested that the ratio of alkyl to O-alkyl carbon (A/O-A ratio) may provide a sensitive index of the extent of decomposition. Contrary to the traditional view that humic substances with an aromatic core accumulate as decomposition proceeds, changes in the aromatic region were variable and suggested a relationship with the activity of lignin-degrading fungi. The A/O-A ratio did appear to provide a sensitive index of extent of decomposition provided that its use was restricted to situations where the organic materials were derived from a common starting material. In addition, the potential for adsorption of highly decomposable materials on mineral soil surfaces and the impacts which such an adsorption may have on bioavailability required consideration when the A/O-A ratio was used to assess the extent of decomposition of organic materials found in mineral soils.

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Chemical Composition of Dust Expected from Condensation Models

International Astronomical Union Colloquium ◽

10.1017/s025292110006721x ◽

1991 ◽

Vol 126 ◽

pp. 413-420

Author(s):

Tetsuo Yamamoto

Keyword(s):

Chemical Composition ◽

Chemical Equilibrium ◽

Organic Materials ◽

Equilibrium Models ◽

Grain Composition ◽

Volatile Solids ◽

Equilibrium Calculations

AbstractThis review examines to what degrees the present chemical equilibrium condensation models are effective in predicting chemical composition of grains observed in a variety of cosmic environments. The composition expected from the equilibrium calculations is reviewed separately for refractory (rocky and metallic) and volatile (icy) components. Comments are given on the limitation of the equilibrium calculations in predicting the grain composition. By taking cometary ice as a typical cosmic volatile condensate, it is pointed out that its composition is far from that expected from the equilibrium models. Theories on the formation of cometary volatiles are reviewed, and an observational clue helpful to testing the theories is pointed out. Discussion is given on the advantage for formation of organic materials from volatile solids.

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Impact of the chemical composition of applied organic materials on bacterial and archaeal community compositions in paddy soil

Biology and Fertility of Soils ◽

10.1007/s00374-022-01619-y ◽

2022 ◽

Author(s):

Sharmin Akter Chowdhury ◽

Aya Kaneko ◽

Md Zakaria Ibne Baki ◽

Chikako Takasugi ◽

Natsumi Wada ◽

...

Keyword(s):

Chemical Composition ◽

Paddy Soil ◽

Organic Materials ◽

Archaeal Community

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Bone Chemical Composition Assessment with Multi-Wavelength Photoacoustic Analysis

Applied Sciences ◽

10.3390/app10228214 ◽

2020 ◽

Vol 10 (22) ◽

pp. 8214

Author(s):

Ting Feng ◽

Yunhao Zhu ◽

Kenneth M. Kozloff ◽

Basma Khoury ◽

Yejing Xie ◽

...

Keyword(s):

Chemical Composition ◽

Optical Absorption ◽

Organic Materials ◽

Spectral Unmixing ◽

Chemical Components ◽

Bone Specimen ◽

Non Invasive ◽

Multi Wavelength ◽

Metabolic Activities ◽

Invasive Evaluation

In this study, the feasibility of assessing the chemical composition in bone using the multi-wavelength photoacoustic analysis (MWPA) method was investigated. By illuminating a bone specimen using laser light with a wavelength tunable over an optical spectrum from 680 nm to 950 nm, the optical absorption spectrum of the bone was acquired. Then, with the optical absorption spectra of all the optically absorbing chemical components in the bone known, a spectral unmixing procedure was performed to quantitatively assess the relative content of each chemical component. The experimental results from porcine rib bones demonstrated that the contents of the chemical components, including not only non-organic materials such as minerals and water but also organic materials including oxygenated hemoglobin, deoxygenated hemoglobin, lipid, and collagen, can all be assessed by MWPA. As the chemical composition in the bone is directly associated with functional and metabolic activities, the finding from this study suggests that the MWPA method could offer a new diagnostic tool for the non-invasive evaluation of bone health.

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The Origin of the Moon

Symposium - International Astronomical Union ◽

10.1017/s0074180900178209 ◽

1962 ◽

Vol 14 ◽

pp. 149-155 ◽

Cited By ~ 1

Author(s):

E. L. Ruskol

Keyword(s):

Chemical Composition ◽

Solar System ◽

The Moon ◽

The Earth ◽

The Difference ◽

Origin Of The Moon

The difference between average densities of the Moon and Earth was interpreted in the preceding report by Professor H. Urey as indicating a difference in their chemical composition. Therefore, Urey assumes the Moon's formation to have taken place far away from the Earth, under conditions differing substantially from the conditions of Earth's formation. In such a case, the Earth should have captured the Moon. As is admitted by Professor Urey himself, such a capture is a very improbable event. In addition, an assumption that the “lunar” dimensions were representative of protoplanetary bodies in the entire solar system encounters great difficulties.

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On the Inhomogeneity of Chemical Composition over the Surface of 21 Per

International Astronomical Union Colloquium ◽

10.1017/s0252921100080659 ◽

1976 ◽

Vol 32 ◽

pp. 343-349

Author(s):

Yu.V. Glagolevsky ◽

K.I. Kozlova ◽

V.S. Lebedev ◽

N.S. Polosukhina

Keyword(s):

Chemical Composition ◽

Spectral Line ◽

Variable Star ◽

Radial Velocities ◽

Crimean Astrophysical Observatory ◽

Line Intensities ◽

Magnetic Variable

SummaryThe magnetic variable star 21 Per has been studied from 4 and 8 Å/mm spectra obtained with the 2.6 - meter reflector of the Crimean Astrophysical Observatory. Spectral line intensities (Wλ) and radial velocities (Vr) have been measured.

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Structural Studies on Mitotic Spindle Fibres

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100070345 ◽

1978 ◽

Vol 36 (3) ◽

pp. 615-626

Author(s):

J.R. Mcintosh

Keyword(s):

Chemical Composition ◽

Mitotic Spindle ◽

Structural Studies ◽

Mitotic Apparatus ◽

Chemical Studies ◽

Medical Interest ◽

Spindle Fibres

The mitotic apparatus is a structure of obvious biological and medical interest, but it has proved to be a difficult cellular machine to understand. The chemical composition of the spindle is only slightly elucidated, largely because of the difficulties in preparing useful isolates of the structure. Chemical studies of the mitotic spindle have been reviewed elsewhere (Mcintosh, 1977), and will not be discussed further here. One would think that structural studies on the mitotic apparatus (MA) in situ would be straightforward, but even with this approach there is some disagreement in the results obtained with various methods and by different investigators. In this paper I will review briefly the approaches which have been used in structural studies of the MA, pointing out the strengths and problems of each approach. I will summarize the principal findings of the different methods, and identify what seem to be fruitful avenues for further work.

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Effects of 5-5'-Diphenyl-2-thiohydantoin (DPTH) and Thyroxine on the Ultrastructure and Chemical Composition of Rat Liver

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100066917 ◽

1971 ◽

Vol 29 ◽

pp. 570-571

Author(s):

E. A. Elfont ◽

R. B. Tobin ◽

D. G. Colton ◽

M. A. Mehlman

Keyword(s):

Chemical Composition ◽

Rat Liver ◽

Future Study ◽

Mode Of Action ◽

Liver Mitochondria ◽

Rat Liver Mitochondria ◽

Effective Inhibitor ◽

Biochemical Effects ◽

Glycerophosphate Dehydrogenase ◽

Stimulation Of

Summary5,-5'-diphenyl-2-thiohydantoin (DPTH) is an effective inhibitor of thyroxine (T4) stimulation of α-glycerophosphate dehydrogenase in rat liver mitochondria. Because this finding indicated a possible tool for future study of the mode of action of thyroxine, the ultrastructural and biochemical effects of DPTH and/or thyroxine on rat liver mere investigated.Rats were fed either standard or DPTH (0.06%) diet for 30 days before T4 (250 ug/kg/day) was injected. Injection of T4 occurred daily for 10 days prior to sacrifice. After removal of the liver and kidneys, part of the tissue was frozen at -50°C for later biocheailcal analyses, while the rest was prefixed in buffered 3.5X glutaraldehyde (390 mOs) and post-fixed in buffered 1Z OsO4 (376 mOs). Tissues were embedded in Araldlte 502 and the sections examined in a Zeiss EM 9S.Hepatocytes from hyperthyroid rats (Fig. 2) demonstrated enlarged and more numerous mitochondria than those of controls (Fig. 1). Glycogen was almost totally absent from the cytoplasm of the T4-treated rats.

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Application of Improved Voltage Compensation in the SEM to Imaging of Organic Materials

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100072666 ◽

1973 ◽

Vol 31 ◽

pp. 444-445

Author(s):

P.J. Killingworth ◽

M. Warren

Keyword(s):

Electron Beam ◽

Organic Materials ◽

Operating Parameters ◽

Low Density ◽

Beam Diameter ◽

Incident Electron Beam ◽

Specimen Material ◽

Voltage Compensation ◽

Selection Of ◽

Scanning Electron

Ultimate resolution in the scanning electron microscope is determined not only by the diameter of the incident electron beam, but by interaction of that beam with the specimen material. Generally, while minimum beam diameter diminishes with increasing voltage, due to the reduced effect of aberration component and magnetic interference, the excited volume within the sample increases with electron energy. Thus, for any given material and imaging signal, there is an optimum volt age to achieve best resolution.In the case of organic materials, which are in general of low density and electric ally non-conducting; and may in addition be susceptible to radiation and heat damage, the selection of correct operating parameters is extremely critical and is achiev ed by interative adjustment.

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