scholarly journals New alternative energy pathway for chemical pulp mills: From traditional fibers to methane production

2017 ◽  
Vol 235 ◽  
pp. 265-273 ◽  
Author(s):  
Lourdes Rodriguez-Chiang ◽  
Kari Vanhatalo ◽  
Jordi Llorca ◽  
Olli Dahl
2016 ◽  
Vol 133 ◽  
pp. 953-964 ◽  
Author(s):  
Teemu Kinnarinen ◽  
Mohammad Golmaei ◽  
Eeva Jernström ◽  
Antti Häkkinen
Keyword(s):  

1988 ◽  
Vol 20 (2) ◽  
pp. 153-160 ◽  
Author(s):  
Filipe de Sousa ◽  
Lars M. Strömberg ◽  
Knut P. Kringstad

Sediments collected at various distances from pulp mills producing bleached chemical pulp were characterized with respect to the presence of chlorinated material extractable by hexane/isopropanol. Also the presence of chlorinated high molecular weight material from spent bleach liquors was investigated by oxidative degradation. The results show that the major part of the hexane/isopropanol soluble material in sediments differs from that in spent bleach liquors. This suggests that this material originates from sources other than spent bleach liquors or is formed by chemical and/or biological transformations of such material. However, the sediments do contain small quantities of chlorinated phenolic compounds and high molecular weight material originating from spent bleach liquors.


2017 ◽  
Vol 142 ◽  
pp. 977-983 ◽  
Author(s):  
Muhammad Naqvi ◽  
Erik Dahlquist ◽  
Abdul-Sattar Nizami ◽  
Muhammad Danish ◽  
Salman Naqvi ◽  
...  

2018 ◽  
Vol 33 (3) ◽  
pp. 420-429 ◽  
Author(s):  
Teemu Kinnarinen ◽  
Mohammad Golmaei ◽  
Eeva Jernström ◽  
Antti Häkkinen

Abstract Green liquor dregs represent the most important inorganic residue of chemical pulp mills. The dregs are usually settled in thickeners, washed and deliquored with lime mud precoat filters, and transported to the landfill. The utilization of dregs is challenging, due to the high concentration of hazardous trace elements (HTE) in their solid phase. There are basically two potential strategies for the reduction of the HTE content of dregs: mechanical classification according to differences in the size and density of particles, and removal of HTE by various chemical treatments. The objective of this study was to evaluate the applicability of straightforward mechanical separation methods for the purification of dregs from HTE. The evaluated separation methods included particle size–based classification by sieving, and classification on the basis of differences in the settling properties of particles in gravitational and centrifugal separation. It can be concluded that all the evaluated separation methods could be used to reduce the HTE content of dregs, although the separation efficiency was not very high in most cases. Centrifugation had clearly the best performance of the investigated techniques. The fractions consisting of large particles contained consistently lower concentrations of HTE, compared to fractions containing a lot of fines.


2016 ◽  
Vol 94 (suppl_5) ◽  
pp. 111-112
Author(s):  
P. Del Bianco Benedeti ◽  
T. Shenkoru ◽  
M. Fonseca ◽  
R. Bittner ◽  
K. Murphy ◽  
...  

Author(s):  
Alexandra Leshchinskaya

MICROWAVE WOOD CHIP TREATMENT USE IN CHEMICAL PULP MANUFACTURING   (TECHNICAL-ECONOMIC ASSESMENT)   A. Leshchinskaya   Plekhanov Russian University of Economics. 36 Stremyannyy Pereulok, 115093 Moscow, Russia, e-mail: [email protected]]   Keywords: chemical pulping, microwave wood modification, pulp, softwood, wood chips.   Large volumes of cellulose are produced from wood chips by chemical methods. Low permeability of many wood species causes problems in the chemical pulp industry. These include: very long cooking times, high chemical consumption, large material losses, high energy consumption, and environmental pollution. New microwave (MW) wood modification technology can provide an increase in wood permeability for liquids and gases, which solves many of these problems. The technology works  by applying intensive MW power to green wood, which generates steam pressure within wood cells. High internal pressure destroys weak elements of wood structure, opens pores and forms micro and macro cracks. A several thousand-fold increase in wood permeability can be achieved in species previously found to be impermeable to liquids and gases. It allows a significant increase in the speed of pulp cooking and improves a production processes. The study of the technology showed radical potential improvements in the pulp industry through: increase in mill throughput significant reduction of chemical consumptionreduction of energy consumption •     increase in pulp quality and yield improvement of environmental performance.   Pulp manufacturing process includs timber chipping, microwave chip treatment, steaming, cooking, washing, and pulp making. The use of MW wood chip treatment in pulp mills with outputs of 50,000 to 500,000 air dry tons (ADT) per year requires MW equipment with power from 1000 to 10,000 kW. Economic modelling of this technology used in different pulp mill conditions allowed assessment of the effect of capital costs, electricity costs, labour costs and other cost components to specific total costs of MW chip processing. Economic assessment of MW technology application showed that specific costs of softwood chip processing at electricity costs of 0.08 - 0.12 US$/kWh are 25.4 -33.7 US$/ADT of pulp. Electricity costs form the most significant part of the total specific costs of MW processing and form 51-69% shear in the total specific costs. Under the same conditions capital costs form 15-20% shear, and labour costs form 5-18% shear of the total specific costs. The electricity cost increase from $0.04 to $0.24/kWh provides specific MW processing cost rise by 2.7 to 3.1 times at pulp mill output range 50,000 to 500,000 ADT/year. New technology use allows benefits up to 7 – 22 Mil US$ per year for pulp mills with output of more than 200,000 ADT/year. The technology can be used by pulp mills with batch and continuous digesting and is not limited by mill throughput. Ecological impacts and high economic advantages of this MW technology application in pulp and paper industry provide good opportunity for commercialisation.  


TAPPI Journal ◽  
2019 ◽  
Vol 18 (9) ◽  
pp. 547-555
Author(s):  
IOANNIS DOGARIS ◽  
MIKAEL LINDSTROM ◽  
GUNNAR HENRIKSSON

Tall oil is a valuable byproduct in chemical pulping of wood, and its fractions have a large spectrum of applications as chemical precursors, detergents, and fuel. High recovery of tall oil is important for the economic and environmental profile of chemical pulp mills. The purpose of this study was to investigate critical parameters of tall oil separation from black liquor. To investigate this in a controlled way, we developed a model test system using a “synthetic” black liquor (active cooking chemicals OH- and HS- ions), a complete process for soap skimming, and determination of recovered tall oil based on solvent extraction and colorimetric analysis, with good reproducibility. We used the developed system to study the effect of the ratio of fatty acids to rosin acids on tall oil separation. When high amounts of rosin acids were present, tall oil recovery was low, while high content of fatty acids above 60% significantly promoted tall oil separation. Therefore, manipulating the content of fatty acids in black liquor before the soap skimming step can significantly affect the tall oil solubility, and hence its separation. The findings open up chemical ways to improve the tall oil yield.


1997 ◽  
Vol 35 (2-3) ◽  
pp. 235-243 ◽  
Author(s):  
R. Saunamäki

The performance of Finnish activated sludge plants (primary clarifier, equalization basin, buffer basin, aeration basin, secondary clarifier and sludge handling) was surveyed. Performance was generally found to be excellent. BOD7 removal averaged 94% at paper mills (21mg/l effluent concentration, 0.43 kg/t discharge) and 95% at chemical pulp mills (18 mg/l, 0.83 kg/t). CODCr removal averaged 82% at paper mills (158 mg/l effluent concentration, 3.52 kg/t discharge) and 60% at pulp mills (531 mg/l, 20.7 kg/t). Treated effluent from paper mills contained 0.57 mg/l (13.3 g/t) of total phosphorus and from pulp mills 1.31 mg/l (47.3 g/t). AOX removal was 45-65% and discharge 0.15-0.90 kg/t. Suspended solids removal averaged 91% at paper mills and 76% at pulp mills, the average overflow concentration in primary clarifier being about 150 mg/l at both types of mill. All activated sludge plants are designed according to either the low load or extended aeration principle; high load plants are no longer in use. The average sludge load was 0.15 kg BOD/(kg MLSS d), the sludge age at the extended aeration plants ranging from 20 to 50 d. Low load appearance to be the main reason for the good performance of the plants. Other factors included the introduction of equalization and buffer basins at many plants, and particularly the fact that aeration factors and nutrients were under control. All paper mill activated sludge plants use nitrogen and phosphorus additions, whereas pulp mill plants manage without phosphorus. Optimization of nutrient addition is vital because almost every mill in Finland has a limit for its phosphorus discharge. Total sludge production at the paper mill plants averaged 40.9 t/d, 15% of which (5.9 t/d, 6.0 kg/t) was biosludge. At the pulp mills the figures were 27.2 t/d (11.5 t/d biosludge, 9.5 kg/tp). Belt filter presses are used for dewatering at most plants and dry solids contents are usually 25-35%. New-generation screw presses have been introduced, mainly at new pulp mill activated sludge plants, yielding dry solids contents of 40%. Combined and dewatered sludge is normally burned in bark-fired boilers, although some mills still landfill their sludge.


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