Suitability of rice straw for biochar production through slow pyrolysis: Product characterization and thermodynamic analysis

2021 ◽  
pp. 100818
Author(s):  
Anil Kumar Sakhiya ◽  
Abhijeet Anand ◽  
Imlisongla Aier ◽  
Virendra Kumar Vijay ◽  
Priyanka Kaushal
Materials ◽  
2020 ◽  
Vol 13 (14) ◽  
pp. 3188
Author(s):  
Paweł Kazimierski ◽  
Paulina Hercel ◽  
Katarzyna Januszewicz ◽  
Dariusz Kardaś

The aim of this study was to assess the possibility of using furniture waste for smokeless fuel production using the pyrolysis process. Four types of wood-based wastes were used in the pyrolysis process: pine sawdust (PS), chipboard (CB), medium-density fiberboard (MDF), and oriented strand board (OSB). Additionally, the slow and fast types of pyrolysis were compared, where the heating rates were 15 °C/min and 100 °C/min, respectively. Chemical analyses of the raw materials and the pyrolysis product yields are presented. A significant calorific value rise was observed for the solid pyrolysis products (from approximately 17.5 MJ/kg for raw materials up to approximately 29 MJ/kg for slow pyrolysis products and 31 MJ/kg for fast pyrolysis products). A higher carbon content of char was observed in raw materials (from approximately 48% for raw materials up to approximately 75% for slow pyrolysis products and approximately 82% for fast pyrolysis products) than after the pyrolysis process. This work presents the possibility of utilizing waste furniture material that is mostly composed of wood, but is not commonly used as a substrate for conversion into low-emission fuel. The results prove that the proposed solution produced char characterized by the appropriate properties to be classified as smokeless coal.


Author(s):  
Muhammad Shahbaz ◽  
Ahmed AlNouss ◽  
Prakash Parthasarathy ◽  
Ali H. Abdelaal ◽  
Hamish Mackey ◽  
...  

Abstract Prior information on the pyrolysis product behaviour of biomass components-cellulose, hemicellulose and lignin is critical in the selection of feedstock as components have a significant influence on the pyrolysis products yield. In this study, the effect of biomass components on the yield of slow pyrolysis products (char, bio-oil and syngas) is investigated using a validated ASPEN Plus® model. The model is simulated at a temperature of 450 °C, a heating rate of 10 °C/min and a solid residence time of 30 min. The results indicated that at the given conditions, lignin contributed 2.4 and 2.5 times more char yield than cellulose and hemicellulose. The hemicellulose contributed 1.33 times more syngas yield than lignin while the cellulose and hemicellulose contributed 8.67 times more bio-oil yield than lignin. Moreover, the cost involved in the production of char using lignin (110 $/ton) is significantly economical than using cellulose (285 $/ton) and hemicellulose (296 $/ton). The net CO2 emission of lignin pyrolysis is 4.14 times lower than cellulose pyrolysis and 3.94 times lower than hemicellulose pyrolysis. It can be concluded that lignin pyrolysis is more advantageous than cellulose and hemicellulose pyrolysis. In the selection of feedstock for the slow pyrolysis, the feedstock with more lignin content is preferred. Graphical abstract


2017 ◽  
Vol 29 (2) ◽  
pp. 111-122 ◽  
Author(s):  
Mahmudul Islam Piash ◽  
Md Faruque Hossain ◽  
Zakia Parveen

Six slow pyrolysis biochars viz. farmyard manure (FM), water hyacinth (WH), domestic organic waste (DW), quick compost (QC), corn cob (CC) and rice straw (RS) were analyzed for their physical and chemical properties. Biochar yielding capacity varied from 34 to 51%, depending on the used feedstock. Water hyacinth biochar exhibited the highest water holding capacity (495%), whereas corn cob biochar had the lowest (146%) regardless of its highest pore volume. Brunauer-Emmett-Teller (BET) specific surface area was found maximum among the plant derived biochars except corn cob. Rice straw biochar exhibited the least mean pore diameter while highest in domestic organic waste. All biochars possessed pH values more than 9. CEC of water hyacinth (WH) was highest, while lowest was in quick compost (QC) biochar. Smallest average particle size (0.54 ?m2) was exhibited by water hyacinth biochar. Organic carbon content ranged from 33 to 49%. Nutrient (N, P, K and S) status of biochar produced from domestic organic waste (DW) was found the maximum compared to the rest and corn cob (CC) biochar showed the lowest nutritional value.Bangladesh J. Sci. Res. 29(2): 111-122, December-2016


Author(s):  
Chasin Krishna C. Cabriga ◽  
Kerstein Vince B. Clarete ◽  
Joyce Ann T. Zhang ◽  
Rose Mardie P. Pacia ◽  
Young Soo Ko ◽  
...  

2022 ◽  
Vol 138 ◽  
pp. 298-307
Author(s):  
Anubhuti Bhatnagar ◽  
Abhishek Singhal ◽  
Henrik Tolvanen ◽  
Kati Valtonen ◽  
Tero Joronen ◽  
...  
Keyword(s):  

Author(s):  
Marcos Antônio Klunk ◽  
Sudipta Dasgupta ◽  
Mohuli Das

Biomass is the term attributed to any renewable resource derived from organic matter that can be used in energy production. Agricultural production generates residues that are of great importance for their energy use, of which sugar cane, eucalyptus, and rice. Various residues are generated from rice cultivation, among which the rice husk and rice straw are the most important. Several thermal conversion technologies have been developed for the use of biomass in industry. Pyrolysis has been notable for its ability to produce biofuels at different stages of aggregation. The slow pyrolysis of biomass has been proposed as a pretreatment method to improve the physical-chemical characteristics of rice straw. In this process is produced, mainly, a solid called biochar, which has a higher energy content when compared to the biomass of origin. This study investigated the slow pyrolysis of rice straw at 300 - 700°C for the purpose of obtaining biochar, bio-oil, and gases for energy purposes. The experimental results show that pyrolysis temperature has important roles in yield product. The highest biochar yield was observed at a temperature of 300°C with 49.91 wt%. This represents 47% more when compared to yield at 700°C (33.87 wt.%). This behavior is linked to the proximate analysis results for fixed carbon 26.01 wt.% at 300°C. The high pH of the biochar was attributed to the presence of alkali metals, according to XRF. Thermal decomposition of the biomass resulting in a gradual increase of bio-oil (16.81 - 34.70 wt.%) and gas (6.53 - 18.05 wt.%) on a wet basis. Thus, in the dry base parameter, the bio-oil increases from 19.22 - 30.6 wt.% and the gases at 9.42-20.19 wt.%. Drying of the raw material showed, by the results, a significant increase in the co-products formed. As a consequence, we have a more efficient energy process.


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