Carboxyl/alkyl composite silica-based amphiphilic nanoparticles enhanced spontaneous imbibition of low permeability sandstone rocks at reservoir conditions

2021 ◽  
pp. 127504
Author(s):  
Yun Bai ◽  
Chunsheng Pu ◽  
Shuai Liu ◽  
Jing Liu
Keyword(s):  
Spontaneous Imbibition ◽  
Low Permeability ◽  
Reservoir Conditions ◽  
Amphiphilic Nanoparticles

scholarly journals Mechanism of active silica nanofluids based on interface-regulated effect during spontaneous imbibition

2021 ◽  
Author(s):  
Xu-Guang Song ◽  
Ming-Wei Zhao ◽  
Cai-Li Dai ◽  
Xin-Ke Wang ◽  
Wen-Jiao Lv
Keyword(s):  
Contact Angle ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Dynamic Contact Angle ◽  
Liquid Interface ◽  
Spontaneous Imbibition ◽  
Wettability Alteration ◽  
Low Permeability ◽  
Oil Water ◽  
Solid Liquid

AbstractThe ultra-low permeability reservoir is regarded as an important energy source for oil and gas resource development and is attracting more and more attention. In this work, the active silica nanofluids were prepared by modified active silica nanoparticles and surfactant BSSB-12. The dispersion stability tests showed that the hydraulic radius of nanofluids was 58.59 nm and the zeta potential was − 48.39 mV. The active nanofluids can simultaneously regulate liquid–liquid interface and solid–liquid interface. The nanofluids can reduce the oil/water interfacial tension (IFT) from 23.5 to 6.7 mN/m, and the oil/water/solid contact angle was altered from 42° to 145°. The spontaneous imbibition tests showed that the oil recovery of 0.1 wt% active nanofluids was 20.5% and 8.5% higher than that of 3 wt% NaCl solution and 0.1 wt% BSSB-12 solution. Finally, the effects of nanofluids on dynamic contact angle, dynamic interfacial tension and moduli were studied from the adsorption behavior of nanofluids at solid–liquid and liquid–liquid interface. The oil detaching and transporting are completed by synergistic effect of wettability alteration and interfacial tension reduction. The findings of this study can help in better understanding of active nanofluids for EOR in ultra-low permeability reservoirs.

Injectivity and Propagation of Sulfonated Acrylamide-Based Copolymers in Low Permeability Carbonate Reservoir Cores in Harsh Salinity and Temperature Conditions : Challenges and Learnings from a Middle East Onshore Case Study

2021 ◽  
Author(s):  
Nicolas Gaillard ◽  
Matthieu Olivaud ◽  
Alain Zaitoun ◽  
Mahmoud Ould-Metidji ◽  
Guillaume Dupuis ◽  
...  
Keyword(s):  
Middle East ◽  
Polymer Solutions ◽  
Carbonate Reservoir ◽  
Core Material ◽  
Low Permeability ◽  
The Core ◽  
Reservoir Conditions ◽  
Carbonate Cores ◽  
The Impact ◽  
Mobility Reduction

Abstract Polymer flooding is one of the most mature EOR technology applied successfully in a broad range of reservoir conditions. The last developments made in polymer chemistries allowed pushing the boundaries of applicability towards higher temperature and salinity carbonate reservoirs. Specifically designed sulfonated acrylamide-based copolymers (SPAM) have been proven to be stable for more than one year at 120°C and are the best candidates to comply with Middle East carbonate reservoir conditions. Numerous studies have shown good injectivity and propagation properties of SPAM in carbonate cores with permeabilities ranging from 70 to 150 mD in presence of oil. This study aims at providing new insights on the propagation of SPAM in carbonate reservoir cores having permeabilities ranging between 10 and 40 mD. Polymer screening was performed in the conditions of ADNOC onshore carbonate reservoir using a 260 g/L TDS synthetic formation brine together with oil and core material from the reservoir. All the experiments were performed at residual oil saturation (Sor). The experimental approach aimed at reproducing the transport of the polymer entering the reservoir from the sand face up to a certain depth. Three reservoir coreflood experiments were performed in series at increasing temperatures and decreasing rates to mimic the progression of the polymer in the reservoir with a radial velocity profile. A polymer solution at 2000 ppm was injected in the first core at 100 mL/h and 40°C. Effluents were collected and injected in the second core at 20 mL/h and 70°C. Effluents were collected again and injected in the third core at 4 mL/h and 120°C. A further innovative approach using reservoir minicores (6 mm length disks) was also implemented to screen the impact of different parameters such as Sor, molecular weight and prefiltration step on the injectivity of the polymer solutions. According to minicores data, shearing of the polymer should help to ensure good propagation and avoid pressure build-up at the core inlet. This result was confirmed through an injection in a larger core at Sor and at 120°C. When comparing the injection of sheared and unsheared polymer at the same concentration, core inlet impairment was suppressed with the sheared polymer and the same range of mobility reduction (Rm) was achieved in the internal section of the core although viscosity was lower for the sheared polymer. Such result indicates that shearing is an efficient way to improve injectivity while maximizing the mobility reduction by suppressing the loss of product by filtration/retention at the core inlet. This paper gives new insights concerning SPAM rheology in low permeability carbonate cores. Additionally, it provides an innovative and easier approach for screening polymer solutions to anticipate their propagation in more advanced coreflooding experiments.

scholarly journals Measuerment of CO2-crude oil minimum miscible pressure in YC Oilfield by core displacement method

2021 ◽  
Vol 2109 (1) ◽  
pp. 012006
Author(s):  
Li Liu ◽  
Jinxin Liu ◽  
Yanfu Pi ◽  
Xuan Guo ◽  
Zhipeng Dai ◽  
...  
Keyword(s):  
Crude Oil ◽  
Physical Simulation ◽  
Low Permeability ◽  
Displacement Method ◽  
Reservoir Water ◽  
Tube Test ◽  
Reservoir Conditions ◽  
Good Repeatability ◽  
Target Block ◽  
Core Displacement

Abstract Aiming at the defect of measuring the CO2-crude oil MMP(minimum miscible pressure) by the slim tube test, the core displacement method is established based on indoor physical simulation and homogeneous rectangular core in the low permeability block of YC oilfield. For comparison, the MMP is measured by the slim tube test in the same block. Experimental results show that the method has good repeatability and can simulate porous media and reservoir water content, which is more consistent with the actual reservoir conditions. The MMP in the target block of YC oilfield was 19.85MPa, which was 1.87MPa lower than that measured by traditional slim tube test.

scholarly journals Analysis of Controlling Factors at Separate Imbibition Stages for Ultra-Low-Permeability Reservoirs

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7093
Author(s):  
Hailong Dang ◽  
Hanqiao Jiang ◽  
Binchi Hou ◽  
Xiaofeng Wang ◽  
Tao Gao ◽  
...  
Keyword(s):  
Fractured Reservoirs ◽  
Influential Factors ◽  
Controlling Factors ◽  
Spontaneous Imbibition ◽  
Low Permeability ◽  
Relative Importance ◽  
Oil Viscosity ◽  
Oil Saturation ◽  
Low Permeability Reservoirs ◽  
Interfacial Characteristics

Spontaneous imbibition is an important mechanism in naturally fractured reservoirs. In our previous studies on the effect of imbibition efficiency of ultra-low permeability reservoirs, we mostly focused on the relationship between macroscopic core recovery rate and influential factors. Additionally, we also mainly focused on the factors that control the final imbibition recovery for ultra-low permeability reservoirs. Through a large number of experiments, it was found that the factors affecting imbibition are different in separate stages. However, the relative importance of those factors in different imbibition stages was hardly studied. In this work, we tested six key factors, i.e., the core length, RQI, salinity, interfacial characteristics, initial oil saturation, and oil viscosity, in natural sandstone samples from Chang 6 in the Zichang area. Based on experimental results, we divided the imbibition process into three stages (i.e., the early stage, the middle stage, and the late stage) to quantify the effects of the controlling factors. The results show that the relative importance of the controlling factors is changing during the imbibition process. The weight of importance is obtained for those factors at each stage. In addition, a comparative model is established for the dual-porosity media from Chang 6 formation. The results show that the increase of the rock size can extend the imbibition period for the early and middle stages. Moreover, the weight of importance for the initial oil saturation, interfacial characteristics, and salinity are also analyzed in three imbibition stages. This study provides theoretical support to guide water injection in ultra-low-permeability reservoirs and to understand the formation of energy supplements and oil recovery during the imbibition process.

scholarly journals Comparative Study of Using Sea-Water for Enhanced Oil Recovery in Carbonate and Sandstone Reservoirs: Effects of Temperature and Aging Time on Oil Recovery

2018 ◽  
Vol 7 (2) ◽  
pp. 1-13
Author(s):  
Madi Abdullah Naser ◽  
Mohamed Erhayem ◽  
Ali Hegaig ◽  
Hesham Jaber Abdullah ◽  
Muammer Younis Amer ◽  
...  
Keyword(s):  
Aging Time ◽  
Oil Recovery ◽  
Sea Water ◽  
Essential Element ◽  
Recovery Process ◽  
Spontaneous Imbibition ◽  
Effect Of Temperature ◽  
Injection Process ◽  
Reservoir Conditions ◽  
The Impact

Oil recovery process is an essential element in the oil industry, in this study, a laboratory study to investigate the effect of temperature and aging time on oil recovery and understand some of the mechanisms of seawater in the injection process. In order to do that, the sandstone and carbonate cores were placed in the oven in brine to simulate realistic reservoir conditions. Then, they were aged in crude oil in the oven. After that, they were put in the seawater to recover, and this test is called a spontaneous imbibition test. The spontaneous imbibition test in this study was performed at room temperature to oven temperature 80 oC with different sandstone and carbonate rock with aging time of 1126 hours. The result shows that the impact of seawater on oil recovery in sandstone is higher than carbonate. At higher temperature, the oil recovery is more moderate than low temperature. Likewise, as the aging time increase for both sandstone and carbonate rocks the oil recovery increase. 

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