Effect of thermal modification of slash pine with linseed oil on water repellency and performance of mechanical connections

2021 ◽  
Vol 305 ◽  
pp. 124776
Author(s):  
Luis Yermán ◽  
Lisa-Mareike Ottenhaus ◽  
Yuhao Zhang ◽  
Jeffrey J. Morrell
2007 ◽  
Vol 83 (4) ◽  
pp. 475-477
Author(s):  
P A Cooper ◽  
J. Wang ◽  
Y T Ung

Thermal modification of wood by immersion in high temperature vegetable oils and other additives impart significant decay and mould fungi resistance, water repellency and dimensional stability. Key words: thermal modification, wood, vegetable oil, decay, termite resistance, oil stability


Holzforschung ◽  
2015 ◽  
Vol 69 (4) ◽  
pp. 405-413 ◽  
Author(s):  
Wang Wang ◽  
Yuan Zhu ◽  
Jinzhen Cao ◽  
Xi Guo

Abstract The aim of this study was to enhance the water repellency and dimensional stability of thermally modified wood by combining the preimpregnation of paraffin wax emulsion. To achieve this, Southern pine (SP; Pinus spp.) samples were first impregnated with paraffin wax emulsion (with 2.0% solid content) and then subjected to thermal modification (TM) in an oven at 180°C and 220°C for 4 and 8 h. The contact angle (CA), surface free energy, water absorption rate (WAR), anti-swelling efficiency (ASE), and bending properties of the control and modified samples were investigated. Moreover, the chemical and morphological alterations were analyzed by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). Both the wax impregnation and TM decreased the surface wettability, water absorption, and tangential swelling, while the combination of wax and thermal treatment exhibited the best water repellency and dimensional stability, indicating the synergism between the two procedures. However, the wax preimpregnation did not affect the mechanical properties of thermally modified wood. The FTIR, SEM, and XPS analyses confirmed that the synergistic effect is mainly due to the redistribution of the paraffin wax during TM rather than its impact on the chemical changes caused by thermal degradation.


2011 ◽  
Vol 332-334 ◽  
pp. 1457-1461 ◽  
Author(s):  
Shao Qiang Zhou ◽  
Jian He Cai ◽  
Shao Wei Dong ◽  
Guo Qiang Chen

A new-style fluorine-containing polymer with short chain was synthesized. The fabrics were finished with polymer emulsions with different contents of fluorine. The performances of the polymers were compared with two kinds of similar products, which contained water repellency, oil repellency, contact angle, brightness, and etc. The type of monomer was determined with infrared spectrum. The variety of micro-morphologic structure of cotton fabrics before and after the finishing was studied with SEM, XRD, and etc. It showed that the polymer was copolymerized by three kinds of acrylic ester monomers, and the application performance was in general accord with the same kind of advanced products of the world.


BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 8085-8092
Author(s):  
Mihaela Liu ◽  
Xinwei Tu ◽  
Xinyou Liu ◽  
Zhihui Wu ◽  
Jiufang Lv ◽  
...  

Linseed oil and shellac are natural, environmentally friendly materials with good water repellency. They were used to impregnate Chinese ash wood at room temperature (20 °C) using a vacuum-pressure procedure (consisting of three cycles of 0.01 MPa for 1.5 h and atmospheric pressure for 1.5 h) to improve the dimensional stability of wood. The effects of the impregnation treatment on wood color changes, dimensional stability, moisture absorption, and morphological characteristics were evaluated. The linseed oil and shellac treatment improved the dimensional stability of wood. Linseed oil and shellac displayed good permeability in Chinese ash wood, with weight gains of 21.7% and 19.0%, respectively, after impregnation. The swelling coefficients of treated wood in the tangential and radial directions decreased by 15 to 22%, indicating that impregnation improved the dimensional stability of wood. Linseed oil and shellac solidified and occluded the pits within the wood interior to prevent moisture absorption. This method can be used to improve the dimensional stability of a variety of wood products, such as buildings, furniture, and landscape architecture.


2021 ◽  
Vol 72 (2) ◽  
pp. 155-167
Author(s):  
Vasiliki Kamperidou

In this study, poplar and black pine wood was exposed to short thermal treatments, aiming to improve some crucial properties. Using wet chemical analyses and Fourier-transform infrared spectroscopy (FT-IR), the influence of these treatments on the chemical composition of the modified species was investigated, as well as on the wood structure, using scanning electron microscopy. With the increase of heat treatment intensity, a mass loss of both species was recorded, attributed to the moisture loss and degradation of volatile compounds, as well as thermally less stable components. In the first treatment stages, the extractives presented a decrease, whereas with the duration and temperature increase, new extractives were formed. Lignin increased its network through ramification, especially at 200 ºC, while holocellulose was found lower in all modified wood categories of both species than in unmodified wood due to the intense decomposition of hemicelluloses. The findings of FT-IR analyses were in line with the chemical analysis results. The thermal modification process made wood materials more hydrophobic and dimensionally stable, providing protection against decomposing factors. At the same time, they were not intensively thermo-degraded, which increased their utilization perspectives and application range as solid wood of enhanced properties, or as wood particles/fibers participating as raw materials in wood-based composite products, wood-polymers composites etc., enhancing their materials compatibility, properties and performance.


Author(s):  
Nguyen Tuan Anh

Flammability of polymer composite appears to be one of the greatest threats and hence limits its advanced applications. Polymer composite materials can be designed to obtain wide ranges of properties in comparison with traditional materials. However, almost common polymers include the intrinsic flammability, restricting their applications in spite of their flexibility and performance efficiency. In this study, a material based on epoxy Epikote 240 resin 90 phr and epoxidized linseed oil 10 phr was prepared. In order to improve the material's flame retardancy ability but maintain its mechanical strength, the mixture of flame retardants including 9 phr antimony trioxide and 11 phr chlorinated paraffins along with amin compounds as a curing agent were added into the material. In addition, E-glass woven fabric (E 600g/m2 ) was used to improve mechanical strength of the material. As a result, the material was considered as the flame- retardant material with LOI index to be 30.3%.


Forests ◽  
2020 ◽  
Vol 11 (3) ◽  
pp. 271
Author(s):  
Jinyu Chen ◽  
Yujiao Wang ◽  
Jinzhen Cao ◽  
Wang Wang

Natural wood is susceptible to moisture during its practical use, limiting not only service life but also the range of uses. In this study, plant extracts, specifically linseed oil and carnauba wax (both environmentally friendly and water-repellent substances), were examined as a means to mitigate limitations of natural wood. Stable and homogenous epoxidized linseed oil/carnauba wax emulsions with an average particle size less than 230 nm were used as a modifier to enhance the performance of wood. Weight percentage gain, bulking coefficient, micromorphology, chemical structure, moisture adsorption, contact angle, water repellency, and dimensional stability of treated wood were measured. Using a scanning electron microscope (SEM), it was observed that carnauba wax and epoxidized linseed oil acted as a mechanical barrier and could partially cover or block vessels, pits, and wood rays. Furthermore, the hydrophobicity of wood increased significantly after emulsion impregnation. However, there was no obvious chemical reaction between epoxidized linseed oil and the main components of wood in the Fourier transform infrared spectroscopy (FTIR) results. The combined effect of epoxidized linseed oil and carnauba wax was apparent in both decreased water absorption and dimensional deformation. Poplar wood impregnated with an epoxidized linseed oil/carnauba wax complex emulsion shows potential for improving water-related properties. Thus, the complex emulsion modification can improve the inherent shortcoming of poplar wood effectively.


Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 143
Author(s):  
Zuzana Vidholdová ◽  
Gabriela Slabejová ◽  
Mária Šmidriaková

In this study, natural linseed oil, hard wax oil, and hard wax, commonly used as finishes for wooden furniture and parquet, were used for surface finishes on Turkey oak wood (Quercus cerris L.), thermally modified at temperatures of 175 °C and 195 °C for 4 h. Several resistance surface properties were investigated. The mechanical resistance properties of all surface finishes were very much allied to interactions between the finish and the type of substrate. The adhesion strength and impact resistance decreased if higher temperature was used for thermal modification of the substrate. The surface hardness and the resistance to abrasion were high and increased slightly with increasing temperature during thermal modification of wood. It was also found that surface adhesion, hardness and resistance to impact were very much related to interactions between the coating film and the substrate. The resistance properties of finishes, such as resistance to cold liquids and mold, were mainly influenced by the type of the surface finish. The resistance to cold liquids increased in the order: surface finish with hard wax < linseed oil < finish system of linseed oil + hard wax oil. The lowest resistance to cold liquids showed up in condensed milk and sanitizer. Resistance to Aspergillus niger and Penicillium purpurogenum was relatively weak, however apparently improved during the first 7 days of the fungal test; the surfaces were covered with a lower distribution density of fungal mycelium after 21 days of the fungal test. Individual surface performances of oil and wax-based surface finishes on native wood were different from thermally modified wood.


Holzforschung ◽  
2017 ◽  
Vol 71 (1) ◽  
pp. 57-64 ◽  
Author(s):  
Miha Humar ◽  
Davor Kržišnik ◽  
Boštjan Lesar ◽  
Nejc Thaler ◽  
Aleš Ugovšek ◽  
...  

Abstract Thermal modification is the most important commercial modification procedure. Thermally modified (TM) wood has improved durability, but its performance does not meet expectations predominately under moist conditions. To reduce water uptake of TM wood, Norway spruce specimens were treated with suspensions of a natural wax by dipping impregnation (DipI) or by vacuum-pressure impregnation (VPI). Wax-treated specimens were subsequently TM at 185, 200, 215, and 230°C. Control specimens were heated up to 100°C only. Contact angle (CA), short-term and long-term water uptake, bending strength, and performance against wood decay fungi of the resulting material were determined. The results show that a combination of wax treatment and thermal modification have a synergistic effect that considerably improves hydrophobicity, reduces liquid water uptake, slows down water vapor uptake, and improves the resistance against fungal decay of the treated material.


Sign in / Sign up

Export Citation Format

Share Document