Thermo-chemo-mechanical characterization, modeling, and analysis of hydration of calcium-sulfoaluminate cement paste

2022 ◽  
Vol 319 ◽  
pp. 125747
Author(s):  
Christian Pichler ◽  
Lukas Perfler ◽  
Kathrin Kaufmann ◽  
Thomas Bidner ◽  
Roman Lackner
2021 ◽  
Vol 1036 ◽  
pp. 263-276
Author(s):  
Hao Ran Huang ◽  
Yi Shun Liao ◽  
Siraj Ai Qunaynah ◽  
Guo Xi Jiang ◽  
Da Wei Guo ◽  
...  

The effects of steel slag with 0, 10%, 20 % and 40% content on the chemical shrinkage, autogenous shrinkage, internal relative humidity, and drying shrinkage of calcium sulfoaluminate cement paste were studied. The results show that the compressive strength of calcium sulfoaluminate cement paste at an early stage decreases gradually when the content of steel slag increases. When the steel slag content is 0 and 10%, the compressive strength of hardened cement pastes gradually decreases at 90 and 180 days, but the samples with steel slag content of 20% and 40% maintain the compressive strength growth within 180 d. With the extension of curing period, the gap of compressive strength is gradually narrowed. The autogenous shrinkage decreases with the increase of steel slag content and has a good linear relationship with the relative humidity inside the paste. The proportion of autogenous shrinkage to chemical shrinkage is deficient, and most chemical shrinkage occurs in the form of the pore volume. Although the trends of drying shrinkage and autogenous are consistent, the former is more severe than the latter.


2015 ◽  
Vol 49 (1-2) ◽  
pp. 719-727 ◽  
Author(s):  
Zanqun Liu ◽  
Xiangning Li ◽  
Dehua Deng ◽  
Geert De Schutter

2021 ◽  
pp. 102894
Author(s):  
Linglin Xu ◽  
Yangjun Ou ◽  
Andreas Hecker ◽  
Christiane Rößler ◽  
H.M. Ludwig ◽  
...  

2021 ◽  
Vol 13 (4) ◽  
pp. 2295
Author(s):  
Hailong Liu ◽  
Jiuye Zhao ◽  
Yu Wang ◽  
Nangai Yi ◽  
Chunyi Cui

Calcium sulfoaluminate cement (CSA) was used to stabilize a type of marine soft soil in Dalian China. Unconfined compressive strength (UCS) of CSA-stabilized soil was tested and compared to ordinary Portland cement (OPC); meanwhile the influence of amounts of gypsum in CSA and cement contents in stabilized soils on the strength of stabilized soils were investigated. X-ray diffraction (XRD) tests were employed to detect generated hydration products, and scanning electron microscopy (SEM) was conducted to analyze microstructures of CSA-stabilized soils. The results showed that UCS of CSA-stabilized soils at 1, 3, and 28 d firstly increased and then decreased with contents of gypsum increasing from 0 to 40 wt.%, and CSA-stabilized soils exhibited the highest UCS when the content of gypsum equaled 25 wt.%. When the mixing amounts of OPC and CSA were the same, CSA-stabilized soils had a significantly higher early strength (1 and 3 d) than OPC. For CSA-stabilized soil with 0 wt.% gypsum, monosulfate (AFm) was detected as a major hydration product. As for CSA-stabilized soil with certain amounts of gypsum, the intensity of ettringite (Aft) was significantly higher than that in the sample hydrating without gypsum, but a tiny peak of AFm also could be detected in the sample with 15 wt.% gypsum at 28 d. Additionally, the intensity of AFt increased with the contents of gypsum increasing from 0 to 25 wt.%. When contents of gypsum increased from 25 to 40 wt.%, the intensity of AFt tended to decrease slightly, and residual gypsum could be detected in the sample with 40 wt.% gypsum at 28 d. In the microstructure of OPC-stabilized soils, hexagonal plate-shaped calcium hydroxide (CH) constituted skeleton structures, and clusters of hydrated calcium silicates (C-S-H) gel adhered to particles of soils. In the microstructure of CSA-stabilized soils, AFt constituted skeleton structures, and the crystalline sizes of ettringite increased with contents of gypsum increasing; meanwhile, clusters of the aluminum hydroxide (AH3) phase could be observed to adhere to particles of soils and strengthen the interaction.


Materials ◽  
2021 ◽  
Vol 14 (2) ◽  
pp. 382 ◽  
Author(s):  
Danying Gao ◽  
Zhenqing Zhang ◽  
Yang Meng ◽  
Jiyu Tang ◽  
Lin Yang

This work aims to investigate the effect of additional flue gas desulfurization gypsum (FGDG) on the properties of calcium sulfoaluminate cement (CSAC) blended with ground granulated blast furnace slag (GGBFS). The hydration rate, setting time, mechanical strength, pore structure and hydration products of the CSAC-GGBFS mixture containing FGDG were investigated systematically. The results show that the addition of FGDG promotes the hydration of the CSAC-GGBFS mixture and improves its mechanical strength; however, the FGDG content should not exceed 6%.


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