Adsorption-desorption dynamics of synthetic and naturally weathered microfibers with toxic heavy metals and their ecological risk in an estuarine ecosystem

2021 ◽  
pp. 112198
Author(s):  
Madhu D. Sharma ◽  
Reddithota J. Krupadam
2021 ◽  
Vol 8 ◽  
Author(s):  
Li Yu ◽  
Shi Kaiyi ◽  
Yuan Jie ◽  
Kuang Qiyu

The Liupanshui Minghu Wetland is a typical artificial urban wetland in a plateau mining region. It is important to identify the sources and potential ecological risks of heavy metal contaminants in its surface sediments to monitor the wetland and the downstream water quality and prevent pollution. In this study, we measured the concentrations of six toxic heavy metals (Pb, Zn, Cr, Cu, Ni, and Cd) in the surface sediments collected from the Liupanshui Minghu Wetland. Further, the geological accumulation indices of heavy metals and their potential ecological risk indices, pollution levels, and associated ecological hazards were evaluated. The average levels of Pb, Zn, Cr, Cu, Ni, and Cd in the superficial sediments were 197, 222, 79.0, 59.1, 68.6, 4.67 mg/kg, respectively. With the exception of Cr, the concentrations of the remaining metals were greater than the background levels in the region. The Statistical analysis indicated a strong correlation between Pb, Zn, Cr, and Cu (p < 0.01). The pollution in the wetland by these elements can be attributed to human activities such as transportation, industrial activity, and agricultural production. Ni and Cd pollution can be attributed to human activities, such as coal mining, and natural phenomena, such as the weathering of mountains and rocks. The geological accumulation indices of Zn, Ni, and Cu indicated low levels of accumulation and minimal contamination. Cd and Pb were moderately enriched, and the levels of Cd and Pb contamination ranged from moderate to high. The potential ecological risk to the Shiyuan region (S) was the highest among the three regions in the wetland park. It was followed by the Longtoutan (L) region, and the potential ecological risk was the lowest in the Erdaoba (E) region. Among the six heavy metals, Cd was the main contributor to pollution in the Minghu Wetland. This study also strives to provide theoretical basis and data support for the prevention and control of heavy metal pollution in artificial wetlands in Alpine mining areas.


2021 ◽  
Author(s):  
Pradeep Kumar ◽  
Dipti Rawat ◽  
Sunil Kumar ◽  
Rana Pratap Singh

Abstract The present study investigates the phytoaccumulation factor (PF), Ecological risk index (ERI), and carcinogenic risk factor (CRs) of toxic heavy metals (THMs) i.e. As, Cd, Cr, Pb, and Ni in the agricultural soil, irrigation water, vegetables and cereals samples collected from peri-urban regions of Lucknow. The level of these metals was within the maximum allowable concentration (MAC) (FAO/WHO 2011) in agricultural soil while it was higher in irrigation water. The phytoaccumulation factor of Cd and Ni was very high in the edible parts of vegetable and cereal samples which show that they might have entered through metal-contaminated irrigation water even if not available in the soil. The contamination coefficient (ifC) and Ecological risk factor (ifE) of metals was detected in the range of low risk in all agricultural soil, whereas Ecological risk index of metals was found in the moderate risk which indicated a mild impact on the agro-ecosystem. The carcinogenic risk potential of metals was found more than the requisite value of 10-4 in tomato, spinach, and wheat samples. This study indicates that the metals possess a moderate ecological risk and high carcinogenic risk potential through the consumption of metal-contaminated vegetables and cereals grown and sold in peri-urban regions and food markets.


Author(s):  
O. R. Akpomrere ◽  
H. Uguru

This study was carried to determine the level of heavy metals toxicity in swampy forest of Isoko South, Delta State, Nigeria. Sediments samples were collected from nine spatial points, within the swampy forest of Enwhe community of Delta State, Nigeria. The study area contained clusters of illegal crude oil refineries, before they were destroyed by the Nigeria military, during the first quarter of 2020. A total area of 1 km2 of the swampy environment was covered in this study. Six toxic heavy metals (Cu, Zn, Cr, Cd, Pb, and Ni) contents, in the sediments were determined in accordance to international approved standards. The results revealed that the activities of the illegal refineries located in the study area, significantly increased the heavy metals toxicity in the sediments.  When compared with the results obtained from a reference point, the concentrations of the heavy metals were significantly higher, across the study area. Within the study area, spatial points B and D sediments contained the highest heavy metals concentrations. In addition, the study revealed that contamination factor of the sediments ranged between moderate and high degree of heavy metals contamination. This portrayed the potential ecological risks of the illegal refineries activities, to the environment of the region. Therefore, if these illegal refineries activities are allowed to continue unabated, they will cause a serious ecological risk to the Niger Delta region ecosystems.


Author(s):  
MdDidarul Islam, Ashiqur Rahaman, Aboni Afrose

This study was based on determining concentration of essential and toxic heavy metal in coconut water available at a local Hazaribagh area in Dhaka, Bangladesh. All essential minerals, if present in the drinking water at high concentration or very low concentration, it has negative actions. In this study, fifteen samples and eight heavy metals were analyzed by Atomic Absorption Spectroscopy (AAS) method which was followed by wet ashing digestion method. The concentration obtained in mg/l were in the range of 0.3 to 1.5, 7.77 to 21.2, 0 to 0.71, 0 to 0.9, 0 to 0.2, 0.9 to 17.3, 0.1 to 0.9, 0 to 0.9 and 0 to 0.7 for Fe, Ni, Cu, Cd, Cr, Zn, Pb and Se respectively. From this data it was concluded that any toxic heavy metals like Cd, Cr, Pb and Ni exceed their toxicity level and some essential nutrients were in low concentration in those samples. 


2017 ◽  
Vol 1 ◽  
pp. 264
Author(s):  
Md Didarul Islam ◽  
Ashiqur Rahaman ◽  
Fahmida Jannat

This study was based on to determine the concentration of macro and micro nutrients as well as toxic and nontoxic heavy metals present in the chicken feed available in Dhaka city of Bangladesh. All macro nutrients, if present in the feed at high concentration have some adverse effect, at the same time if this nutrient present in the feed at low concentration this have some adverse effect too. So that this nutrient level should be maintained at a marginal level. On the other side toxic heavy metals if present in the feed at very low concentration those can contaminate the total environment of the ecosystem. In this study six brand samples (starter, grower, finisher and layer) which was collected from different renowned chicken feed formulation industry in Bangladesh. Those samples were prepared for analysis by wet ashing and then metals were determined by Atomic Absorption Spectroscopy. It was found that 27.7 to 68.4, 57.3 to 121.9, 0.21 to 4.1, 0.32 to 2.1, 0.11 to 1.58, 0.28 to 2.11 and 0.28 to 1.78 for zinc, iron, copper, mercury, cadmium, nickel and cobalt respectively. It was found that essential macro and micro nutrients were present in the feed in low concentration on the other side mercury was present in high concentration in the feed samples.


2017 ◽  
Vol 68 (10) ◽  
pp. 2363-2366
Author(s):  
Delia Nica Badea

The paper evaluates the presence and content of traces of heavy metals Hg, Pb, Ni, Cd (total forms) from coal and solid combustion products, the degree of transfer and accessibility in the area of influence of a lignite power plant. The content of toxic heavy metals in residues are characterized by RE Meiji [ 1 (Pb and Hg) and REMeij �1 (Ni and Cd) for the filter ash. Pb and Ni content in the soil exceeds normal values, and Pb exceeds and alert value for sensitive soils around the residue deposit (70.20 mg.Kg-1). The degree of accessibility of the metals in plants (TF), reported at the Khan reference value (0.5), indicates a significant bioaccumulation level for the metals: Cd (1.9) and Hg (0.6) inside the deposit; Cd (0.39) at the base of the deposit, Hg (0.8) in the area of the thermal power plant. The trace levels of heavy metals analyzed by GFAAS and CVAAS (Hg), indicates a moderate risk potential for food safety and quality of life in the studied area.


1982 ◽  
Vol 14 (12) ◽  
pp. 107-125 ◽  
Author(s):  
Roland Wollast

A comparison of the concentration of dissolved and of particulate heavy metals in the aquatic system indicates that these elements are strongly enriched in the suspended matter. The transfer between the aqueous phase and the solid phase may be due to dissolution-precipitation reactions, adsorption-desorption processes or biological processes. When these processes are identified, it is further possible to develop mathematical models which describe the behaviour of these elements. The enrichment of heavy metals in the particulate phase suspended or deposited and in aquatic organisms constitutes a powerful tool in order to evaluate sources of pollution.


Author(s):  
Sangeetha Annam ◽  
Anshu Singla

Abstract: Soil is a major and important natural resource, which not only supports human life but also furnish commodities for ecological and economic growth. Ecological risk has posed a serious threat to the ecosystem by the degradation of soil. The high-stress level of heavy metals like chromium, copper, cadmium, etc. produce ecological risks which include: decrease in the fertility of the soil; reduction in crop yield & degradation of metabolism of living beings, and hence ecological health. The ecological risk associated, demands the assessment of heavy metal stress levels in soils. As the rate of stress level of heavy metals is exponentially increasing in recent times, it is apparent to assess or predict heavy metal contamination in soil. The assessment will help the concerned authorities to take corrective as well as preventive measures to enhance the ecological and hence economic growth. This study reviews the efficient assessment models to predict soil heavy metal contamination.


Author(s):  
Varsha Shukla ◽  
Siddharth Kumar Das ◽  
Abbas Ali Mahdi ◽  
Shweta Agarwal ◽  
Ragini Alok ◽  
...  

BACKGROUND: Fibromyalgia syndrome (FMS) is an extra-articular rheumatological disease characterised by widespread chronic musculoskeletal pain. Metal-induced oxidative stress contributes to the severity of FMS. AIMS: First, this study evaluated the association between plasma levels of toxic heavy metals and essential metals with oxidative stress (OS) markers. Second, the OS markers and metal contents were correlated with the disease severity by assessing the Fibromyalgia Impact Questioner Revised (FIQR) and tender points (TP). METHOD: A total of 105 FMS patients and 105 healthy controls of similar age and sex were recruited. OS parameter such as lipid peroxidation (LPO), protein carbonyl group (PCG), nitric oxide (NO) and essential metals such as zinc (Zn), magnesium (Mg), manganese (Mn), copper (Cu) and toxic heavy metals such as aluminium (Al), arsenic (As), lead (Pb) were estimated. RESULTS: Levels of LPO, PCG, NO (p< 0.001) and Cu, Mn, and Al (p< 0.001), were significantly higher, and Mg (p< 0.001) and Zn (p< 0.001) were significantly lower in patients compared to controls. A positive association was observed between OS parameters, FIQR and TP with Cu, Al and Mn. A significant negative association was observed between Zn and Mg with FIQR, TP and OS parameters. CONCLUSION: Heavy metals such as Al induce OS parameters and decrease the levels of essential trace elements such as Mg and Zn, which may be responsible for the severity of FMS.


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