scholarly journals Production of fuel oil and combustible gases from pyrolysis of polystyrene waste: Kinetics and thermodynamics interpretation

Author(s):  
Jan Nisar ◽  
Ghulam Ali ◽  
Afzal Shah ◽  
Zahoor Hussain Farooqi ◽  
Munawar Iqbal ◽  
...  
2021 ◽  
Vol 7 (3) ◽  
pp. 43-48
Author(s):  
Shalu Patel ◽  
Shalu Patel ◽  
Savita Dixit ◽  
Kavita Gidwani Suneja ◽  
Nilesh Tipan

Polystyrene usage has risen significantly in recent years as a result of its wide variety of applications. The persistent consumer demand for polystyrene resulted in the accumulation of polystyrene waste in landfills, inducing environmental degradation. Since polystyrene is a petroleum-derived material, the increasing demand for it resulted in the depletion of petroleum, a non-renewable energy source. Research teams from all over the world have invented many methods for dealing with polystyrene waste, including recycling and energy regeneration. However, there are drawbacks to recycling methods, such as the fact that they need a lot of manpower in the separating procedure and pollute the water, reducing the process's sustainability. Because of these flaws, the experimenters have cantered their efforts on the energy harvesting approach. As petroleum is the primary component of polystyrene, the pyrolysis process for recovering fuel oil from polystyrene is an useful technology because the retrieved oil has a higher calorific value than commercially available gasoline. The current paper discusses polystyrene conversion technologies as well as the pyrolysis techniques for polystyrene, which generates end products such as oil, gas, and char. The impact of different processing parameters on the product yield has been addressed using more advanced techniques of conducting pyrolysis with a solvent.


2020 ◽  
Vol 38 (11) ◽  
pp. 1269-1277
Author(s):  
Jan Nisar ◽  
Ghulam Ali ◽  
Afzal Shah ◽  
Muhammad Naeem Ashiq ◽  
Zahoor Hussain Farooqi ◽  
...  

The present work is focused on pyrolysis of polystyrene waste for production of combustible hydrocarbons. The experiments were performed in an indigenously made furnace in the presence of a laboratory synthesised copper oxide. The pyrolysis products were collected and characterised. The Fourier transform infrared spectra showed that the liquid fraction contains C–H, C–O, C–C, C=C and O–H bonds, which correspond to various aliphatic and aromatic compounds. Gas chromatography–mass spectrometry traced compounds ranging from C1 to C4 in the gaseous fraction, whereas in the liquid fraction 15 components ranging from C3 to C24 were detected. From the results it has been concluded that CuO as a catalyst not only increased the liquid yield but also reduced the degradation temperature to great extent. Fuel properties of the pyrolysis oil were determined and compared with standard values of commercial fuel oil. The comparison suggested potential application of pyrolysis oil for domestic and commercial use.


Author(s):  
J.K. Lampert ◽  
G.S. Koermer ◽  
J.M. Macaoy ◽  
J.M. Chabala ◽  
R. Levi-Setti

We have used high spatial resolution imaging secondary ion mass spectrometry (SIMS) to differentiate mineralogical phases and to investigate chemical segregations in fluidized catalytic cracking (FCC) catalyst particles. The oil industry relies on heterogeneous catalysis using these catalysts to convert heavy hydrocarbon fractions into high quality gasoline and fuel oil components. Catalyst performance is strongly influenced by catalyst microstructure and composition, with different chemical reactions occurring at specific types of sites within the particle. The zeolitic portions of the particle, where the majority of the oil conversion occurs, can be clearly distinguished from the surrounding silica-alumina matrix in analytical SIMS images.The University of Chicago scanning ion microprobe (SIM) employed in this study has been described previously. For these analyses, the instrument was operated with a 40 keV, 10 pA Ga+ primary ion probe focused to a 30 nm FWHM spot. Elemental SIMS maps were obtained from 10×10 μm2 areas in times not exceeding 524s.


1997 ◽  
Vol 9 (6) ◽  
pp. 541-565 ◽  
Author(s):  
Cheryl R. Killingsworth ◽  
Francesca Alessandrini ◽  
G. G. Krishna Murthy ◽  
Paul J. Catalano ◽  
Joseph D. Paulauskis ◽  
...  

1913 ◽  
Vol 76 (1960supp) ◽  
pp. 61-64
Author(s):  
C. F. Hirshfeld
Keyword(s):  

2015 ◽  
Vol 1 (1) ◽  
pp. 5-16
Author(s):  
John Ohoiwutun

Utilization of conventional energy sources such as coal, fuel oil, natural gas and others on the one hand has a low operating cost, but on the other side of the barriers is the greater source of diminishing returns and, more importantly, the emergence of environmental pollution problems dangerous to human life. This study aims to formulate the kinematics and dynamics to determine the movement of Solar Power Mower. In this study, using solar power as an energy source to charge the battery which then runs the robot. Design and research was conducted in the Department of Mechanical Workshop Faculty of Engineering, University of Hasanuddin of Gowa. Control system used is a manual system using radio wave transmitter and receiver which in turn drive the robot in the direction intended. Experimental results showed that treatment with three variations of the speed of 6.63 m / s, 8.84 m / s and 15.89 m / sec then obtained the best results occur in grass cutting 15.89 sec and high-speed cutting grass 5 cm. Formulation of kinematics and dynamics for lawn mowers, there are 2 control input variables, x and y ̇ ̇ 3 to control the output variables x, y and θ so that there is one variable redudant. Keywords: mobile robots, lawn mower, solar power


2019 ◽  
Vol 12 (1) ◽  
pp. 22-28
Author(s):  
V. Ye. Mikhailov ◽  
S. P. Kolpakov ◽  
L. A. Khomenok ◽  
N. S. Shestakov

One of the most important issues for modern domestic power industry is the creation and further widespread introduction of solid propellant energy units for super-critical steam parameters with high efficiency (43–46%) and improved environmental parameters. This will significantly reduce the use of natural gas.At the same time, one of the major drawbacks of the operation of pulverized coal power units is the need to use a significant amount of fuel oil during start-up and shutdown of boilers to stabilize the burning of the coal torch in the variable boiler operating modes.In this regard, solid fuel TPPs need to be provided with fuel oil facilities, with all the associated problems to ensure the performance (heating of fuel oil in winter), reliability and safety. All of the above problems increase both the TPP capital construction costs, and the electricity generating cost.A practical solution to the above problems at present is the use of a plasma technology for coal torch ignition based on thermochemical preparation of fuel for combustion. The materials of the developments of JSC “NPO CKTI” on application of plasmatrons in boilers of thermal power plants at metallurgical complexes of the Russian Federation are also considered.Plasma ignition systems for solid fuels in boilers were developed by Russian specialists and were introduced at a number of coal-fi red power plants in the Russian Federation, Mongolia, North Korea, and Kazakhstan. Plasma ignition of solid fuels is widely used in China for almost 30% of power boilers.The introduction of plasma-energy technologies will improve the energy efficiency of domestic solid-fuel thermal power plants and can be widely implemented in the modernization of boilers.During the construction of new TPPs, the construction of fuel oil facilities can be abandoned altogether, which will reduce the capital costs of the construction of thermal power plants, reduce the construction footprint, and increase the TPP safety.


2020 ◽  
pp. 49-52
Author(s):  
S.E. YANUTINA ◽  

The relevance of research in the factory laboratory of JSC «198 KZHI», which is part of the HC GVSU «Center», is dictated by the need to dispose of foam polystyrene waste that occurs in large quantities when producing the precast concrete. In the production of three-layer external wall panels, polystyrene heatinsulating plates of the PPS 17-R-A brand are used as an effective insulation material. The secondary use of PPS 17-R-A for its intended purpose, as a heater, is not possible. The volume of foam polystyrene produced varies from 25 to 45 m3 per month. Utilization (disposal) of foam polystyrene waste is an expensive undertaking. Its use as a filler in the production of expanded polystyrene blocks was tested in the factory’s laboratory to produce foam polystyrene concrete with specified physical and mechanical characteristics. The results of testing of expanded polystyrene concrete of classes B2.5 and B 7.5 are presented. It is shown that under the conditions of the reinforced concrete factory technology, the production of polystyrene concrete blocks is possible with the achievement of the design strength. The information presented in the article is aimed at motivating specialists who produce recast concrete to the possibility of using foam polystyrene waste for low-rise construction. Keywords: foam polystyrene, ecology, energy efficiency, foam polystyrene concrete, foam polystyrene heat insulation plates, precast concrete.


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