scholarly journals Review of Conversion Technologies of Waste Polystyrene into useful Products

2021 ◽  
Vol 7 (3) ◽  
pp. 43-48
Author(s):  
Shalu Patel ◽  
Shalu Patel ◽  
Savita Dixit ◽  
Kavita Gidwani Suneja ◽  
Nilesh Tipan

Polystyrene usage has risen significantly in recent years as a result of its wide variety of applications. The persistent consumer demand for polystyrene resulted in the accumulation of polystyrene waste in landfills, inducing environmental degradation. Since polystyrene is a petroleum-derived material, the increasing demand for it resulted in the depletion of petroleum, a non-renewable energy source. Research teams from all over the world have invented many methods for dealing with polystyrene waste, including recycling and energy regeneration. However, there are drawbacks to recycling methods, such as the fact that they need a lot of manpower in the separating procedure and pollute the water, reducing the process's sustainability. Because of these flaws, the experimenters have cantered their efforts on the energy harvesting approach. As petroleum is the primary component of polystyrene, the pyrolysis process for recovering fuel oil from polystyrene is an useful technology because the retrieved oil has a higher calorific value than commercially available gasoline. The current paper discusses polystyrene conversion technologies as well as the pyrolysis techniques for polystyrene, which generates end products such as oil, gas, and char. The impact of different processing parameters on the product yield has been addressed using more advanced techniques of conducting pyrolysis with a solvent.

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 225
Author(s):  
Ibrahim M. Maafa

The manufacturing of polystyrene around the globe has escalated in the past years due to its huge applications in various areas. The perpetual market needs of polystyrene led the polystyrene wastes accretion in the landfill causing environmental deterioration. The soaring need for polystyrene also led to the exhaustion of petroleum, a non-renewable energy source, as polystyrene is a petroleum-derived product. Researchers from around the world have discovered a few techniques to take care of the polystyrene scraps, namely recycling and energy recovery techniques. Nevertheless, there are demerits involved with recycling techniques, such as they call for huge labor expenses in the separation process and cause water pollution, thereby decreasing the process sustainability. Owing to these demerits, the researchers have focused their attention on the energy recovery technique. Since petroleum is the main ingredient of polystyrene synthesis, the restoration of liquid oil from polystyrene via the pyrolysis method is a promising technique as the recovered oil has greater calorific value as compared to commercially available fuel. The present paper surveys the pyrolysis technique for polystyrene and the important process parameters that control the end product, like oil, gas, and char. The chief process parameters that are discussed in this review paper include the type of reactors, temperature, residence time, pressure, catalyst types, type of fluidizing gases, and their flow rate. A more recent technique of utilizing a solvent to perform pyrolysis and the effect of various process conditions on the product yield have been discussed. Apart from this, various outlooks to optimize the liquid oil recovery from polystyrene are also reviewed.


2020 ◽  
Vol 2020 (10) ◽  
pp. 19-33
Author(s):  
Nadiia NOVYTSKA ◽  
◽  
Inna KHLIEBNIKOVA ◽  

The market of tobacco products in Ukraine is one of the most dynamic and competitive. It develops under the influence of certain factors that cause structural changes, therefore, the aim of the article is to conduct a comprehensive analysis of transformation processes in the market of tobacco and their alternatives in Ukraine and identify the factors that cause them. The high level of tax burden and the proliferation of alternative products with a potentially lower risk to human health, including heating tobacco products and e-cigarettes, are key factors in the market’s transformation process. Their presence leads to an increase in illicit turnover of tobacco products, which accounts for 6.37% of the market, and the gradual replacement of cigarettes with alternative products, which account for 12.95%. The presence on the market of products that are not taxed or taxed at lower rates is one of the reasons for the reduction of excise duty revenues. According to the results of 2019, the planned indicators of revenues were not met by 23.5%. Other reasons for non-fulfillment of excise duty revenues include: declining dynamics of the tobacco products market; reduction in the number of smokers; reorientation of «cheap whites» cigarette flows from Ukraine to neighboring countries; tax avoidance. Prospects for further research are identified, namely the need to develop measures for state regulation and optimization of excise duty taxation of tobacco products and their alternatives, taking into account the risks to public health and increasing demand of illegal products.


Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 213
Author(s):  
Hamid Ait Said ◽  
Hassan Noukrati ◽  
Hicham Ben Youcef ◽  
Ayoub Bayoussef ◽  
Hassane Oudadesse ◽  
...  

Three-dimensional hydroxyapatite-chitosan (HA-CS) composites were formulated via solid-liquid technic and freeze-drying. The prepared composites had an apatitic nature, which was demonstrated by X-ray diffraction and Infrared spectroscopy analyses. The impact of the solid/liquid (S/L) ratio and the content and the molecular weight of the polymer on the composite mechanical strength was investigated. An increase in the S/L ratio from 0.5 to 1 resulted in an increase in the compressive strength for HA-CSL (CS low molecular weight: CSL) from 0.08 ± 0.02 to 1.95 ± 0.39 MPa and from 0.3 ± 0.06 to 2.40 ± 0.51 MPa for the HA-CSM (CS medium molecular weight: CSM). Moreover, the increase in the amount (1 to 5 wt%) and the molecular weight of the polymer increased the mechanical strength of the composite. The highest compressive strength value (up to 2.40 ± 0.51 MPa) was obtained for HA-CSM (5 wt% of CS) formulated at an S/L of 1. The dissolution tests of the HA-CS composites confirmed their cohesion and mechanical stability in an aqueous solution. Both polymer and apatite are assumed to work together, giving the synergism needed to make effective cylindrical composites, and could serve as a promising candidate for bone repair in the orthopedic field.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2621
Author(s):  
Aneta Bartkowska

The paper presents the results of a study of the microstructure, chemical composition, microhardness and corrosion resistance of Cr-B coatings produced on Vanadis 6 tool steel. In this study, chromium and boron were added to the steel surface using a laser alloying process. The main purpose of the study was to determine the impact of those chemical elements on surface properties. Chromium and boron as well as their mixtures were prepared in various proportions and then were applied on steel substrate in the form of precoat of 100 µm thickness. Depending on the type of precoat used and laser processing parameters, changes in microstructure and properties were observed. Coatings produced using precoat containing chromium and boron mixture were characterized by high microhardness (900 HV0.05–1300 HV0.005) while maintaining good corrosion resistance. It was also found that too low laser beam power contributed to the formation of cracks and porosity.


Author(s):  
Guglielmo Costa ◽  
Alessandro Bressan ◽  
Michela Mapelli ◽  
Paola Marigo ◽  
Giuliano Iorio ◽  
...  

Abstract Pair-instability (PI) is expected to open a gap in the mass spectrum of black holes (BHs) between ≈40 − 65 M⊙ and ≈120 M⊙. The existence of the mass gap is currently being challenged by the detection of GW190521, with a primary component mass of $85^{+21}_{-14}$ M⊙. Here, we investigate the main uncertainties on the PI mass gap: the 12C(α, γ)16O reaction rate and the H-rich envelope collapse. With the standard 12C(α, γ)16O rate, the lower edge of the mass gap can be 70 M⊙ if we allow for the collapse of the residual H-rich envelope at metallicity Z ≤ 0.0003. Adopting the uncertainties given by the starlib database, for models computed with the 12C(α, γ)16O rate −1 σ, we find that the PI mass gap ranges between ≈80 M⊙ and ≈150 M⊙. Stars with MZAMS > 110 M⊙ may experience a deep dredge-up episode during the core helium-burning phase, that extracts matter from the core enriching the envelope. As a consequence of the He-core mass reduction, a star with MZAMS = 160 M⊙ may avoid the PI and produce a BH of 150 M⊙. In the −2 σ case, the PI mass gap ranges from 92 M⊙ to 110 M⊙. Finally, in models computed with 12C(α, γ)16O −3 σ, the mass gap is completely removed by the dredge-up effect. The onset of this dredge-up is particularly sensitive to the assumed model for convection and mixing. The combined effect of H-rich envelope collapse and low 12C(α, γ)16O rate can lead to the formation of BHs with masses consistent with the primary component of GW190521.


2004 ◽  
Vol 49 (7) ◽  
pp. 89-95
Author(s):  
J. Pittock ◽  
R. Holland

More than for any other biome, freshwater biodiversity is increasingly imperiled, particularly due to poor stream flow management and increasing demand for water diversions. The adoption by the world's governments of targets to extend water services to the poor and at the same time to conserve biodiversity increase the need to better direct investments in freshwater management. In this paper WWF draws on examples from its work to identify areas where investment can be focused to assure efficient water use and improve stream flow management, namely:• Prioritize and target those river basins and sub-catchments that are most critical for conservation of freshwater biodiversity to maintain stream flows;• Link strategic field, policy and market interventions at different scales in river basins to maximize the impact of interventions;• Implement the World Commission on Dams guidelines to minimize investment in large scale and costly infrastructure projects;• Apply market mechanisms and incentives for more sustainable production of the world's most water consuming crops;• Enhance statutory river basin management organizations to draw on their regulatory and financial powers;• Implement international agreements, such as the Convention on Wetlands;• Integrate environment and development policies.


2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Begüm Yurteri Kösedağlı ◽  
Gül Huyugüzel Kışla ◽  
A. Nazif Çatık

AbstractThis study analyzes oil price exposure of the oil–gas sector stock returns for the fragile five countries based on a multi-factor asset pricing model using daily data from 29 May 1996 to 27 January 2020. The endogenous structural break test suggests the presence of serious parameter instabilities due to fluctuations in the oil and stock markets over the period under study. Moreover, the time-varying estimates indicate that the oil–gas sectors of these countries are riskier than the overall stock market. The results further suggest that, except for Indonesia, oil prices have a positive impact on the sectoral returns of all markets, whereas the impact of the exchange rates on the oil–gas sector returns varies across time and countries.


2012 ◽  
Vol 182-183 ◽  
pp. 422-426 ◽  
Author(s):  
Hui Juan Hao ◽  
Guang He Cheng ◽  
Ji Yong Xu

In this paper, the pulse-induced acoustic sound in laser cutting is collected, and the data processing is performed with wavelet denoising and time-frequncy analyzing. The impact of laser processing parameters on the acoustic signal is discussed; and further analysis of the effect of cutting speed is conducted. The corresponding relationship between the best velocity and the maximum time-frequency energy density is got; also the plan of adaptive control in laser cutting is designed. The results in this paper can provide important parameters for adaptive control of laser cutting.


2018 ◽  
Vol 7 (11) ◽  
pp. 425 ◽  
Author(s):  
Kumar Jayant ◽  
Isabella Reccia ◽  
Francesco Virdis ◽  
A. Shapiro

Aim: The livers from DCD (donation after cardiac death) donations are often envisaged as a possible option to bridge the gap between the availability and increasing demand of organs for liver transplantation. However, DCD livers possess a heightened risk for complications and represent a formidable management challenge. The aim of this study was to evaluate the effects of thrombolytic flush in DCD liver transplantation. Methods: An extensive search of the literature database was made on MEDLINE, EMBASE, Cochrane, Crossref, Scopus databases, and clinical trial registry on 20 September 2018 to assess the role of thrombolytic tissue plasminogen activator (tPA) flush in DCD liver transplantation. Results: A total of four studies with 249 patients in the tPA group and 178 patients in the non-tPA group were included. The pooled data revealed a significant decrease in ischemic-type biliary lesions (ITBLs) (P = 0.04), re-transplantation rate (P = 0.0001), and no increased requirement of blood transfusion (P = 0.16) with a better one year graft survival (P = 0.02). Conclusions: To recapitulate, tPA in DCD liver transplantation decreased the incidence of ITBLs, re-transplantation and markedly improved 1-year graft survival, without any increased risk for blood transfusion, hence it has potential to expand the boundaries of DCD liver transplantation.


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