Synthesis of starch nanoparticles with controlled morphology and various adsorption rate for urea

2022 ◽  
Vol 369 ◽  
pp. 130882
Author(s):  
Xin Pan ◽  
Pei Liu ◽  
Yiwei Wang ◽  
Yan-ling Yi ◽  
Huang-qin Zhang ◽  
...  
Keyword(s):  
Adsorption Rate ◽  
Starch Nanoparticles ◽  
Controlled Morphology

Postmortem and in situ TEM methods to study the mechanism of failure in controlled-morphology high-impact polystrene resin

1996 ◽  
Vol 54 ◽  
pp. 178-179
Author(s):  
R. C. Cieslinski ◽  
M. T. Dineen ◽  
J. L. Hahnfeld
Keyword(s):  
Poisson Ratio ◽  
Acrylonitrile Butadiene Styrene ◽  
High Impact ◽  
In Situ Tem ◽  
Styrene Copolymers ◽  
Controlled Morphology ◽  
Point Bend ◽  
Mechanism Of Failure ◽  
Impact Energies

Advanced Styrenic resins are being developed throughout the industry to bridge the properties gap between traditional HIPS (High Impact Polystyrene) and ABS (Acrylonitrile-Butadiene-Styrene copolymers) resins. These new resins have an unprecedented balance of high gloss and high impact energies. Dow Chemical's contribution to this area is based on a unique combination of rubber morphologies including labyrinth, onion skin, and core-shell rubber particles. This new resin, referred as a controlled morphology resin (CMR), was investigated to determine the toughening mechanism of this unique rubber morphology. This poster will summarize the initial studies of these resins using the double-notch four-point bend test of Su and Yee, tensile stage electron microscopy, and Poisson Ratio analysis of the fracture mechanism.

A New Adsorption Rate Equation in Batch Systems

2018 ◽  
Author(s):  
yongson hong ◽  
Kye-Ryong Sin ◽  
Jong-Su Pak ◽  
Chol-Min Pak
Keyword(s):  
Experimental Data ◽  
Kinetic Analysis ◽  
Adsorption Kinetics ◽  
Rate Equation ◽  
Kinetic Models ◽  
Adsorption Kinetic ◽  
Adsorption Rate ◽  
Batch Systems ◽  
New View

<p><b>In this paper, the deficiencies and cause of previous adsorption kinetic models were revealed, new adsorption rate equation has been proposed and its validities were verified by kinetic analysis of various experimental data.</b> <b>This work is a new view on the adsorption kinetics rather than a comment on the previous adsorption papers.</b></p>

ALUMINA MATRIX WITH CONTROLLED MORPHOLOGY FOR COLORED SPECTRALLY SELECTIVE COATINGS

2017 ◽  
Vol 16 (3) ◽  
pp. 715-724 ◽  
Author(s):  
Luminita Isac ◽  
Lavinia Nicoara ◽  
Ramona Panait ◽  
Alexandru Enesca ◽  
Dana Perniu ◽  
...  
Keyword(s):  
Alumina Matrix ◽  
Spectrally Selective ◽  
Controlled Morphology

Mannose Conjugated Starch Nanoparticles for Preferential Targeting of Liver Cancer

2020 ◽  
Vol 17 ◽  
Author(s):  
Akhlesh Kumar Jain ◽  
Hitesh Sahu ◽  
Keerti Mishra ◽  
Suresh Thareja
Keyword(s):  
Side Effects ◽  
Liver Cancer ◽  
Entrapment Efficiency ◽  
Xrd Analysis ◽  
In Vitro Cytotoxicity ◽  
Physical Interaction ◽  
Scanning Calorimetry ◽  
Starch Nanoparticles

Aim: To design D-Mannose conjugated 5-Fluorouracil (5-FU) loaded Jackfruit seed starch nanoparticles (JFSSNPs) for site specific delivery. Background: Liver cancer is the third leading cause of death in world and fifth most often diagnosed cancer is the major global threat to public health. Treatment of liver cancer with conventional method bears several side effects, thus to undertake these side effects as a formulation challenge, it is necessary to develop novel target specific drug delivery system for the effective and better localization of drug into the proximity of target with restricting the movement of drug in normal tissues. Objective: To optimize and characterize the developed D-Mannose conjugated 5-Fluorouracil (5-FU) loaded Jackfruit seed starch nanoparticles (JFSSNPs) for effective treatment of liver cancer. Materials and methods: 5-FU loaded JFSSNPs were prepared and optimized formulation had higher encapsulation efficiency were conjugated with D-Mannose. These formulations were characterized for size, morphology, zeta potential, X-Ray Diffraction, and Differential Scanning Calorimetry. Potential of NPs were studied using in vitro cytotoxicity assay, in vivo kinetic studies and bio-distribution studies. Result and discussion: 5-Fluorouracil loaded NPs had particle size between 336 to 802nm with drug entrapment efficiency was between 64.2 to 82.3%. In XRD analysis, 5-FU peak was diminished in the diffractogram, which could be attributed to the successful incorporation of drug in amorphous form. DSC study suggests there was no physical interaction between 5- FU and Polymer. NPs showed sustained in vitro 5-FU release up to 2 hours. In vivo, mannose conjugated NPs prolonged the plasma level of 5-FU and assist selective accumulation of 5-FU in the liver (vs other organs spleen, kidney, lungs and heart) compared to unconjugated one and plain drug. Conclusion: In vivo, bio-distribution and plasma profile studies resulted in significantly higher concentration of 5- Fluorouracil liver suggesting that these carriers are efficient, viable, and targeted carrier of 5-FU treatment of liver cancer.

Transient Kinetic and Thermodynamic Behaviour of Langmuir Adsorption in a Flow System

1999 ◽  
Vol 64 (4) ◽  
pp. 726-734 ◽  
Author(s):  
Miloslav Pekař ◽  
Josef Koubek
Keyword(s):  
Adsorption Equilibrium ◽  
Flow System ◽  
Adsorption Rate ◽  
Adsorption Behaviour ◽  
Transient Responses ◽  
Simple Reaction ◽  
Langmuir Adsorption ◽  
Thermodynamic Behaviour

Various kinetic pathways to the adsorption equilibrium in an isothermal differential bed of adsorbent are illustrated on several examples. Discussion is based on the computed transient responses of adsorption rate and distance from adsorption equilibrium to the start of adsorptive feed. It is shown that adsorption behaviour in flow system may not be smooth and very steep changes on the rate responses may appear. Even the simple reaction need not approach equilibrium smoothly but at a jump. The approach assuming "closeness to the equilibrium" should be used very carefully, in this case.

Physicochemical properties of starch nanocomposite films enhanced by self-assembled potato starch nanoparticles

LWT ◽  
2016 ◽  
Vol 69 ◽  
pp. 251-257 ◽  
Author(s):  
Suisui Jiang ◽  
Chengzhen Liu ◽  
Xiaojin Wang ◽  
Liu Xiong ◽  
Qingjie Sun
Keyword(s):  
Physicochemical Properties ◽  
Potato Starch ◽  
Nanocomposite Films ◽  
Starch Nanoparticles ◽  
Self Assembled

Combined effect of cassava starch nanoparticles and protein isolate in properties of starch‐based nanocomposite films

2021 ◽  
Vol 138 (18) ◽  
pp. 50008
Author(s):  
Fabiane Cerqueira Almeida ◽  
Carolina Oliveira Souza ◽  
Biane Oliveira Philadelpho ◽  
Paulo Vitor Lemos ◽  
Lucas Guimarães Cardoso ◽  
...  
Keyword(s):  
Cassava Starch ◽  
Protein Isolate ◽  
Combined Effect ◽  
Nanocomposite Films ◽  
Starch Nanoparticles

Study on Adsorption of Crosslinked Starch Microspheres towards Heavy Metal Ions

2013 ◽  
Vol 834-836 ◽  
pp. 531-535
Author(s):  
Li Yan Yang ◽  
Yi Hui Guo ◽  
Li Li Yu ◽  
Jing You
Keyword(s):  
Metal Ions ◽  
Reversed Phase ◽  
Adsorption Rate ◽  
X Ray Diffraction ◽  
Adsorption Selectivity ◽  
X Ray ◽  
Starch Microsphere ◽  
Other Substances ◽  
Effects Of Media ◽  
Kinetics Of

A type of cross-linking starch microsphere (CSMs) has been synthesized via reversed phase suspension method. Crosslinked starch microsphere has good adsorption performance to metal ions in water. The adsorption kinetics of Co (II) on the CSMs, selectivity of adsorption CSMs towards Co (II),Cu (II),Pb (II),Cd (II) and adsorption effects of media towards Co (II) were investigated. The CSMs and its adsorption product were comparatively characterized by X-ray diffraction (XRD). The results showed that The adsorption rate is mainly controlled by liquid film diffusion, and the constant of adsorption rate is 0.0686min-1 at 308K. The crystal structure of the CSMs decreased greatly after the incorporation of Co (II). Co (II) has better adsorption selectivity on CSMs. Ions coexist and other substances in the solution have certain impact on adsorption. Those data are helpful for treatment of the wastewater containing heavy ions.

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