New mechanistic insights into the effect of cations on membrane fouling caused by anionic polyacrylamide

Author(s):  
Bing Zhang ◽  
Heli Tang ◽  
Jinyu Chen ◽  
Bing Zhang ◽  
Yu Shen ◽  
...  
2017 ◽  
Vol 75 (8) ◽  
pp. 1982-1989 ◽  
Author(s):  
Ruijun Zhang ◽  
Shengnan Yuan ◽  
Wenxin Shi ◽  
Cong Ma ◽  
Zhiqiang Zhang ◽  
...  

With the purpose of improving the ultrafiltration (UF) efficiency, anionic polyacrylamide (APAM) has been used as a coagulant aid in the flocculation-UF process. In this study, the impact of APAM on UF efficiency has been investigated with regard to membrane fouling, membrane cleaning and effluent quality. The results indicated that the optimal dosage of APAM had positive impacts on membrane fouling control, membrane cleaning and effluent quality. According to the flux decline curve, scanning electron microscopy and contact angle characterization, the optimal dosage of APAM was determined to be 0.1 mg/L coupled with 2 mg/L (as Al3+) poly-aluminium chloride. Under this optimal condition, membrane fouling can be mitigated because of the formation of a porous and hydrophilic fouling layer. APAM in the fouling layer can improve the chemical cleaning efficiency of 0.5% NaOH due to the disintegration of the fouling layer when APAM is dissolved under strong alkaline conditions. Furthermore, with the addition of APAM in the flocculation-UF process, more active adsorption sites can be formed in the flocs as well as the membrane fouling layer, thus more antipyrine molecules in the raw water can be adsorbed and removed in the flocculation-UF process.


2020 ◽  
Vol 320 ◽  
pp. 114463
Author(s):  
Bing Zhang ◽  
Heli Tang ◽  
Dongmei Huang ◽  
Xu Gao ◽  
Bing Zhang ◽  
...  

2019 ◽  
Vol 1 (1) ◽  
pp. 1-10
Author(s):  
Kong Linghan ◽  
Zhao Weidian ◽  
Ran Deqin ◽  
Hui Bing ◽  
Lu Linguo ◽  
...  

2004 ◽  
Vol 4 (5-6) ◽  
pp. 215-222 ◽  
Author(s):  
A.R. Costa ◽  
M.N. de Pinho

Membrane fouling by natural organic matter (NOM), namely by humic substances (HS), is a major problem in water treatment for drinking water production using membrane processes. Membrane fouling is dependent on membrane morphology like pore size and on water characteristics namely NOM nature. This work addresses the evaluation of the efficiency of ultrafiltration (UF) and Coagulation/Flocculation/UF performance in terms of permeation fluxes and HS removal, of the water from Tagus River (Valada). The operation of coagulation with chitosan was evaluated as a pretreatment for minimization of membrane fouling. UF experiments were carried out in flat cells of 13.2×10−4 m2 of membrane surface area and at transmembrane pressures from 1 to 4 bar. Five cellulose acetate membranes were laboratory made to cover a wide range of molecular weight cut-off (MWCO): 2,300, 11,000, 28,000, 60,000 and 75,000 Da. Severe fouling is observed for the membranes with the highest cut-off. In the permeation experiments of raw water, coagulation prior to membrane filtration led to a significant improvement of the permeation performance of the membranes with the highest MWCO due to the particles and colloidal matter removal.


2004 ◽  
Vol 4 (5-6) ◽  
pp. 199-206
Author(s):  
M. Ribau Teixeira ◽  
H. Lucas ◽  
M.J. Rosa

A rapid small-scale evaluation of ultrafiltration (UF) performance with and without physical–chemical pre-treatment was performed to up-grade the conventional treatment used for drinking water production in Alcantarilha's water treatment works, Algarve, Portugal. Direct UF and pre-ozonation/coagulation/flocculation/sedimentation/UF (O/C/F/S/UF) were evaluated using polysulphone membranes of different apparent molecular weight cut-off (MWCO) (15–47 kDa). The results indicated that (i) UF is an effective barrier against microorganisms, including virus larger than 80 nm; (ii) for surface waters with low to moderate SUVA values, direct UF performance is equivalent or better than the conventional treatment in terms of residual turbidity, while UV254 nm and TOC residuals require the use of O/C/F/S/UF; (iii) the permeate quality improves with the membrane apparent MWCO decrease, especially for the direct UF, although the conventional treatment performance is never reached using UF; (iv) membrane fouling and adsorption phenomena are more severe in direct UF than in O/C/F/S/UF sequence (pre-ozonation decreases the membrane foulants by decreasing their hydrophobicity) and these phenomena increase with the membrane hydraulic permeability and, particularly, with the membrane apparent MWCO.


1975 ◽  
Vol 10 (1) ◽  
pp. 101-109
Author(s):  
H. Kirk Johnston ◽  
H.S. Lim

Abstract The suitability of reverse osmosis as a renovation technique for the treatment of municipal wastewaters has been assessed. Cellulose acetate membranes capable of 70% and 90% NaCl rejections were employed in both laboratory and pilot plant studies to evaluate the efficiency of this technique in removing the residual precipitant chemicals generally employed in phosphorus removal programs (iron chloride, alum, and lime) and the nutrients (phosphates, nitrates and ammonia) characteristic of municipal wastewaters. Secondary sewage and raw sewage as well as prepared nutrient solutions were employed in the course of this program. Both laboratory and pilot plant studies indicated consistently outstanding removal efficiencies for the species examined, almost independent of the nature of the waste solutions being treated. Permeation of the purified effluent was subject to significant reductions due to membrane fouling. This characteristic was most pronounced for the more permeable (less selective) membranes. Routine chemical and physical cleanings enable satisfactory flux levels to be maintained, thereby suggesting that reverse osmosis may become a viable municipal waste treatment technique.


2003 ◽  
Vol 3 (5-6) ◽  
pp. 15-22
Author(s):  
P. Kouadio ◽  
M. Tétrault

Three colored surface water nanofiltration pilot-scale projects were conducted in the province of Quebec (eastern Canada), between November 2000 and March 2002, by the company H2O Innovation (2000) inc., for the municipalities of Lac Bouchette, Latulipe-et-Gaboury and Charlesbourg (now part of Quebec City). Results indicated that nanofiltration permeate quality has an advance on present drinking water regulation standard in Quebec, but important membrane fouling occurred. Fouling can be controlled by pretreatment and optimization of the operating conditions.


2011 ◽  
Vol 11 (4) ◽  
pp. 481-489
Author(s):  
S. Krause ◽  
A. Obermayer

The public drinking water supply of southern Germany is characterized by a rather decentralized network. Due to the hydrogeological setting in these parts of Germany many of the small water works with an average capacity of 50 m3/h have to treat raw water extracted from karstic or cliffy aquifers. These raw waters tend to be contaminated with particles and pathogens acquired during snowmelt or after strong rainfalls. In the last decade ultrafiltration has become the technology of choice for the removal of the aforementioned contaminants. Flux decline caused by unanticipated membrane fouling is the main limitation for the application of ultrafiltration membranes. This paper describes how membrane fouling phenomena can be predicted by using a statistical approach based on data from large scale filtration systems in combination with field and lab experiments on raw water quality and membrane performance. The data defines water quality and respective fouling phenomena both in technical scale filtration plants and in lab experiments of eleven different raw waters. The method described here is more economically feasible for small water works when compared to typical pilot experiments that are used for high capacity water works.


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