Optimized CWPO oxidation of natural organic matter in continuous fixed bed reactor catalyzed by an extruded Al/Fe-PILC clay catalyst

Author(s):  
Gustavo Pinchao ◽  
Lucia Ortiz ◽  
Luis-Alejandro Galeano ◽  
Arsenio Hidalgo ◽  
José-Herney Ramírez
2014 ◽  
Vol 34 (2) ◽  
pp. 341-351 ◽  
Author(s):  
Cristiane Kreutz ◽  
Fernando H. Passig ◽  
Karina Q. de Carvalho ◽  
Juliana B. R. Mees ◽  
Simone D. Gomes

This paper sought to evaluate the behavior of an upflow Anaerobic-Aerobic Fixed Bed Reactor (AAFBR) in the treatment of cattle slaughterhouse effluent and determine apparent kinetic constants of the organic matter removal. The AAFBR was operated with no recirculation (Phase I) and with 50% of effluent recirculation (Phase II), with θ of 11h and 8h. In terms of pH, bicarbonate alkalinity and volatile acids, the results indicated the reactor ability to maintain favorable conditions for the biological processes involved in the organic matter removal in both operational phases. The average removal efficiencies of organic matter along the reactor height, expressed in terms of raw COD, were 49% and 68% in Phase I and 54% and 86% in Phase II for θ of 11h and 8h, respectively. The results of the filtered COD indicated removal efficiency of 52% and k = 0.0857h-1 to θ of 11h and 42% and k = 0.0880h-1 to θ of 8h in the Phase I. In Phase II, the removal efficiencies were 59% and 51% to θ of 11h and 8h, with k = 0.1238h-1 and k = 0.1075 h-1, respectively. The first order kinetic model showed good adjustment and described adequately the kinetics of organic matter removal for θ of 11h, with r² equal to 0.9734 and 0.9591 to the Phases I and II, respectively.


Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 637
Author(s):  
Cristian S. Portilla-Delgado ◽  
Ana M. García-Mora ◽  
Frederic Dappozze ◽  
Chantal Guillard ◽  
Luis A. Galeano

An Al/Fe-pillared clay catalyst (Al/Fe-PILC) prepared from low cost technical-grade reagents has been investigated in the photocatalytic Wet Peroxide Oxidation (photo-CWPO) of dissolved Natural Organic Matter (NOM) under circumneutral pH. The successful pillaring of the layered clay material was confirmed by X-ray diffraction (XRD), N2 adsorption at −196 °C, cation exchange capacity (CEC) and simultaneous thermal analysis (TGA/DSC). High levels of mineralization of the dissolved organic carbon and color removal of a synthetic NOM surrogate solution were achieved even under natural lab’s lighting and ambient temperature and pressure, whereas the absence of radiation (in dark) was found to strongly affect the performance of the degradation. The photo-CWPO of NOM activated by the Al/Fe-PILC clay catalyst under visible light irradiation (LED lamp, 450 and 550 nm peaks) displayed a DOC mineralization of 72% and color removal of 73% in just 210 min of irradiation at neutral pH, whereas both responses decayed under ultraviolet lightning (λ: 365 nm) to 41% and 58%, respectively. This behavior is ascribed to formation of triplet states of natural organic matter (3NOM*) by absorption of visible light, which seems to synergistically improve the rate-determining step of the heterogeneous Fenton process, namely reduction of Fe3+ into Fe2+ on the surface of the clay catalyst. Interestingly, experiments performed at neutral and pH 3.0 showed very similar efficiencies under visible light irradiation; these findings may really facilitate the application of the photo-CWPO process to assist conventional drinking water treatment plants in the removal of NOM before the typical disinfection by chlorine to produce safer drinking water.


Adsorption ◽  
2007 ◽  
Vol 13 (5-6) ◽  
pp. 569-577 ◽  
Author(s):  
Fusheng Li ◽  
Akira Yuasa ◽  
Yoshihiro Katamine ◽  
Hidenori Tanaka

2020 ◽  
Vol 92 (11) ◽  
pp. 1956-1965
Author(s):  
Yaneth A. Bustos‐Terrones ◽  
Rogelio Estrada‐Vázquez ◽  
Blenda Ramírez‐Pereda ◽  
Victoria Bustos‐Terrones ◽  
Jesús Gabriel Rangel‐Peraza

2020 ◽  
Vol 191 ◽  
pp. 03006
Author(s):  
Banu Sizirici ◽  
Ibrahim Yildiz

In this study, the adsorption capability of the activated sludge immobilized gravel as a low-cost and efficient adsorbent to remove organic matter in terms of chemical oxygen demand (COD) from synthetic wastewater was investigated using fixed bed columns. The effects of parameters including column pack height and influent COD concentrations on removal efficiencies were assessed through breakthrough curves. It was found that the removal efficiency increased when fixed bed height was increased and influent COD concentration was decreased. The maximum COD removal rate of 36.35%, was obtained for a medium-strength wastewater sample with 1166 mg/L of COD concentration when the bed height was 2 cm, and the flow rate was 11 mL/min. Activated sludge immobilized gravel can be utilized as a low cost bio-filter to remove organic material from wastewater.


2017 ◽  
Vol 189 ◽  
pp. 480-491 ◽  
Author(s):  
Lucas Tadeu Fuess ◽  
Luma Sayuri Mazine Kiyuna ◽  
Antônio Djalma Nunes Ferraz ◽  
Gabriela Felix Persinoti ◽  
Fabio Marcio Squina ◽  
...  

2016 ◽  
Vol 14 (4) ◽  
pp. 833-840 ◽  
Author(s):  
S. Álvarez-Torrellas ◽  
J. L. Sotelo ◽  
A. Rodríguez ◽  
G. Ovejero ◽  
J. García

2018 ◽  
Vol 156 ◽  
pp. 02011
Author(s):  
Adi Kurniawan ◽  
Dian Listiyani ◽  
Jono Suhartono ◽  
Suparman Juhanda

Nowadays water, one the most important substance in human life, are being much polluted by not only industrial activities but also caused by human activities and natural polluted material. One of the natural impurities that commonly occur in water is Natural Organic Matter (NOM). NOM are extracted organic compounds from soils, plants, or decomposed animals that infiltrate into the water body when the water contacts with those materials. Thus, the presence of NOM in water body is inevitable. Many techniques have been applied to remove this impurity such as coagulation, flocculation, and filtration. In this research, NOM were controlled using ozonated activated carbon in a fixed bed adsorption system. There were two parameters studied that are activated carbon ozonation time that ranging from 5 - 25 minutes and the fixed bed height of 1 - 7.5 cm. Interestingly, the investigation showed that the optimum condition for the bed height was obtained at 6 cm whilst the optimum carbon active ozonation time was at 5 minute. The experiment was concordant with the conducted BET analysis that showed the highest activated carbon surface area at 5 minute compared to other ozonation time. The ozonated activated carbon was also found to be have slightly better adsorption performance compared to unozonated activated carbon bought from the market with capacity of ozonated activated carbon adsorption was found to be 6.12 ϰ 10-3 mg/g.


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