A coating method combined with bulk addition for efficient flame retardant thermoplastic polyolefin sheet material

2020 ◽  
Vol 174 ◽  
pp. 109093 ◽  
Author(s):  
Wei Wang ◽  
Yuan Liu ◽  
Zhongqiang Han ◽  
Qi Wang
Author(s):  
Pham Thi Thu Trang ◽  
Le Ha Giang ◽  
Nguyen Ba Manh ◽  
Trinh Duc Cong ◽  
Ngo Trinh Tung ◽  
...  

SiO2 and TiO2 sols were successfully synthesized by using sodium silicate and titanium chloride as Si and Ti sources. SiO2-TiO2 sol coated polyester/cotton fabric was fabricated by deep-coating method and using SiO2, TiO2 sols as coating materials. SiO2-TiO2 coated fabric were characterized by XRD, FTIR, TGA, SEM and EDX. From SEM image, it showed the SiO2, TiO2 particles of 20-30 nm which well deposited on fabric surface. TGA result revealed the significant improvement of thermal resistance and stability of SiO2-TiO2 coated fabric as compared to those of uncoated fabric. Flame retardant performance of SiO2-TiO2 coated fabrics was much better than that of uncoated fabric. Thus, SiO2-TiO2 coated fabric SiO2-TiO2 content of 26wt% showed the UL-94 classification of V-0 and LOI value of 30.3 were obtained. Moreover, mechanical property (tear strength) of SiO2-TiO2 coated fabrics were also improved.


Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1542
Author(s):  
Marcin Przybylak ◽  
Michał Dutkiewicz ◽  
Karol Szubert ◽  
Hieronim Maciejewski ◽  
Szymon Rojewski

The development of novel flame retardants for cotton textiles that form a stable layer on textile fiber is of high economical and practical relevance. A novel flame retardant fluorinated phosphoric acid esters modified silicone resins for cotton modification were synthesized. The investigated phosphoric acid esters based compounds were substituted by a fluorinated chain or ring, and alkoxysilyl groups. The presence of alkoxysilyl groups allowed the formation of bonds with cellulose, while derivatives of phosphoric esters reduced the flammability of fabrics. Additionally, the presence of fluoride in their structures affected the hydrophobic properties. Cotton fabrics were modified in a simple one-step process by dip-coating method. The flame retardant properties of modified textiles were examined by performing microcalorimetric analysis, thermogravimetry analysis, and measuring oxygen index. The hydrophobicity was evaluated by measuring the water contact angle. The modified fabrics were characterized by SEM-EDS (Scanning Electron Microscopy with Energy Dispersive Spectroscopy) analysis and surface morphology. As a result of the tests, multifunctional fabrics were obtained.


2016 ◽  
Vol 721 ◽  
pp. 409-413 ◽  
Author(s):  
Arita Micule ◽  
Skaidrite Reihmane ◽  
Ilze Baltina

Due to its wide application improvement of fire protection of materials has always been topical. Aim of the research is to render textile materials less flammable in an economically and environmentally friendly manner using modified commercial products. Plain wave cotton fabric pretreated with cyclic phosphonate flame retardant (FR) Itoflam PES was used in experiments. Printing pastes Printperfect LAC 60, Tubiscreen EX-TS and Printperfect EX-AR with additive antimony trioxide (Sb2O3) were used for additional treatment of cotton fabric via flat screen coating method. FR properties, physico – mechanical characteristics (tensile strength, elongation, stiffness, abrasion resistance) were examined. It is concluded that foamed coating increases the stiffness and abrasion resistance of material. Recommendations for material application are given.


In this study, once-daily porosity osmotic pump tablets (POPTs) of Glimepiride were prepared using HPMC K100M (61%), osmotic agent (30% NaCl) coated using two different coating techniques spraying and dipping methods. The coating solution composed of ethyl cellulose (7.5%) w\w in ethanol (90%), castor oil (2%) as water-insoluble plasticizer and Gingo red color (0.5% w\w). In both techniques, the coating level was adjusted to give a 10% increase in the weight of the tablets. The effect of the coating by dipping technique with an increase in the weight of tablet (10 %, 20% & 50%) was also investigated to see the effect coating level on the percentage of drug release from POPTs. The results of the in vitro release of Glimepiride from tablets coated by the spraying method showed longer release time (24 hrs) than those coated with dipping method. On the other hand, increasing the coating level by dipping method retarded the release of the drug from tablets. However, the same retardation effect on release as shown with the spraying technique was only obtained by increasing the coating level with a 50% increase in the weight of the tablet. Thus, coating by spraying is more efficient to prepare POPTs to give a continuous release of Glimepiride from once daily table with the lowest increase in the total weight of the tablet.


2013 ◽  
Vol 133 (5) ◽  
pp. 170-176 ◽  
Author(s):  
Mikio Akamatsu ◽  
Kyohei Terao ◽  
Hidekuni Takao ◽  
Fusao Simokawa ◽  
Fumikazu Oohira ◽  
...  

2000 ◽  
Vol 628 ◽  
Author(s):  
Kazuki Nakanishi ◽  
Souichi Kumon ◽  
Kazuyuki Hirao ◽  
Hiroshi Jinnai

ABSTRACTMacroporous silicate thick films were prepared by a sol-gel dip-coating method accompanied by the phase separation using methyl-trimethoxysilane (MTMS), nitric acid and dimethylformamide (DMF) as starting components. The morphology of the film varied to a large extent depending on the time elapsed after the hydrolysis until the dipping of the coating solution. On a glass substrate, the films prepared by early dipping had inhomogeneous submicrometer-sized pores on the surface of the film. At increased reaction times, relatively narrow sized isolated macropores were observed and their size gradually decreased with the increase of reaction time. On a polyester substrate, in contrast, micrometer-sized isolated spherical gel domains were homogeneously deposited by earlier dippings. With an increase of reaction time, the volume fraction of the gel phase increased, then the morphology of the coating transformed into co-continuous gel domains and macropores, and finally inverted into the continuous gel domains with isolated macropores. The overall morphological variation with the reaction time was explained in terms of the phase separation and the structure freezing by the forced gelation, both of which were induced by the evaporation of methanol during the dipping operation.


2012 ◽  
pp. 1805-1808 ◽  
Author(s):  
L. Chibane ◽  
M.S. Belkaid ◽  
M. Pasquinelli ◽  
H. Derbal-Habak ◽  
J.J. Simon ◽  
...  

Author(s):  
V. A. Martynyuk ◽  
V. A. Trudonoshin ◽  
V. G. Fedoruk

The article considers applications of foreign CAD-systems in creating the challenging projects at domestic enterprises and design bureaus. As stated in the article "... presently, there is no domestic CAD-system that could completely replace such foreign products as NX, CATIA, Credo". Besides, due to international cooperation in creating the challenging projects (for example, the project to create a modern wide-body aircraft, proposed jointly with China), it makes sense to use the worldwide known and popular CAD systems (the aforementioned NX, CATIA, Credo). Therefore, in the foreseeable future, we will still have to use foreign software products. Of course, there always remains a question of the reliability of the results obtained. Actually, this question is always open regardless of what software product is used - domestic or foreign. This question has been haunting both developers and users of CAD systems for the last 30 to 40 years. But with using domestic systems, it is much easier to identify the cause of inaccurate results and correct the mathematical models used, the methods of numerical integration applied, and the solution of systems of nonlinear algebraic systems. Everything is much more complicated if we use a foreign software product. All advertising conversations that there is a tool to make the detected errors available to the developers, remain only conversations in the real world. It is easily understandable to domestic users, and, especially, to domestic developers of similar software products. The existing development rates and competition for potential buyers dictate a rigid framework of deadlines for releasing all new versions of the product and introducing the latest developments into commercial product, etc. As a result, the known errors migrate from version to version, and many users have accepted it long ago. Especially, this concerns the less popular tools rather than the most popular applications (modules) of a CAD system. For example, in CAD systems, the "Modeling" module where geometric models of designed parts and assembly units are created has been repeatedly crosschecked. But most of the errors are hidden in applications related to the design of parts from sheet material and to the pipeline design, as well as in applications related to the analysis of moving mechanisms and to the strength or gas dynamic analysis by the finite element method.The article gives a concrete example of a moving mechanism in the analysis of which an error was detected using the mathematical model of external influence (a source of speed) in the NX 10.0 system of Siemens.


2019 ◽  
Vol 9 (2) ◽  
pp. 182-191
Author(s):  
Akihiro Minami ◽  
Hirokazu Tamura ◽  
Hidetoshi Sakamoto ◽  
Yoshifumi Ohbuchi ◽  
Yasuo Marumo

Sign in / Sign up

Export Citation Format

Share Document