The degradation mechanism of a marine coating under service conditions of water ballast tank

2022 ◽  
Vol 162 ◽  
pp. 106588
Author(s):  
Paul Iannarelli ◽  
Douglas Beaumont ◽  
Yanwen Liu ◽  
Xiaorong Zhou ◽  
Timothy L. Burnett ◽  
...  
Keyword(s):  
Degradation Mechanism ◽  
Ballast Tank ◽  
Service Conditions

Revealing Degradation Mechanism of Ni-Rich Cathode Materials after Ambient Storage and Related Regeneration Method

2021 ◽  
Author(s):  
Congjie Lv ◽  
Zhenguo Li ◽  
Xiaoning Ren ◽  
Kaixiang Li ◽  
Jianmin Ma ◽  
...  
Keyword(s):  
Electric Vehicles ◽  
High Stability ◽  
Degradation Mechanism ◽  
High Energy ◽  
High Energy Density ◽  
Li Ion Batteries ◽  
Widespread Application ◽  
Ambient Storage ◽  
Li Ion ◽  
Service Conditions

Widespread application of Li-ion batteries (LIBs) in electric vehicles requires high energy density and high stability of the batteries in prolonged and diverse storage and service conditions. As one of...

The Tension Leg Semisubmersible (TLS): The Hybrid TLP-Semisubmersible Floater With the Spar Response

2014 ◽  
Author(s):  
Alaa M. Mansour ◽  
Chunfa Wu ◽  
Dhiraj Kumar ◽  
Ricardo Zuccolo
Keyword(s):  
Second Generation ◽  
State Of The Art ◽  
Service Condition ◽  
Harsh Environment ◽  
Ballast Tank ◽  
Execution Plan ◽  
Four Corners ◽  
Close Proximity ◽  
Service Conditions

The Tension Leg Semisubmersible (TLS) floater is the second generation of the Free-Hanging Solid Ballast Semisubmersible (FHSB Semi) design. The FHSB Semi is the state-of-the-art design that maintains the advantages of the conventional Semisubmersibles and provides the motions of Spars. The FHSB Semi design is a conventional semisubmersible with an added feature of a Free-Hanging Solid Ballast tank (SBT) located deep below the hull keel level and connected through four groups of chains (on its four corners) to the semisubmersible hull. During the pre-service conditions, the chains are used to retract the SBT and maintain it at a close proximity to the hull keel to facilitate the transportation and installation operations. Once the semisubmersible is moored in-place, the chain system is operated to lower the SBT to its desired elevation below the hull keel and maintain it permanently connected to the semisubmersible hull during the in-service condition. The SBT provides substantial in-water weight and added mass that significantly reduce the platform response and maintains the chains in tension. In this paper, detailed description of the Tension Leg Semisubmersible (TLS) design as the second generation of the FHSB Semi is presented. The paper also includes discussions on the proposed project execution plan for the TLS covering the fabrication, transportation and installation as well as the added risks and risk mitigations associated with the new semisubmersible design and execution. A case study is introduced where a TLS is used as a dry tree host for a field located at 6,000 ft of water in the central Gulf of Mexico (GoM) harsh environment.

Structures of c-di-GMP/cGAMP degrading phosphodiesterase VcEAL: identification of a novel conformational switch and its implication

2019 ◽  
Vol 476 (21) ◽  
pp. 3333-3353 ◽  
Author(s):  
Malti Yadav ◽  
Kamalendu Pal ◽  
Udayaditya Sen
Keyword(s):  
Active Site ◽  
Metal Binding ◽  
Metal Ion ◽  
Triosephosphate Isomerase ◽  
Catalytic Mechanism ◽  
Degradation Mechanism ◽  
Structural Basis ◽  
Conserved Residues ◽  
Phosphodiester Bond ◽  
Cyclic Dinucleotides

Cyclic dinucleotides (CDNs) have emerged as the central molecules that aid bacteria to adapt and thrive in changing environmental conditions. Therefore, tight regulation of intracellular CDN concentration by counteracting the action of dinucleotide cyclases and phosphodiesterases (PDEs) is critical. Here, we demonstrate that a putative stand-alone EAL domain PDE from Vibrio cholerae (VcEAL) is capable to degrade both the second messenger c-di-GMP and hybrid 3′3′-cyclic GMP–AMP (cGAMP). To unveil their degradation mechanism, we have determined high-resolution crystal structures of VcEAL with Ca2+, c-di-GMP-Ca2+, 5′-pGpG-Ca2+ and cGAMP-Ca2+, the latter provides the first structural basis of cGAMP hydrolysis. Structural studies reveal a typical triosephosphate isomerase barrel-fold with substrate c-di-GMP/cGAMP bound in an extended conformation. Highly conserved residues specifically bind the guanine base of c-di-GMP/cGAMP in the G2 site while the semi-conserved nature of residues at the G1 site could act as a specificity determinant. Two metal ions, co-ordinated with six stubbornly conserved residues and two non-bridging scissile phosphate oxygens of c-di-GMP/cGAMP, activate a water molecule for an in-line attack on the phosphodiester bond, supporting two-metal ion-based catalytic mechanism. PDE activity and biofilm assays of several prudently designed mutants collectively demonstrate that VcEAL active site is charge and size optimized. Intriguingly, in VcEAL-5′-pGpG-Ca2+ structure, β5–α5 loop adopts a novel conformation that along with conserved E131 creates a new metal-binding site. This novel conformation along with several subtle changes in the active site designate VcEAL-5′-pGpG-Ca2+ structure quite different from other 5′-pGpG bound structures reported earlier.

WIELAND-B18

Alloy Digest ◽  
2003 ◽  
Vol 52 (1) ◽  
Keyword(s):  
Corrosion Resistance ◽  
Physical Properties ◽  
Tensile Properties ◽  
Heat Treating ◽  
Bend Strength ◽  
Service Conditions ◽  
Common Application

Abstract Wieland-B18 is a phosphor bronze with a composition that allows usage in slightly more severe service conditions than alloy B16 (UNS C52100). A common application is in slide bearings and slideways. This datasheet provides information on composition, physical properties, hardness, elasticity, tensile properties, and bend strength as well as fatigue. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: CU-696. Producer or source: Wieland Metals Inc., Wieland-Werke AG.

Stochastic Models of Particle Trajectories in Turbulent Atmosphere Flows by Using the LANGEVIN Equations

Proceedings ◽  
2020 ◽  
Vol 1 (1) ◽  
Author(s):  
Youssra El Qasemy ◽  
Abdelfatah Achahbar ◽  
Abdellatif Khamlichi
Keyword(s):  
Wind Speed ◽  
Wind Turbine ◽  
Classical Method ◽  
Degradation Mechanism ◽  
Transformation Process ◽  
Langevin Equations ◽  
Turbulence Data ◽  
Power Curves ◽  
And Diffusion ◽  
Fluctuating Wind

The stochastic behavior of wind speed is a particular characteristic of wind energy production, which affects the degradation mechanism of the turbine, resulting in stochastic charging on the wind turbine. A model stochastic is used in this study to evaluate the efficiency of wind turbine power of whatever degree given fluctuating wind turbulence data. This model is based on the Langevin equations, which characterize, by two coefficients, drift and diffusion functions. These coefficients describe the behavior of the transformation process from the input wind speed to the output data that need to be determined. For this present work, the computation of drift and diffusion functions has been carried out by using the stochastic model to assess the output variables in terms of the torque and power curves as a function of time, and it is compared by the classical method. The results show that the model stochastic can define the efficiency of wind turbine generation more precisely.

Synthesis, Characterization and Thermal Degradation of Some New 3,5-dimethyl Pyrazole Derivatives

2017 ◽  
Vol 68 (2) ◽  
pp. 317-322
Author(s):  
Anca Mihaela Mocanu ◽  
Constantin Luca ◽  
Alina Costina Luca
Keyword(s):  
Thermal Degradation ◽  
Degradation Mechanism ◽  
New Products ◽  
Analysis Data ◽  
Biological Properties ◽  
Elemental Analysis Data ◽  
Ftir Analysis ◽  
Spectral Measurements ◽  
Chemical Structures ◽  
And Storage

The purpose of this research is to synthetize, characterize and thermal degradation of new heterolytic derivates with potential biological properties. The derivates synthesis was done by obtaining new molecules with pyralozone structure which combine two pharmacophore entities: the amidosulfonyl-R1,R2 phenoxyacetil with the 3,5-dimethyl pyrazole which can have potential biological properties. The synthesis stages of the new products are presented as well as the elemental analysis data and IR, 1H-NMR spectral measurements made for elucidating the chemical structures and thermostability study which makes evident the temperature range proper for their use and storage. The obtained results were indicative of a good correlation of the structure with the thermal stability as estimated by means of the initial degradation temperatures as well as with the degradation mechanism by means of the TG-FTIR analysis.

scholarly journals Failure Analysis on a Collapsed Flat Cover of an Adjustable Ballast Tank Used in Deep-Sea Submersibles

2019 ◽  
Vol 9 (23) ◽  
pp. 5258
Author(s):  
Fang Wang ◽  
Mian Wu ◽  
Genqi Tian ◽  
Zhe Jiang ◽  
Shun Zhang ◽  
...  
Keyword(s):  
Deep Sea ◽  
Material Selection ◽  
High Strength ◽  
External Pressure ◽  
Element Analysis ◽  
Ballast Tank ◽  
Material Inhomogeneity ◽  
Comprehensive Properties ◽  
Ultimate Cause ◽  
Flat Cover

A flat cover of an adjustable ballast tank made of high-strength maraging steel used in deep-sea submersibles collapsed during the loading process of external pressure in the high-pressure chamber. The pressure was high, which was the trigger of the collapse, but still considerably below the design limit of the adjustable ballast tank. The failure may have been caused by material properties that may be defective, the possible stress concentration resulting from design/processing, or inappropriate installation method. The present paper focuses on the visual inspections of the material inhomogeneity, ultimate cause of the collapse of the flat cover in pressure testing, and finite element analysis. Special attention is paid to the toughness characteristics of the material. The present study demonstrates the importance of material selection for engineering components based on the comprehensive properties of the materials.

scholarly journals Recent Achievements in Development of TiO2-Based Composite Photocatalytic Materials for Solar Driven Water Purification and Water Splitting

Materials ◽  
2020 ◽  
Vol 13 (6) ◽  
pp. 1338 ◽  
Author(s):  
Klara Perović ◽  
Francis M. dela Rosa ◽  
Marin Kovačić ◽  
Hrvoje Kušić ◽  
Urška Lavrenčič Štangar ◽  
...  
Keyword(s):  
Water Treatment ◽  
Transition Metal ◽  
Photocatalytic Degradation ◽  
Water Splitting ◽  
Water Purification ◽  
Degradation Mechanism ◽  
Living Environment ◽  
Solar Irradiation ◽  
Metal Chalcogenides ◽  
Photocatalytic Water Splitting

Clean water and the increased use of renewable energy are considered to be two of the main goals in the effort to achieve a sustainable living environment. The fulfillment of these goals may include the use of solar-driven photocatalytic processes that are found to be quite effective in water purification, as well as hydrogen generation. H2 production by water splitting and photocatalytic degradation of organic pollutants in water both rely on the formation of electron/hole (e−/h+) pairs at a semiconducting material upon its excitation by light with sufficient photon energy. Most of the photocatalytic studies involve the use of TiO2 and well-suited model compounds, either as sacrificial agents or pollutants. However, the wider application of this technology requires the harvesting of a broader spectrum of solar irradiation and the suppression of the recombination of photogenerated charge carriers. These limitations can be overcome by the use of different strategies, among which the focus is put on the creation of heterojunctions with another narrow bandgap semiconductor, which can provide high response in the visible light region. In this review paper, we report the most recent advances in the application of TiO2 based heterojunction (semiconductor-semiconductor) composites for photocatalytic water treatment and water splitting. This review article is subdivided into two major parts, namely Photocatalytic water treatment and Photocatalytic water splitting, to give a thorough examination of all achieved progress. The first part provides an overview on photocatalytic degradation mechanism principles, followed by the most recent applications for photocatalytic degradation and mineralization of contaminants of emerging concern (CEC), such as pharmaceuticals and pesticides with a critical insight into removal mechanism, while the second part focuses on fabrication of TiO2-based heterojunctions with carbon-based materials, transition metal oxides, transition metal chalcogenides, and multiple composites that were made of three or more semiconductor materials for photocatalytic water splitting.

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