Evaluation and Optimal Design of a High Stability Hydrothermal Deoxygenation Process for Production of Green Diesel Fuel via Deoxygenation of Waste Cooking Oil

Author(s):  
Sahar T. Mohammed ◽  
Saba A. Gheni ◽  
Dhia Y. Aqar ◽  
Khaleel I. Hamad ◽  
Safaa M.R. Ahmed ◽  
...  
Processes ◽  
2021 ◽  
Vol 9 (5) ◽  
pp. 750
Author(s):  
Nor Shafinaz Azman ◽  
Tengku Sharifah Marliza ◽  
Nurul Asikin Mijan ◽  
Taufiq Yap Yun Hin ◽  
Nozieana Khairuddin

Waste cooking oil (WCO) from palm oil is one of the most prospective biodiesel feedstock when compared to other oil seeds. Thus, WCO has great potential as a green source of diesel fuel for engines in motor vehicles and machinery. This project aimed to study the potential of three randomly selected types of WCO, namely; sample A (used 1× once to fry an egg), sample B (used 3–5× to fry salted fish), and sample C (used repeatedly to fry banana fritter) for the production of green diesel fuel over Ni-Mo/AC (nickel and molybdenum oxides incorporated with activated carbon) catalyst through the deoxygenation (DO) process. The prepared catalyst was characterized through X-ray diffraction (XRD), thermogravimetric analysis (TGA), and field emission scanning electron microscopy (FESEM). The DO process was performed at 350 °C to remove oxygen from the WCO samples. The liquid products were analysed by gas chromatography-mass spectrometer (GC-MS) and gas chromatography-flame ionization detector (GC-FID), to measure the yields of straight-chain hydrocarbons and fractions in the range C8‒C20. Results showed that the highest n-(C8‒C20) hydrocarbon fractions were produced in the order of sample B (89.93%) > C (88.84%) > A (82.81%).


2014 ◽  
Vol 3 (10) ◽  
pp. 3419
Author(s):  
Mohan Reddy Nalabolu* ◽  
Varaprasad Bobbarala ◽  
Mahesh Kandula

At the present moment worldwide waning fossil fuel resources as well as the tendency for developing new renewable biofuels have shifted the interest of the society towards finding novel alternative fuel sources. Biofuels have been put forward as one of a range of alternatives with lower emissions and a higher degree of fuel security and gives potential opportunities for rural and regional communities. Biodiesel has a great potential as an alternative diesel fuel. In this work, biodiesel was prepared from waste cooking oil it was converted into biodiesel through single step transesterification. Methanol with Potassium hydroxide as a catalyst was used for the transesterification process. The biodiesel was characterized by its fuel properties including acid value, cloud and pour points, water content, sediments, oxidation stability, carbon residue, flash point, kinematic viscosity, density according to IS: 15607-05 standards. The viscosity of the waste cooking oil biodiesel was found to be 4.05 mm2/sec at 400C. Flash point was found to be 1280C, water and sediment was 236mg/kg, 0 % respectively, carbon residue was 0.017%, total acid value was 0.2 mgKOH/g, cloud point was 40C and pour point was 120C. The results showed that one step transesterification was better and resulted in higher yield and better fuel properties. The research demonstrated that biodiesel obtained under optimum conditions from waste cooking oil was of good quality and could be used as a diesel fuel.


2014 ◽  
Vol 660 ◽  
pp. 386-390 ◽  
Author(s):  
Norazwan Azman ◽  
Mirnah Suardi ◽  
Amir Khalid

The use of fossil fuels as energy sources has grown to significantly be likely to have a major environmental impact. Reduction of world oil reserves and increasing environmental concerns have prompted alternative is found and renewable source of energy called biodiesel. Biodiesel fuel from vegetable oil is considered as the best candidates for diesel fuel replacement in diesel engines because of its closer. Fuel prices are going up day by day in the world. Thus, the means and methods have been trying for years to get fuel alternative outcomes. This study investigated the effects of different storage periods used in quality biodiesel blends (B5, B10, B15) of waste cooking oil and diesel fuel under low temperature and the temperature of the environment. Biodiesel samples were stored in glass containers under indoor conditions, and outdoor conditions for 10 weeks in total. These samples were monitored on a weekly basis through the test properties. The experimental density, viscosity, acid value, water content and flash point discussed in detail. Biodiesel storage at low temperatures is suitable and more advantageous because the impact on the physical properties is minimal and beneficial to slow down the degradation of biodiesel and storage.


Author(s):  
Ramanathan Velmurugan ◽  
Jaikumar Mayakrishnan ◽  
S. Induja ◽  
Selvakumar Raja ◽  
Sasikumar Nandagopal ◽  
...  

Vegetable oil is considered as one among the promising alternatives for diesel fuel as it holds properties very close to diesel fuel. However, straight usage of vegetable oil in compression ignition (CI) engine resulted in inferior performance and emission behavior. This can be improved by modifying the straight vegetable oil into its esters, emulsion, and using them as a fuel in CI engine showcased an improved engine behavior. Waste cooking oil (WCO) is one such kind of vegetable oil gained a lot of attraction globally as it is generated in a large quantity locally. The present investigation aims at analyzing various parameters of single cylinder four stroke CI engine fueled with waste cooking oil biodiesel (WCOB), waste cooking oil biodiesel water emulsion (WCOBE) while the engine is operated with a constant speed of 1500 rpm. Furthermore, an attempt is made to study the impact of nanofluids in the behavior of the engine fueled with WCOB blended with nanofluids (WCOBN50). This work also explored a novel method of producing nanofluids using one-step chemical synthesis method. Copper oxide (CuO) nanofluids were prepared by the above mentioned method and blended with waste cooking oil biodiesel (WCOBN50) using ethylene glycol as a suitable emulsifier. Results revealed that brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC) of WCOBN50 are significantly improved when compared to WCOB and WCOBE. Furthermore, a higher reduction in oxides of nitrogen (NOx), carbon monoxide (CO), hydrocarbon (HC), and smoke emissions were observed with WCOBN50 on comparison with all other tested fuels at different power outputs. It is also identified that one-step chemical synthesis method is a promising technique for preparing nanofluids with a high range of stability.


Author(s):  
H. Sharon ◽  
Joel Jackson R. ◽  
Prabha C.

Feed stock cost and NOX emission are the major barriers for commercialization of biodiesel. Waste cooking oil is well identified as one of the cheapest feed stocks for biodiesel production. This chapter reduces NOX emission of waste cooking oil biodiesel. Test fuel blends are prepared by mixing diesel (20 to 50 v/v%), butanol (5 v/v%), and waste cooking oil biodiesel (45 to 75 v/v%). Fuel properties of waste cooking oil biodiesel are enhanced due to addition of diesel and butanol. Brake specific energy consumption of the blends is higher than diesel fuel. Harmful emissions like carbon monoxide, nitrous oxide, and smoke opacity are lower for blends than diesel fuel. Increasing biodiesel concentration in blend also reduces hydrocarbon emission to a significant extent. The obtained results justify the suitability of proposed cheap blends for diesel engine emission reduction.


2020 ◽  
Author(s):  
Hemanandh Janarthanam ◽  
Venkatesan Sorakka Ponnappan ◽  
Ganesan Subbiah ◽  
Purushothaman Mani ◽  
D. Suman ◽  
...  

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