Effects of Physico-Chemical Properties of the Blended Diesel and Waste Cooking Oil Biodiesel

Biodiesel is a renewable fuel with similar chemical and physical properties to diesel. The study used waste cooking oil to make biodiesel because reusing waste cooking oil harms human health by raising FFA levels above the norm. Transesterification was performed at 60 °C using a 1:5 methanol to waste cooking oil volume ratio, 30 min reaction time, 600 rpm stirring speed and 1% wt. KOH was employed as a homogenous base catalyst. Biodiesel samples of B0, B2, B5, B20, B40 and B100 were processed at 25 ºC in combination with petrodiesel. Samples were tested for density, kinetic viscosity, flash point, acid value and pH. The fuel economy and flue gas analysis were performed using three-wheeler diesel. The amount of waste cooking oil biodiesel increases the density, kinematic viscosity, flash point, acid value and pH of the sample. In blended diesel, the amount of biodiesel also lowered CO2, CO, NO, NOx, hydrocarbon (HC) and SO2 emissions.

Effect of Time and Temperature on Biodiesel Production using Melon (Cucumeropsismannii), Groundnut (Arachis hypogea) and Soya bean (Glycine max)

This study investigated the optimum condition for biodiesel production at varying temperatures and time using melon (Cucumeropsismannii), groundnut (Arachis hypogea), and soya bean (Glycine max) seed oils. Extraction of oil from Cucumeropsismannii, Arachis hypogea, and Glycine max was accomplished using n-hexane (67.7-69.2oC) as the solvent. Biodiesel was produced from the three different seed oils at varying temperatures of 65oC, 55oC, and 45oC and also at the varied time of 60mins, 50mins and 40mins. The best percentage yield was obtained at a temperature of 65oC and a period of 60 minutes. At 40 min, the process was not complete. A good number of the transesterification process was completed at 50 mins. Also, at the lower temperature of 45oC, the method was not complete. The maximum % yield of the biodiesel obtained was 90.83% for Glycine max, 78.00% for Arachis hypogea, and 77.58% for Cucumeropsismannii seed oils. Fuel properties such as kinematic viscosity, pour point, carbon residue, cloud point, water content, flash point, cetane index, and sulfated ash were examined on the biodiesel. The flash point, carbon residue, kinematic viscosity, and water content were within the standard specified for petrol diesel. Cloud point and pour points of this product were found to be greater than that of petrol diesel. The cetane index was lower than the standard specified for petrol diesel and the three samples contained no sulfated ash. Therefore, melon (Cucumeropsismannii), groundnut (Arachis hypogea), and soya bean (Glycine max) are good alternatives to biodiesel production. Copyright (c) The Authors

COMPARATIVE EVALUATION OF BND 50/70 ROAD BITUMEN MODIFIED WITH SKEPT-60 AND SKN-26 ELASTOMERS

The article provides information on the physical and mechanical properties of polymer-bitumen compositions obtained by modifying road bitumen BND 50/70 with elastomers SKEPT-60 and SKN-26 and determination of the obtained polymer-bitumen composites. The properties of composite samples of various concentrations (2.5, 3.0, 5.0%, 6.5 and 7.0%) were determined: needle depth, softening, brittleness and flash point, stretching and adhesion. It was determined that the physical and mechanical characteristics of polymer-bitumen composite materials obtained at high concentrations (6.5, 7.0%) are improved

Determination of Fuel Properties of Biodiesel from Sand Apple Seed Oil with Automotive Gas Oil Blend

The objective of this study was to determine the fuel properties of Sand Apple Ethyl Ester (SAEE) and its blends with Automotive Gas Oil (AGO).using eggshell as catalyst. Sand apple seed oil (SASO) obtained was characterized based on America Society for Testing and Material (ASTM D6751) to determine acid value, saponification, iodine content, density, kinematic viscosity, flash point, cloud point and pour point. Sand Apple fruits were processed and oil extracted using solvent extraction method. Raw eggshells were calcined at 800oC for 120 min in the muffle furnace. SAEE was blended with AGO at 5 – 25 % mix. Data obtained was analyzed using ANOVA at P < 0.05 significant level. Cloud and pour points obtained for SASO are 4.68 and 3.09℃ . Flash point was 103℃ which fell within ASTM D93 range indicating that SASO is safe for handling and storage. Heating value was 42.61 MJ/kg, slightly lower than that of diesel oil of 44.8 MJ/kg shows that AGO has ability to produce heat of combustion than SASO. Iodine value was 80.71 g I/100g while acid value was determined to be 2.62 mgKOH/g, which was higher than that of ASTM D6751 of 0.5 mgKOH/g. Sulphur contents for AGO and SASO–AGO blends were 0.006, 0.009, 0.014, 0.016 and 0.004%, respectively. Low sulphur values indicates that hazardous sulphur dioxide emission of SAEE has reduced. This study established that all the properties obtained, except acid value, fell within the ASTM specification and could suitably be compared with those of fossil diesel.

PROPERTIES OF BOILER FUEL COMPOUNDED BY NARROW FUEL FRACTIONS

In order to improve the performance properties, in particular viscosity-temperature, of boiler fuel, it is proposed to combine them with narrow fuel fractions obtained by thermal destruction of secondary polymer raw materials (low pressure polyethylene and polypropylene). When compounding grade 100 fuel oil with narrow fuel fractions, the values ​​of density are reduced to 865 (873) kg / m3, conditional viscosity to 2.50 (2.63) deg. um., pour point up to 8 (13) °C), sulfur content up to 0.17 wt%. and the lower heat of combustion increases to 43606 (43850) kJ / kg. At the same time, there is a gradual decrease in the value of the flash point to 114 (127) °C. This reduction is a negative point, which leads to increased fire safety of fuel oil during its use, storage, pumping and transport. However, the values of the flash point, according to the requirements of regulatory documentation, are within acceptable limits. That is, the value of this indicator can limit the content of fuel oil in narrow fuel fractions. It is determined that the rational concentration of narrow fuel fractions in the composition of fuel oil grade 100, is within 30% of the mass. Within these limits, there is a permissible decrease in flash point values – an indicator that characterizes the fire hazard of fuel oil during its use, storage, pumping and transportation against the background of improving other performance properties of fuel oil. The production of the proposed compound boiler fuel on the one hand allows to expand the raw material base of the process by involving in the production process secondary polymer raw materials – solid waste subject to mandatory disposal, on the other – to meet existing demand for boiler fuel by increasing its production.

Utilization of Breed Chicken Eggshells to Make Biodiesel from Waste Cooking Oil

Chicken eggshell waste is a potential source of CaO which can be converted into heterogeneous catalysts. The purpose of this study was to utilize CaO heterogeneous catalysts to make biodiesel from waste cooking oil through the process of transesterification. A total of 4 g of catalyst was mixed with 200 g of waste cooking oil and 60 g of methanol, stirred at a speed of 700 rpm for 6 hours at a temperature of 600C ± 40C. The results were analyzed using GC-MS to confirm the formation of various methyl ester compounds. The product was found to have a density of 855 Kg/m3., viscosity of 3.74 mm2/s (cSt), and flash point of 1350C Based on the results, it be concluded that breed chicken eggshells can be converted as catalysts heterogeneous to make biodiesel from waste cooking oil. This information is very useful for further optimization of mass catalysts heterogeneous CaO from breed chicken eggshells including the production of biodiesel.